Development of Chiral Tetraaminophosphonium Peroxyacids for Asymmetric Catalyses
| Project/Area Number |
23655080
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 有機分子触媒 / 酸化反応 / 不斉合成 / 過オキソ酸イオン / ホスホニウムイオン / 過酸化水素 / イオン対 / 酸化 / オキソ酸 |
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| Research Abstract |
Novel chiral salts which are constructed from P-spiro chiral aminophosphonium ion and peroxoacid ions were achieved. It was revealed that the salts can be used for oxidation reactions. In addition, we found the ability of chiral iminophosphorane for activating hydrogen peroxide and applied this fact to develop asymmetric oxidation of N-sulfonyl imines.
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Report
(3 results)
Research Products
(8 results)
