• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Molecular motors based on stochastic resonance

Research Project

Project/Area Number 23655109
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionHokkaido University

Principal Investigator

NAKAMURA Takayoshi  北海道大学, 電子科学研究所, 教授 (60270790)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords分子ローター / 一方向回転 / クラウンエーテル / 超分子
Research Abstract

Introduction of saw-tooth type potential for a unidirectional rotation was investigated toward the realization of Brownian-Ratchet mechanism. Chiral crown ether was introduced in the crystal so that it produces saw-tooth potential for molecular rotator. Functions associated with the structure were examined. We synthesized trans-syn-trans-dicyclohexano[18]crown-6 and prepared racemic crystals. In the crystal, the crown ether took a favorable conformation for produce saw-tooth type potential. The 4-aminopyridinium salt showed a hysteresis in the temperature dependent dielectric constants.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (37 results)

All 2015 2014 2013 2012 2011

All Journal Article (27 results) (of which Peer Reviewed: 27 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Invited: 7 results)

  • [Journal Article] Gold nanoparticle assemblies stabilized by bis(phthalocyaninato)lanthanide(III) complexes through van der Waals interactions2015

    • Author(s)
      Yuki Noda, Shin-ichiro Noro, Tomoyuki Akutagawa, and Takayoshi Nakamura
    • Journal Title

      Scientific Reports

      Volume: 4 Issue: 1 Pages: 3758-3758

    • DOI

      10.1038/srep03758

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Design of Crystalline Spaces for Molecular Rotations in Crystals2014

    • Author(s)
      Z. Q. Liu, K. Kubo, S. Noro, T. Akutagawa and T. Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 2 Pages: 537-543

    • DOI

      10.1021/cg4013262

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Motion in Pyridazinium/Crown Ether Supramolecular Cation Salts of a Nickel Dithiolene Complex2013

    • Author(s)
      Zun-qi Liu, Li Lin, Kazuya Kubo, Nirihisa Hoshino, Shin-ichiro Noro, Tomoyuki Akutagawa,* Takayoshi Nakamura
    • Journal Title

      Dalton Transactions

      Volume: 42 Issue: 8 Pages: 2930-2939

    • DOI

      10.1039/c2dt32542j

    • NAID

      120005350087

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] (3-Fluoro-4-methoxy-anilinium+)([18]Crown-6) Supramolecular Cation Salt of Ferromagnetic [MnIICrIII (oxalate)3]2013

    • Author(s)
      Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagawa, and Takayoshi Nakamura
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 2 Pages: 137-139

    • DOI

      10.1246/cl.2013.137

    • NAID

      130004426850

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure of a Supramolecular Cation Salt: (adamantylammonium+)2(benzo[18]crown-6)2[Pd(dmit)2]2-(acetone)22013

    • Author(s)
      Kazuya Kubo, Yin-Nan Yan, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Inorganica Chimica Acta

      Volume: 404 Pages: 206-209

    • DOI

      10.1016/j.ica.2013.02.018

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric and Structural Phase Transition of [Ni(dmit)2]- Salt with (4-ethoxyanilinium)([18]crown-6) Supramolecular Cation2013

    • Author(s)
      Q. Ye, P. P. Shi, X. Q. Fu, T. Akutagawa and T. Nakamura
    • Journal Title

      CrystEngCommun

      Volume: 15 Issue: 26 Pages: 5307-5313

    • DOI

      10.1039/c3ce40220g

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecule-Displacive Ferroelectricity in Organic Supramolecular Solids2013

    • Author(s)
      H. Ye, Y. Zhang, S. Noro, K. Kubo, M. Yoshitake, Z. Liu, H. Cai, D. Fu, H. Yoshikawa, K. Awaga, R. G. Xiong and T. Nakamura
    • Journal Title

      Scientific Reports

      Volume: 3 Issue: 1 Pages: 2249-2249

    • DOI

      10.1038/srep02249

    • NAID

      120006795651

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Motions and Hydrogen-Bonding Networks in (o-Aminoanilinium)-(Crown Ethers)-[PMo_<12>O_<40>]^42012

    • Author(s)
      Daigoro Endo, Tomoyuki Akutagawa, Kazuya Kubo, Shin-ichiro Noro, Leroy Cronin, Takayoshi Nakamura
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 85 Issue: 3 Pages: 305-315

    • DOI

      10.1246/bcsj.20110371

    • NAID

      130004153043

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] [Ni(dmit)2]- Salt with Flexible Supramolecular Cation Rotator2012

    • Author(s)
      Q. Ye, P. P. Shi, Z. Q. Chen, T. Akutagawa, S. Noro, and T. Nakamura
    • Journal Title

      Inorg. Chem. Commun.

      Volume: 20 Pages: 219-224

    • DOI

      10.1016/j.inoche.2012.03.012

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cation-Anion Packing and Molecular Motion in (m-Fluoroanilinium)(dibenzo[18]crown-6)[Ni(mnt)2]-(CH3CN)0.25 Crystals2012

    • Author(s)
      Kiyonori Takahashi, Norihisa Hoshino, Kazuya Kubo, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      CrystEngComm.

      Volume: 14 Issue: 16 Pages: 5235-5241

    • DOI

      10.1039/c2ce25493j

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Flexible cis-Cyclohexane-1,4-diammonium in Magnetic [Ni(dmit)_2] Crystals2012

    • Author(s)
      Qiong Ye, Ping-Ping Shi, Zi-Qi Chen, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: (未定)(印刷中) Issue: 23 Pages: 3732-3739

    • DOI

      10.1002/ejic.201200099

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Rotators of (Aniliniums)([18]crown-6) in Electrically Conducting [Ni(dmit)2] Crystals,2012

    • Author(s)
      Norihisa Hoshino, Yuuya Yoshii, Kazuya Kubo, Masaki Aonuma, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      Inorganic Chemistr

      Volume: 51 Issue: 23 Pages: 12968-12975

    • DOI

      10.1021/ic302093b

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal Structures and Magnetic Properties of (4,4'-Phenylazophenyl)-diammonium(Crown ethers)[Ni(dmit)2]2 Crystals2012

    • Author(s)
      Norihisa Hoshino, Kazuya Kubo, Takayoshi Nakamura, and Tomoyuki Akutagawa
    • Journal Title

      Dalton Transactions

      Volume: 41 Issue: 31 Pages: 12968-12975

    • DOI

      10.1039/c2dt30807j

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Incorporation of Cationic Electron Donor of Ni-pyridyltetrathiafulvalene with Anionic Electron Acceptor of Polyoxometalate2012

    • Author(s)
      Ryo Tsunashima, Takumi Matsumoto, Kei Kondo, Yoshihiko Suyama, Yukihiro Nishioka, Jun Kawamata, Shin-ichiro Noro, Takayoshi Nakamura, Tomoyuki Akutagawa , Katsuya Ishiguro
    • Journal Title

      Dalton Transactions.

      Volume: 41 Issue: 33 Pages: 10060-10064

    • DOI

      10.1039/c2dt30398a

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Crystal Structure of a One-dimensional Cu(II) Coordination Polymer Bridged by Inorganic CH3SO3- Anions Using Werner-type Cu(II) Complexes as Building Blocks2012

    • Author(s)
      S. Noro, K. Kubo and T. Nakamura
    • Journal Title

      Chem. Lett. 41

      Volume: 41 Issue: 8 Pages: 772-773

    • DOI

      10.1246/cl.2012.772

    • NAID

      130004426636

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Crystal Structure, and Adsorption Properties of Werner-type Cu(II) Complex [Cu(CF3SO3)2(4-methylpyridine)4]2012

    • Author(s)
      S. Noro, K. Fukuhara, K. Kubo and T. Nakamura
    • Journal Title

      Chem. Lett.

      Volume: 41 Issue: 10 Pages: 1314-1316

    • DOI

      10.1246/cl.2012.1314

    • NAID

      130004426366

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Phase Transition Induced by Molecular Motions within a (Anilinium)(L-Tartarate) Ionic Molecular Crystal2012

    • Author(s)
      Yuuya Yoshii, Norihisa Hoshino, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      CrystEngComm.

      Volume: 14 Issue: 21 Pages: 7458-7465

    • DOI

      10.1039/c2ce25945a

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Highly Selective CO2 Adsorption Accompanied with Low-Energy Regeneration in a Two-Dimensional CU(II) Porous Coordination Polymer with Inorganic Fluoriuated PF6- Anions2012

    • Author(s)
      S. Noro, T. Fukushima, S. Kitagawa, T. Nakamura, 他
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 1 Pages: 280-285

    • DOI

      10.1021/ic301823j

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Exploring the Thermochromism of Sulfite-embedded Polyoxometalate Capsules2011

    • Author(s)
      Ryo Tsunashima, De Liang Long, Toru Endo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura, Raul Quesada Cabrera, Paul F.McMillan, Paul Kogerler, Leroy Cronin
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 13 Issue: 16 Pages: 7295-7297

    • DOI

      10.1039/c1cp20074g

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-bonded Assemblies of Two-Electron Reduced Mixed-Valence [XMo_<12>O_<40>] (X=P and Si) with p-Phenylenediamines2011

    • Author(s)
      Tomoyuki Akutagawa, Fumito Kudo, Ryo Tsunashima, Shin-ichiro Noro; Leroy Cronin, Takayoshi Nakamura
    • Journal Title

      Inorganic Chemistry

      Volume: 50 Issue: 14 Pages: 6711-6718

    • DOI

      10.1021/ic200683e

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polymornhs and-Structural Phase Transition of [Ni(dmit_2)]^-Crystals Induced by Flexible (trans-Cyclohexane-1,4-diammonium)(Benzo[18]crown-6)_2 Supramolecule2011

    • Author(s)
      Qiong Ye, Tomoyuki Akutagawa, Nonhisa Hoshino, Takemitsu Kikuchi, Shin-ichiro Noro, Ren Gen Xiong, Takayoshi Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 11 Issue: 9 Pages: 4175-4182

    • DOI

      10.1021/cg2007556

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 4-(cyanomethyl) anilinium Perchlorate : A New Displacive-Type Molecular Ferroelectric2011

    • Author(s)
      Hong-Ling Cai, Wen Zhang, Jia-Zhen Ge, Yi Zhang, Kunio Awaga, Takayoshi Nakamura, Ren Gen
    • Journal Title

      Phys.Rev.Lett.

      Volume: 107 Issue: 14 Pages: 147-601

    • DOI

      10.1103/physrevlett.107.147601

    • NAID

      120006795654

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Phase Transition Due to the Flexible Supramolecule of (4-cyanomethylanilinium) ([18]crown-6) in [Ni(dmit)2]-Crystal2011

    • Author(s)
      Qiong Ye, Tomoyuki Akutagawa, Heng Yun Ye, Tian Hang, Jia Zhen Ge, Ren-Gen Xiong, Shin-ichiro Noro, Takayoshi Nakamura
    • Journal Title

      Cryst.Eng.Commun.

      Volume: 13 Issue: 20 Pages: 6185-6191

    • DOI

      10.1039/c1ce05581j

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Huge Dielectric Response and Molecular Motions in Paddle-Wheel [CuII2(Adamantylcarboxylate)4(DMF)2]・(DMF)22011

    • Author(s)
      Qiong Ye, Kiyonori Takahashi, Norihisa Hoshino, Takemitsu Kikuchi, Tomoyuki Akutagawa, Shin-ichiro Noro, Sadamu Takeda, Takayoshi Nakamura
    • Journal Title

      Chem.Eur.J.

      Volume: 17 Issue: 51 Pages: 14442-14449

    • DOI

      10.1002/chem.201101743

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Supramolecular cations of the m-fluoroanilinium(dibenzo[18]crown-6) in ferromagnetic salt2011

    • Author(s)
      Toru Endo, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura
    • Journal Title

      Dalton Transaction

      Volume: 40 Issue: 7 Pages: 1491-1496

    • DOI

      10.1039/c0dt01140a

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Diverse structures and adsorption properties of quasi-Werner-type copper (II) complexes2011

    • Author(s)
      Shin-ichiro Noro, Tomonori Ohba, Katsuo Fukuhara, Yukiko Takahashi, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Dalton Transactions

      Volume: 40 Issue: 10 Pages: 2268-2274

    • DOI

      10.1039/c0dt01129k

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer2011

    • Author(s)
      S.Noro, K.Fukuhara, K.Kubo, T.Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 11 Issue: 6 Pages: 2379-2385

    • DOI

      10.1021/cg2001392

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Dielectrics based on Supramolecular Rotator Units in Single Crystals2014

    • Author(s)
      T. Nakamura
    • Organizer
      Symposium on Molecular Science and Synthesis of Functional Molecules for Next Generation
    • Place of Presentation
      Hiroshima
    • Year and Date
      2014-03-10
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Dielectrics based on Supramolecular Rotator Units in Single Crystals2014

    • Author(s)
      T. Nakamura
    • Organizer
      Symposium on Molecular Science and Synthesis of Functional Molecules for Next Generation
    • Place of Presentation
      広島大学 (広島県)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Supramolecular Rotators for Ferroelectrics and Multiferroics2013

    • Author(s)
      T. Nakamura, S. Yoshitake, K. Kubo, S. Noro and T. Akutagawa
    • Organizer
      The 15th Asian Chemical Congress, Sentosa
    • Place of Presentation
      Singapore
    • Year and Date
      2013-08-21
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Supramolecular Rotators for Ferroelectrics and Multiferroics2013

    • Author(s)
      T. Nakamura, S. Yoshitake, K. Kubo, S. Noro and T. Akutagawa
    • Organizer
      The 15th Asian Chemical Congress
    • Place of Presentation
      Resorts World Sentosa (Sentosa, Singapore)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Molecular Multiferroics Based on Supramolecular Rotators2012

    • Author(s)
      T. Nakamura, M. Yoshitake, K. Kubo and S. Noro
    • Organizer
      8th IUPAC International Conference on Novel Materials and their Synthesis (NMS-VIII) & 22nd International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      Xi'an, China
    • Year and Date
      2012-10-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Molecular Multiferroics Based on Supramolecular Rotators2012

    • Author(s)
      T. Nakamura, M. Yoshitake, K. Kubo and S. Noro
    • Organizer
      8th IUPAC International Conference on Novel Materials and their Synthesis (NMS-VIII) & 22nd International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      西北大学・西安・中国
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Ferroelectrics and Multiferroics based on Supramolecular Rotators2011

    • Author(s)
      T. Nakamura
    • Organizer
      the third RIES-CIS Symposium
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2011-10-28
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Organic‐Inorganic Hybrid Systems toward " Dynamic" Functional Materials2011

    • Author(s)
      T. Nakamura
    • Organizer
      1st Discussion Symposium on 'Inorganic Biology and Protocells : Engineering Artificial Life'
    • Place of Presentation
      Glasgow, UK
    • Year and Date
      2011-09-09
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Organic‐Inorganic Hybrid Systems toward"Dynamic" Functional Materials2011

    • Author(s)
      Takayoshi Nakamura
    • Organizer
      1st Discussion Symposium on‘Inorganic Biology and Protocells: Engineering Artificial Life’(招待講演)
    • Place of Presentation
      University of Glasgow (UK)
    • Related Report
      2011 Research-status Report
  • [Presentation] Ferroelectrics and Multiferroics based on Supramolecular Rotators2011

    • Author(s)
      Takayoshi Nakamura
    • Organizer
      the third RIES-CIS Symposium(招待講演)
    • Place of Presentation
      National Chiao Tung University (Taiwan)
    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi