Development of Novel Synthetic Methods of Soluble Graphene Derivatives Having Transistor Performance
Project/Area Number |
23655090
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Synthetic chemistry
|
Research Institution | Keio University |
Principal Investigator |
|
Project Period (FY) |
2011 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | C-H活性化 / 有機トランジスタ / アリール化 / グラフェン類 / オリゴアセン類アリールボロン酸エステル / 芳香族ケトン / 遷移金属錯体触媒 / C-H活性化 / オリゴアセン類 / アリールボロン酸エステル |
Research Abstract |
We have studied development of short syntheses of polycyclic aromatic hydrocarbons using coupling of aromatic ketones and arylboronates via carbon-hydrogen, carbon-oxygen, and carbon-nitrogen bond cleavages and have examined applications of these polycycl 1) development of multi-arylation of acetophenones via unreactive carbon bond cleavage and construction of benzene ring by transformation of acetyl groups; 2) development of new methods of short synthesis of polycyclic aromatic hydrocarbons having graphene frameworks by our multi-arylation protocols; 3) measurements of OFET performance of the synthesized polycyclic aromatic hydrocarbons.
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Report
(3 results)
Research Products
(52 results)