Living Radical Polymerization of Non-Radically Polymerizable Monomers
| Project/Area Number |
23655102
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | University of Fukui |
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Principal Investigator |
SUGIHARA Shinji 福井大学, 大学院・工学研究科, 准教授 (70377472)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | リビングラジカル重合 / リビングカチオン重合 / ビニルエーテル / RAFT / 極性変換 / 高分子合成 / 精密重合 / ラジカル重合 / カチオン重合 / RAFT重合 / 塊状重合 |
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| Research Abstract |
Vinyl ethers cannot be inherently polymerized via radical mechanism. In contrast, the vinyl ethers can be polymerized into high molecular weight products only by cationic polymerizations. The cationic polymerization is known to be influenced by the presence of nucleophiles such as water and monomer with a hydroxyl group. However, the vinyl ether with a hydroxyl group is an interesting monomer with the potential to polymerize by radical process. This is because the electron density of the vinyl moiety in vinyl ethers is changed by the hydrogen bonding between the hydroxyl group and the ether of the monomer. Thus, direct radical polymerization using the vinyl ether having a hydroxyl group was investigated in this project as the basis of precision radical polymerization of non-radically polymerizable monomers.
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Report
(3 results)
Research Products
(20 results)
