Functionalization of crystalline channels with multiple recognition sites
| Project/Area Number |
23655117
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | The University of Tokyo |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
|---|
| Keywords | 多孔性結晶 / 自己集合 / 超分子 / 大環状金属錯体 / ホスト・ゲスト化学 / X線構造解析 / 分子認識 / 機能性結晶 / 超分子金属錯体 / 不斉結晶化 |
|---|
| Research Abstract |
It was found in this study that trinuclear Pd complexes of a macrocyclic N6-type ligand simultaneously form four kinds of conformational and stereo isomers in solution and that self-assembly of these isomers results in crystalline nanochannel structure of ca. 2 nm diameter. In the channel, five enantio-paired pockets and various types of hydrogen bonding sites are arranged. In the guest adsorption experiments, a single-crystal was soaked in a guest solution for a given time, and then the position and adsorption patterns of the guest was determined by single-crystal X-ray structural analysis. This method has revealed the adsorption positions of many types of aromatic compounds, metal catalysts, and bio-related compounds, which allowed adsorption mapping. Moreover, simultaneous site-selective adsorption of different multiple guests has been achieved and further developed to multicomponent intermolecular reactions in the channel.
|
Report
(4 results)
Research Products
(14 results)
