Absolute self-asymmetric polymerization : sponteneous, self catalyzed, and amplificated asymmetric polymerization

• Project/Area Number: 23655100
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Polymer chemistry
• Research Institution: Niigata University
• Principal Investigator: AOKI Toshiki 新潟大学, 自然科学系, 教授 (80212372)
• Co-Investigator(Kenkyū-buntansha): TERAGUCHI Masahiro 新潟大学, 自然科学系, 助教 (30334650)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
• Keywords: 不斉反応 / らせん選択重合 / 自発性

Research Abstract

We have reconfirmed the three unusual phenomena on the helix-sense-selective polymerization(HSSP) as gollows: 1) Spontaneous HSSP: The HSSP happened without any chiral cocatalyst. The best condition was a melt polymerization. 2) HSSP catalyzed by chiral polymers prepared by HSSP: The HSSP proceeded when the chiral polymers prepared by HSSP of the corresponding monomer. 3) Achiral-condition control HSSP: The helical sense of the chiral polymer prepared by HSSP was controlled by ahiral conditions. The mechanism was discussed by some spectra of the chiral catalytic system.

Research Products

• [Journal Article] Synthesis and Enantioselective Permeability of One-handed Helical Multihydroxy Poly(phenylacetylene) Membrane by In Situ Removal of the Original Chiral Substituents (2014)
  • Author(s): Lijia Liu, Kazuomi Mottate, Toshiki Aoki, Takashi Kaneko, and Masahiro Teraguchi
  • Journal Title: Chem. Lett Volume: 43 Pages: 237-239
  • NAID: 130004867973
  • Peer Reviewed
• [Journal Article] Synthesis and Enantioselective Permeability of One-handed Helical Multihydroxy Poly(phenylacetylene) Membrane by In Situ Removal of the Original Chiral Substituents (2014)
  • Author(s): Lijia Liu, Kazuomi Mottate, Toshiki Aoki,* Takashi Kaneko,2 and Masahiro Teraguchi
  • Journal Title: Chemistry Letters Volume: 43 Issue: 2 Pages: 237-239
  • DOI: 10.1246/cl.130896
  • NAID: 130004867973
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] Helix-Sense-Selective Polymerization of 3, 5-Bis(hydroxymethyl)phenylacetylene Connected with a Rigid and π-Conjugated Substituent (2013)
  • Author(s): Zhichun Shi, Yoshinori Murayama, Takashi Kaneko, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Chem. Lett Volume: 42(9) Pages: 1087-1089
  • Peer Reviewed
• [Journal Article] Chiral Amplification during Asymmetric-Induced Copolymerization of Phenylacetylenes with Tight Cis-Cisoidal Main Chains (2013)
  • Author(s): Lijia Liu, Kazuomi Mottate, Geng Zhang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Macromol. Rapid Commun Volume: 34(14) Pages: 1140-1144
  • Peer Reviewed
• [Journal Article] Folding-Induced Through-Space Magnetic Interaction of Poly(1, 3-phenyleneethynylene)-Based Polyradicals (2013)
  • Author(s): Takashi Kaneko, Hiromasa Abe, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Macromolecules Volume: 46(7) Pages: 2583-2589
  • Peer Reviewed
• [Journal Article] Helix-sense-selective Polymerization of Substituted Acetylenes by Using an Isolated Rh Chiral Initiator with an Amino Acid Ligand (2013)
  • Author(s): Yu Zang, Tomoyuki Ohishi, Toshiki Aoki, Masahiro Teraguchi, and Takashi Kaneko
  • Journal Title: Chem. Lett Volume: 42(4) Pages: 430-432
  • NAID: 10031162197
  • Peer Reviewed
• [Journal Article] Excellent oxygen permselectivity of fluorine-containing poly(trimethylsilyldiphenylacetylene)s prepared by direct alkylation of perfluorodecyl groups in membrane state (2013)
  • Author(s): Takashi Sato, Naoki Yoshida, Akihiro Ishida, Masahiro Teraguchi, Toshiki Aoki and Takashi Kaneko
  • Journal Title: Polymer Volume: 54(9) Pages: 2231-2234
  • Peer Reviewed
• [Journal Article] Living-like helix-sense-selective polymerization of an achiral substituted acetylene having bulky substituents (2013)
  • Author(s): Yu Zang, Kazuki Nakao, Hiroki Yotsuyanagi, Toshiki Aoki, Takeshi Namikoshi, Toyokazu Tsutsuba, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Polymer Volume: 54(7) Pages: 1729-1733
  • Peer Reviewed
• [Journal Article] Helix-Sense-Selective Polymerization of Achiral Acetylene Monomer Catalyzed by Rh Zwitterionic Complexes with Tethered Chiral Amino and Ether Groups (2013)
  • Author(s): Naoya Onishi, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi, Natsuhiro Sano, Toshio Masuda, Masashi Shiotsuki, Fumio Sanda
  • Journal Title: Chem. Lett Volume: 42 Pages: 278-280
  • NAID: 10031155779
  • Peer Reviewed
• [Journal Article] Top-down Preparation of Self-Supporting Supramolecular Polymeric Membranes Using Highly Selective Photocyclic Aromatization of Cis-Cisoid Helical Poly(phenylacetylene)s in the Membrane State (2013)
  • Author(s): Lijia Liu, Takeshi Namikoshi, Yu Zang, Toshiki Aoki, Shingo Hadano, Yunosuke Abe, Ikuya Wasuzu, Toyokazu Tsutsuba, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: J. Am. Chem. Soc Volume: 135(2) Pages: 602-605
  • Peer Reviewed
• [Journal Article] 『2D ポリマー』膜の合成-究極の分子分離膜をめざして (2013)
  • Author(s): 青木俊樹, 藏雨, 宮田真理, 棚木宏幸, 中尾和樹, 王建军, 寺口昌宏
  • Journal Title: 未来材料 Volume: 13(2) Pages: 31-38
  • Peer Reviewed
• [Journal Article] Helix-sense-selective Polymerization of 3,5-Bis(hydroxymethyl)phenylacetylene Connected with a Rigid and π-Conjugated Substituent (2013)
  • Author(s): Zhichun Shi, Yoshinori Murayama, Takashi Kaneko*, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Chemistry Letters Volume: 42 Issue: 9 Pages: 1087-1089
  • DOI: 10.1246/cl.130339
  • NAID: 10031194351
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] Chiral Amplification during Asymmetric-Induced Copolymerization of Phenylacetylenes with Tight Cis-Cisoidal Main Chains (2013)
  • Author(s): Lijia Liu,* Kazuomi Mottate, Geng Zhang, Toshiki Aoki,* Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Macromol. Rapid Commun. Volume: 34 Issue: 14 Pages: 1140-1144
  • DOI: 10.1002/marc.201300318
  • Peer Reviewed
• [Journal Article] Folding-Induced Through-Space Magnetic Interaction of Poly(1,3-phenyleneethynylene)-Based Polyradicals (2013)
  • Author(s): Takashi Kaneko, Hiromasa Abe, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Macromolecules Volume: 46 Issue: 7 Pages: 2583-2589
  • DOI: 10.1021/ma302314n
  • Peer Reviewed
• [Journal Article] Helix-sense-selective Polymerization of Substituted Acetylenes by Using an Isolated Rh Chiral Initiator (2013)
  • Author(s): Yu Zang, Tomoyuki Ohishi, Toshiki Aoki, Masahiro Teraguchi, and Takashi Kaneko
  • Journal Title: Chem. Lett. Volume: 42 Pages: 430-432
  • Peer Reviewed
• [Journal Article] Excellent oxygen permselectivity of fluorine-containing poly(trimethylsilyldiphenylacetylene)s prepared by direct alkylation of perfluorodecyl groups in membrane state (2013)
  • Author(s): Takashi Sato, Naoki Yoshida, Akihiro Ishida, Masahiro Teraguchi, Toshiki Aoki * and Takashi Kaneko
  • Journal Title: POLYMER Volume: 54 Issue: 9 Pages: 2231-2234
  • DOI: 10.1016/j.polymer.2013.03.008
  • Peer Reviewed
• [Journal Article] Living-like helix-sense-selective polymerization of an achiral substituted acetylene having bulky substituents (2013)
  • Author(s): Yu Zang, Kazuki Nakao, Hiroki Yotsuyanagi, Toshiki Aoki,* Takeshi Namikoshi, Toyokazu Tsutsuba, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: POLYMER Volume: 54 Issue: 7 Pages: 1729-1733
  • DOI: 10.1016/j.polymer.2013.02.009
  • Peer Reviewed
• [Journal Article] Helix-sense-selective Polymerization of Achiral Acetylene Monomer Catalyzed by Rh Zwitterionic Complexes with Tethered Chiral Amino and Ether Groups (2013)
  • Author(s): Naoya Onishi
  • Journal Title: Chemistry Letters Volume: 42 Issue: 3 Pages: 278-280
  • DOI: 10.1246/cl.2013.278
  • NAID: 10031155779
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] op-down Preparation of Self-Supporting Supramolecular Polymeric Membranes Using Highly Selective Photocyclic Aromatization of Cis-Cisoid Helical Poly(phenylacetylene)s in the Membrane State (2013)
  • Author(s): Lijia Liu, Takeshi Namikoshi, Yu Zang, Toshiki Aoki,* Shingo Hadano, Yunosuke Abe, Ikuya Wasuzu, Toyokazu Tsutsuba, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: J. Am. Chem. Soc Volume: 185 Issue: 2 Pages: 602-605
  • DOI: 10.1021/ja3113214
  • Peer Reviewed
• [Journal Article] Two Modes of Asymmetric Polymerization of Phenylacetylenes Having an L-Amino Alcohol Residue and Two Hydroxy Groups (2012)
  • Author(s): Hongge Jia, Yu Zang, Jun Li, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: J. Polym. Sci., Part A : Polym. Chem Volume: 50(24) Pages: 5134-5143
  • Peer Reviewed
• [Journal Article] Polymerization of Phenylacetylene-Based Monodendrons with Alkoxy Peripheral Groups, and Oxygen/Nitrogen Permeation Behavior of Their Membranes (2012)
  • Author(s): Takashi Kaneko, Kazuaki Sato, Yoshihiko Uchiya, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Int. J. Polym. Sci Volume: 2012(1) Pages: 974204-974204
  • Peer Reviewed
• [Journal Article] Helix-Sense-Selective Polymerization of Achiral Phenylacetylenes with Two N-Alkylamide Groups to Generate the One-Handed Helical Polymers Stabilized by Intramolecular Hydrogen Bonds (2012)
  • Author(s): Masahiro Teraguchi, Daisuke Tanioka, Takashi Kaneko, Toshiki Aoki
  • Journal Title: Macro. Lett Volume: 1(11) Pages: 1258-1261
  • Peer Reviewed
• [Journal Article] Enhanced Gas Permselectivity of Copoly(Hyperbranched Macromonomer) Synthesized by One-pot Simultaneous Copolymerization of Dimethylsilyl-containing Phenylacetylenes (2012)
  • Author(s): Jun Li, Jianjun Wang, Yu Zang, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
  • Journal Title: Chem. Lett Volume: 41 Pages: 1462-1464
  • NAID: 10031126564
  • Peer Reviewed
• [Journal Article] Synthesis of stable and soluble one-handed helical poly(substituted acetylene)s without chiral pendant groups via polymer reaction in membrane state, Yunosuke Abe (2012)
  • Author(s): Toshiki Aoki, Hongge Jia, Shingo Hadano, Takeshi Namikoshi, Yuriko Kakihana, Lijia Liu, Yu Zang, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Polym. Commun Volume: 53(11) Pages: 2129-2133
  • Peer Reviewed
• [Journal Article] Pseudo helix-sense-selective polymerization of achiral substituted acetylenes (2012)
  • Author(s): Yu Zang, Toshiki Aoki, Lijia Liu, Yunosuke Abe, Yuriko Kakihana, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Chem. Commun Volume: 48(39) Pages: 4761-4763
  • Peer Reviewed
• [Journal Article] Two Modes of Asymmetric Polymerization of Phenylacetylenes Having an L-Amino Alcohol Residue and Two Hydroxy Groups (2012)
  • Author(s): Hongge Jia, Yu Zang, Jun Li, Toshiki Aoki,* Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. Volume: 50 Issue: 24 Pages: 5134-5143
  • DOI: 10.1002/pola.26346
  • Peer Reviewed
• [Journal Article] Polymerization of Phenylacetylene-Based Monodendrons with Alkoxy Peripheral Groups, and Oxygen/Nitrogen Permeation Behavior of Their Membranes (2012)
  • Author(s): 金子隆司
  • Journal Title: Int.J.Polym.Sci. Volume: ID 974204 Pages: 1-8
  • DOI: 10.1155/2012/974204
  • Peer Reviewed
• [Journal Article] Helix-Sense-Selective Polymerization of Achiral Phenylacetylenes with Two N-Alkylamide Groups to Generate the One-Handed Helical Polymers Stabilized by Intramolecular Hydrogen Bonds (2012)
  • Author(s): Masahiro Teraguchi,* Daisuke Tanioka, Takashi Kaneko, Toshiki Aoki
  • Journal Title: Macro. Lett. Volume: 1 Issue: 11 Pages: 1258-1261
  • DOI: 10.1021/mz300309c
  • Peer Reviewed
• [Journal Article] Enhanced Gas Permselectivity of Copoly(Hyperbranched Macromonomer) Synthesized by One-pot Simultaneous Copolymerization of Dimethylsilyl-containing Phenylacetylenes (2012)
  • Author(s): Jun Li, Jianjun Wang, Yu Zang, Toshiki Aoki,* Takashi Kaneko, Masahiro Teraguchi
  • Journal Title: Chemistry Letters Volume: 41 Issue: 11 Pages: 1462-1464
  • DOI: 10.1246/cl.2012.1462
  • NAID: 10031126564
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] Synthesis of stable and soluble one-handed helical poly(substituted acetylene)s without chiral pendant groups via polymer reaction in membrane state (2012)
  • Author(s): Yunosuke Abe, Toshiki Aoki,* Hongge Jia, Shingo Hadano, Takeshi Namikoshi, Yuriko Kakihana, Lijia Liu, Yu Zang, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: POLYMER Volume: 53 Issue: 11 Pages: 2129-2133
  • DOI: 10.1016/j.polymer.2012.03.022
  • Peer Reviewed
• [Journal Article] Pseudo helix-sense-selective polymerization of achiral substituted acetylenes (2012)
  • Author(s): Yu Zang, Toshiki Aoki,* Lijia Liu, Yunosuke Abe, Yuriko Kakihana, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Chem. Commun. Volume: 48 Pages: 4761-4763
  • Peer Reviewed
• [Presentation] Unusual Phenomenon in Helix-Sense-Selective Polymerization-Control of the Helical Sense of Polyphenylacetylenes by Changing an Achiral Condition (2013)
  • Author(s): Geng Zhang, Sawa Taguchi, Masahiro Teraguchi, Takashi Kaneko and Toshiki Aoki*
  • Organizer: The 13th Pacific Polymer Conference (PPC 2013)
  • Place of Presentation: Kaohsiung, Taiwan
  • Year and Date: 2013-11-19
• [Presentation] ビフェニル基を有する3, 5-ビス(ヒドロキシメチル)フェニルアセチレンのらせん選択重合とそのポリマーの蛍光特性 (2013)
  • Author(s): 金子隆司, 時志春, 村山善則, 寺口昌宏, 青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢(金沢大学 角間キャンパス)
  • Year and Date: 2013-09-13
• [Presentation] 低分子量体を用いた超高分子量シス-シソイダルポリフェニルアセチレン片巻きらせん選択重合体の分子構造の解明 (2013)
  • Author(s): 筒場豊和, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢(金沢大学 角間キャンパス)
  • Year and Date: 2013-09-12
• [Presentation] ポリフェニルアセチレンのらせん選択重合におけるらせん巻き方向のアキラル条件による制御 (2013)
  • Author(s): 張耿, 田口紗和, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢(金沢大学 角間キャンパス)
  • Year and Date: 2013-09-11
• [Presentation] らせん選択重合により得られたシス-シソイダルポリフェニルアセチレンを鋳型としたADMET後重合によるマルチストランドポリマーの合成 (2013)
  • Author(s): 松井香奈, 棚木宏幸, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢(金沢大学 角間キャンパス)
  • Year and Date: 2013-09-11
• [Presentation] かさ高い置換基を持つアキラルな置換アセチレンのリビング的らせん選択重合 (2013)
  • Author(s): 中尾和樹, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都(京都国際会議場)
  • Year and Date: 2013-05-31
• [Presentation] ビニル基をペンダントに持つらせん選択重合体を鋳型としたリボン, カラム, あるいはシート状特殊構造高分子の合成 (2013)
  • Author(s): 棚木宏幸, 松井香奈, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都(京都国際会議場)
  • Year and Date: 2013-05-29
• [Presentation] ポルフィリンまたは亜鉛ポルフィリン部位と2 つの水酸基を有するフェニルアセチレンのらせん選択重合 (2013)
  • Author(s): 西村卓浩, 寺口昌宏, 名畑信之, 金子隆司, 青木俊樹
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都(京都国際会議場)
  • Year and Date: 2013-05-29
• [Presentation] Pseudo helix-sense-selective polymerization of achiral substituted acetylenes - A new concept and its realization -/ (2012)
  • Author(s): 藏雨, 劉立佳, 垣花百合子, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-31
• [Presentation] 円偏光によるらせんポリ置換アセチレン膜のらせん巻き方向選択的光分解反応 (2012)
  • Author(s): 遠藤大慶, 寺口昌宏, 安部佑之介, 垣花百合子, 劉立佳, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-30
• [Presentation] ビニル基を有するポリフェニルアセチレンの後重合によるヘテロラダーポリマーの合成とキャラクタリゼーション (2012)
  • Author(s): 棚木宏幸, 垣花百合子, 劉立佳, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-30
• [Presentation] 水酸基を2つ有する置換アセチレンのらせん選択重合および生成シス-シソイダルポリマーの選択的環化芳香族分解の分子設計を用いた反応機構の提案 (2012)
  • Author(s): 和須津郁弥, 安部佑之介, 菊地一智, 藏雨, 劉立佳, 垣花百合子, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-29
• [Presentation] 置換アセチレンのらせん選択重合(HSSP)の種々の特異な挙動と機構-アキラル制御HSSP, 絶対HSSP, 自己HSSP, 不斉増幅HSSP と機構解明 (2012)
  • Author(s): 菊地一智, 田口紗和, 和須津郁弥, 大石智之, 劉立佳, 垣花百合子, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-29
• [Presentation] フェノキシラジカルを有するポリ(1, 2-フェニレンエチニレン-1, 2-フェニレンビニレン)のらせんフォルダマー形成における溶媒効果 (2012)
  • Author(s): 富樫勇太, 劉立佳, 垣花百合子, 寺口昌宏, 青木俊樹, 金子隆司
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-29
• [Presentation] 超分子前駆体よりの可溶性ポリシルセスキオキサンのラダー構造の完全性と気体選択透過性との関係 (2012)
  • Author(s): 加藤史也, 垣花百合子, 金子匠, 劉立佳, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-29
• [Presentation] Highly selective cycloaromatization of cross-linked helical polyphenylacetylenes for preparation of novel 2D polymer membranes (2012)
  • Author(s): 劉立佳, 宮田真理, 垣花百合子, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-29
• [Presentation] シス-シソイダル片巻きポリ置換フェニルアセチレン膜の光高選択トポケミカル環化芳香族化分解反応の機構 (2012)
  • Author(s): 安部佑之介, 和須津郁弥, 垣花百合子, 劉立佳, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2012-05-29
• [Presentation] Synthesis of chiral polyphenylacetylenes having one-handed helical backbone without any other chiral moieties (2012)
  • Author(s): Yu Zang, Lijia Liu, Masahiro Teraguchi, Takashi Kaneko, and Toshiki Aoki*
  • Organizer: International Chiral Meeting (ICM 2012)
  • Place of Presentation: Zhangjiajie, China
  • Invited
• [Presentation] Mechanism of Highly Selective Photocyclicaromatization(SCAT) of Cis-Cisoidal Helical Poly (phenylacetylene)s in Membrane State FOR Petit Top-Down Preparation of Self-Supporting Supramolecular Polymeric Membranes (2012)
  • Author(s): Yu Zang, Yunosuke Abe, and Toshiki Aoki*
  • Organizer: The 44th International Symposium on Macromolecules (MACRO 2012) _ IUPAC World Polymer Congress
  • Place of Presentation: Blacksburg, Virginia, USA
  • Invited
• [Presentation] Pseudo helix-sense-selective polymerization of achiral phenylacetylene (2012)
  • Author(s): Yu Zang, Lijia Liu, Masahiro Teraguchi, Takashi Kaneko and Toshiki Aoki*
  • Organizer: International Chiral Meeting (ICM 2012)
  • Place of Presentation: Zhangjiajie, China
• [Presentation] Helix-sense-selective polymerization of achiral phenylacetylene having two bulky imino substituents (2012)
  • Author(s): Yu ZANG, Masahiro Teraguchi, Takashi Kaneko and Toshiki Aoki*
  • Organizer: The 44th International Symposium on Macromolecules (MACRO 2012) _ IUPAC World Polymer Congress
  • Place of Presentation: Blacksburg, Virginia, USA
• [Presentation] MECHANISM OF HIGHLY SELECTIVE PHOTOCYCLICAROMATIZATION(SCAT) OF CIS-CISOIDAL HELICAL POLY (PHENYLACETYLENE)S IN MEMBRANE STATE FOR PETIT TOP-DOWN PREPARATION OF SELF-SUPPORTING SUPRAMOLECULAR POLYMERIC MEMBRANE (2012)
  • Author(s): Yu ZANG, Yunosuke ABE, and Toshiki AOKI*
  • Organizer: The 44th International Symposium on Macromolecules (MACRO 2012) _ IUPAC World Polymer Congress
  • Place of Presentation: Blacksburg, Virginia, USA
  • Invited
• [Presentation] Helix-sense-selective polymerization of achiral phenylacetylene having two bulky imino substituents (2012)
  • Author(s): Yu ZANG, Masahiro Teraguchi, Takashi Kaneko and Toshiki AOKI*
  • Organizer: The 44th International Symposium on Macromolecules (MACRO 2012) _ IUPAC World Polymer Congres
  • Place of Presentation: Blacksburg, Virginia, USA
• [Presentation] 2 つの水酸基を持つアキラルなフェニルアセチレンモノマーのキラル触媒系を用いたらせん選択重合の高度化 (2011)
  • Author(s): 菊地一智, 大石智之, 垣花百合子, 寺口昌宏, 金子隆司, 青木俊樹
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山
  • Year and Date: 2011-09-28
• [Presentation] 2つの水酸基を持つアキラルなフェニルアセチレンモノマーのキラル触媒系を用いたらせん選択重合の高度化 (2011)
  • Author(s): 菊地一智、大石智之、垣花百合子、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
• [Presentation] Unusual Phenomenon in Helix-Sense-Selective Polymerization-Control of the Helical Sense of Polyphenylacetylenes by Changing an Achiral Condition
  • Author(s): Geng Zhang, Sawa Taguchi, Masahiro Teraguchi, Takashi Kaneko and Toshiki Aoki
  • Organizer: The 13th Pacific Polymer Conference (PPC 2013)
  • Place of Presentation: Kaohsiung, Taiwan
• [Presentation] ポリフェニルアセチレンのらせん選択重合におけるらせん巻き方向のアキラル条件による制御
  • Author(s): 張耿、田口紗和、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス
• [Presentation] らせん選択重合により得られたシス-シソイダルポリフェニルアセチレンを鋳型としたＡＤＭＥＴ後重合によるマルチストランドポリマーの合成
  • Author(s): 松井香奈、棚木宏幸、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス
• [Presentation] 低分子量体を用いた超高分子量シス-シソイダルポリフェニルアセチレン片巻きらせん選択重合体の分子構造の解明
  • Author(s): 筒場豊和、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス
• [Presentation] ビフェニル基を有する3,5-ビス(ヒドロキシメチル)フェニルアセチレンのらせん選択重合とそのポリマーの蛍光特性
  • Author(s): 金子隆司、時志春、村山善則、寺口昌宏、青木俊樹
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学 角間キャンパス
• [Presentation] ビニル基をペンダントに持つらせん選択重合体を鋳型としたリボン、カラム、あるいはシート状特殊構造高分子の合成
  • Author(s): 棚木宏幸、松井香奈、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都国際会議場
• [Presentation] ポルフィリンまたは亜鉛ポルフィリン部位と2つの水酸基を有するフェニルアセチレンのらせん選択重合
  • Author(s): 西村卓浩、寺口昌広、名畑信之、金子隆司、青木俊樹
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都国際会議場
• [Presentation] かさ高い置換基を持つアキラルな置換アセチレンのリビング的らせん選択重合
  • Author(s): 中尾和樹、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都国際会議場
• [Presentation] シス-シソイダル片巻きポリ置換フェニルアセチレン膜の光高選択トポケミカル環化芳香族化分解反応の機構
  • Author(s): 安部佑之介、和須津郁弥、垣花百合子、劉立佳、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] Highly selective cycloaromatization of cross-linked helical polyphenylacetylenes for preparation of novel 2D polymer membranes
  • Author(s): 劉立佳、宮田真理、垣花百合子、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] 超分子前駆体よりの可溶性ポリシルセスキオキサンのラダー構造の完全性と気体選択透過性との関係
  • Author(s): 加藤史也、垣花百合子、金子匠、劉立佳、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] フェノキシラジカルを有するポリ(1,2-フェニレンエチニレン-1,2-フェニレンビニレン)のらせんフォルダマー形成における溶媒効果
  • Author(s): 富樫勇太、劉立佳、垣花百合子、寺口昌宏、青木俊樹、金子隆司
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] 置換アセチレンのらせん選択重合(HSSP)の種々の特異な挙動と機構－アキラル制御HSSP、絶対HSSP、自己HSSP、不斉増幅HSSPと機構解明
  • Author(s): 菊地一智、田口紗和、和須津郁弥、大石智之、劉立佳、垣花百合子、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] 水酸基を２つ有する置換アセチレンのらせん選択重合および生成シス－シソイダルポリマーの選択的環化芳香族分解の分子設計を用いた反応機構の提案
  • Author(s): 和須津郁弥、安部佑之介、菊地一智、藏雨、劉立佳、垣花百合子、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] 棚木宏幸、垣花百合子、劉立佳、寺口昌宏、金子隆司、青木俊樹
  • Author(s): ビニル基を有するポリフェニルアセチレンの後重合によるヘテロラダーポリマーの合成とキャラクタリゼーション
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] 円偏光によるらせんポリ置換アセチレン膜のらせん巻き方向選択的光分解反応
  • Author(s): 遠藤大慶、寺口昌宏、安部佑之介、垣花百合子、劉立佳、金子隆司、青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] Pseudo helix-sense-selective polymerization of achiral substituted acetylenes - A new concept and its realization -
  • Author(s): 藏雨、劉立佳、垣花百合子、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Book] 化学便覧応用化学編第7版II, 1.高分子分離膜, a.気体分離膜, (ii)特殊構造高分子膜, 日本化学会編 (2013)
  • Author(s): 青木俊樹*, 寺口昌宏, 金子隆司
  • Publisher: 丸善
• [Book] 化学便覧応用化学編第7版II, 1.高分子分離膜, c.光学分割膜, 日本化学会編 (2013)
  • Author(s): 青木俊樹*, 寺口昌宏, 金子隆司
  • Total Pages: 1903
  • Publisher: 丸善
• [Book] 化学便覧応用化学編第７版II (2013)
  • Author(s): 青木俊樹・寺口昌宏・金子隆司
  • Publisher: 丸善
• [Book] 未来材料 (2013)
  • Author(s): 青木俊樹、藏雨、宮田 真理、棚木宏幸、中尾和樹、王建军、寺口昌宏
  • Total Pages: 8
  • Publisher: （株）エヌ・ティー・エス
• [Remarks]
  • URL: http://www.gs.niigata-u.ac.jp/~kantak00/AokenHP/JpnTop.htm
• [Remarks] 機能性高分子合成研究室 －青木・金子・寺口研究室－
  • URL: http://www.gs.niigata-u.ac.jp/~kantak00/AokenHP/JpnTop.htm
• [Remarks] 機能性高分子合成研究室-青木・金子・寺口研究室-
  • URL: http://www.gs.niigata-u.ac.jp/~kantak00/AokenHP/List.htm