| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Research Abstract |
To develop the novel field of amino acid chemistry, we focused on the synthesis of chiral amino acids and peptides having dynamic chirality or a silicon stereocenter. We accomplished the synthesis of dynamic planar chiral amino acids and peptides having an orthocyclophane skeleton. Furthermore, we successfully developed a catalytic enantioselective approach to chiral alkenylhydrosilanes, which are potential chiral building blocks for chiral amino acids having a silicon stereocenter.
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