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Development of Light-driven Crystal Machinery

Research Project

Project/Area Number 23655129
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionEhime University

Principal Investigator

KOSHIMA Hideko  愛媛大学, 理工学研究科, 教授 (20304644)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords分子機械 / 分子結晶 / メカニカル機能
Research Abstract

Construction of crystal machinery was studied by utilizing photomechanical crystals, which exhibit photomechanical bending motion upon photoirradiation. However, it is impractical to use one piece of a single crystal as a crystal machine due to insufficient durability. A composite of single crystals with some soft materials such as polymers may increase the possibility for mechanical devices. Silicone polymer films in which plate-like chiral and achiral crystals of salicylidenephenylethylamines were aligned by a magnetic field were prepared. Further, rubbing of the surface of liquid resin suspension also gave alignment of crystals. The polymer films exhibited reversible photomechanical bending upon alternate irradiation with UV and visible light. In conclusion, element technology was developed to make crystal machinery.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (57 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (38 results) (of which Invited: 4 results) Book (6 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Absolute Asymmetric Photocyclization of Triisopropylbenzophenone Derivatives in Crystals and Their Morphological Changes2014

    • Author(s)
      Hideko Koshima, Michitaro Fukano, Naoko Ojima, Kohei Johmoto, Hidehiro Uekusa, M. Shiro
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 79 Issue: 7 Pages: 3088-3093

    • DOI

      10.1021/jo5000913

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Light-driven Bending of Polymer Films in Which Salicylidenephenylethylamine Crystals are Aligned Magnetically2013

    • Author(s)
      Hideko Koshima, Masafumi Matsudomi, Yutaro Uemura, Fumiko Kimura, Tsunehisa Kimura
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 12 Pages: 1517-1519

    • DOI

      10.1246/cl.130797

    • NAID

      130004867853

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Light-Driven Bending Crystals of Salicylidenephenylethylamines in Enantiomeric and Racemate Forms132013

    • Author(s)
      Hideko Koshima, Risa Matsuo, Masafumi Matsudomi, Yutaro Uemura, Motoo Shiro
    • Journal Title

      Crystal Growth & Design

      Volume: 13 Issue: 10 Pages: 4330-4337

    • DOI

      10.1021/cg400675r

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] An Application of the Advanced High-accuracy Universal Polarimeter to the Chiroptical Measurement of a Intercalated Compound K4Nb6O17 with High Anisotropy2012

    • Author(s)
      Masahito Tanaka
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 45 Issue: 17 Pages: 175303-175303

    • DOI

      10.1088/0022-3727/45/17/175303

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photomechanical Motion of Furylfulgide Crystals2012

    • Author(s)
      Hideko Koshima, Hidemitsu Nakaya, Hidetaka Uchimoto, Naoko Ojima
    • Journal Title

      Chemistry Letters

      Volume: 41 Issue: 1 Pages: 107-109

    • DOI

      10.1246/cl.2012.107

    • NAID

      10030222801

    • Related Report
      2013 Final Research Report 2012 Research-status Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photomechanical Bending of 4-Aminoazobenzene Crystals2012

    • Author(s)
      Hideko Koshima
    • Journal Title

      Dyes & Pigments

      Volume: 92 Issue: 2 Pages: 798-801

    • DOI

      10.1016/j.dyepig.2011.05.003

    • Related Report
      2013 Final Research Report 2012 Research-status Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photomechanical Motion of Salicylideneaniline Microcrystals2011

    • Author(s)
      Hideko Koshima, Kyoko Takechi, Hidetaka Uchimoto, Motoo Shiro, Daisuke Hashizume
    • Journal Title

      Chemical Communications

      Volume: Vol. 47 Pages: 11423-11425

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Metastable Polymorphic Form of Isopropylbenzophenone Derivative Directly Obtained by the Solid-state Photoreaction Investigated by ab initio Powder X-ray Diffraction Analysis2011

    • Author(s)
      Kotaro Fujii
    • Journal Title

      CrystEngComm

      Volume: 13 Issue: 9 Pages: 3197-3201

    • DOI

      10.1039/c0ce00500b

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photomechanical Motion of Salcylideneaniline Microcrystals2011

    • Author(s)
      H. Koshima, K. Takechi
    • Journal Title

      Chem. Comm.

      Volume: 47 Pages: 11423-11425

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] フォトメカニカル機能をもつキラルなサリチリデンアニリン結晶の光学的性質2014

    • Author(s)
      高鍋彰文、田中真人、松冨正文、小島秀子、朝日透
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      相模原
    • Related Report
      2013 Annual Research Report
  • [Presentation] キラルアゾベンゼン結晶のフォトメカニカル運動2014

    • Author(s)
      小島秀子、藤澤珠里、松冨正文
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] キラルサリチリデンアニリン複合結晶のフォトメカニカル運動2014

    • Author(s)
      松冨正文、山岡洋平、小島秀子
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] フォトメカニカル結晶配向ポリマー膜の光屈曲2014

    • Author(s)
      小島秀子、水川貴彰、松冨正文
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] ベンゾフェノン結晶の絶対構造と光学活性2014

    • Author(s)
      萩原裕樹、石川和彦、小島秀子、朝日透
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] 有機固体光化学 : 分子の動きから結晶の動きへ2013

    • Author(s)
      小島秀子
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      松山
    • Related Report
      2013 Final Research Report
  • [Presentation] Chiral Solid-state Photochemistry Based on Spontaneous Chiral Crystallization Approach, Keynote Lecture2013

    • Author(s)
      Hideko Koshima
    • Organizer
      25th International Symposium on Chirality (ISCD-25)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2013 Final Research Report
  • [Presentation] Light-Driven Molecular-Crystal Machinery2013

    • Author(s)
      Hideko Koshima, Masafumi Matsudomi
    • Organizer
      Challenges in Organic Materials & Supramolecular Chemistry (ISACS10)
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Annual Research Report
  • [Presentation] Chiral Solid-state Photochemistry Based on Spontaneous Chiral Crystallization Approach2013

    • Author(s)
      Hideko Koshima
    • Organizer
      25th International Symposium on Chirality (ISCD-25)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機固体光化学:分子の動きから結晶の動きへ2013

    • Author(s)
      小島秀子
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] サリチリデンアニリン微結晶の光学的性質とメカニカル機能の関係2013

    • Author(s)
      高鍋彰文、田中真人、松冨正文、小島秀子、朝日透
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光屈曲性サリチリデンアニリン結晶の力学的性質に及ぼす置換基の効果2013

    • Author(s)
      松冨正文、山岡洋平、小島秀子
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
  • [Presentation] フォトメカニカル結晶のポリマー膜へのラビング配向制御2013

    • Author(s)
      小島秀子、松浦大介、水川貴彰、松冨正文
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
  • [Presentation] サリチリデンアニリン多形結晶のフォトクロミズムと光屈曲2013

    • Author(s)
      小島秀子、山岡洋平、松冨正文
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
  • [Presentation] サリチリデンアニリン結晶の光屈曲と力学的性質2013

    • Author(s)
      松冨正文、小島秀子
    • Organizer
      第3回CSJ化学フェスタ
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] フォトメカニカル結晶の集積化2013

    • Author(s)
      小島秀子、水川貴彰、松冨正文
    • Organizer
      第22回有機結晶シンポジウム
    • Place of Presentation
      札幌
    • Related Report
      2013 Annual Research Report
  • [Presentation] スピロピラン擬似多形結晶の光屈曲挙動2013

    • Author(s)
      小島秀子・福山哲也・城始勇
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津、滋賀
    • Related Report
      2012 Research-status Report
  • [Presentation] サリチリデンアニリン系フォトメカニカル結晶のポリマー膜への集積化2013

    • Author(s)
      松冨正文・松浦大輔・小島秀子・木村史子・木村恒久
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津、滋賀
    • Related Report
      2012 Research-status Report
  • [Presentation] 光屈曲性サリチリデンアニリン結晶の力学的特性2013

    • Author(s)
      松冨正文・小島秀子
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津、滋賀
    • Related Report
      2012 Research-status Report
  • [Presentation] サリチリデンアニリン誘導体結晶の光屈曲における置換基効果2013

    • Author(s)
      小島秀子・岡本麻美・松冨正文
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津、滋賀
    • Related Report
      2012 Research-status Report
  • [Presentation] Hideko Koshima, Naoko Ojima, Kyoko Takechi, Hidetaka Uchimoto, Photomechanical Function of Molecular Crystals2012

    • Author(s)
      Hideko Koshima, Naoko Ojima, Kyoko Takechi, Hidetaka Uchimoto
    • Organizer
      7th Asian Photochemistry Conference (APC)
    • Place of Presentation
      Osaka
    • Related Report
      2013 Final Research Report
  • [Presentation] Photomechanical bending of molecular crystals2012

    • Author(s)
      Hideko Koshima, Jun Nakamura, Naoko Ojima, Kyoko Takechi, Hidetaka Uchimoto
    • Organizer
      XXIV IUPAC Symposium on Photochemistry
    • Place of Presentation
      Coimbra, Portugal
    • Related Report
      2013 Final Research Report
  • [Presentation] Photomechanical bending of molecular crystals2012

    • Author(s)
      Hideko Koshima, Jun Nakamura, Naoko Ojima, Kyoko Takechi, Hidetaka Uchimoto
    • Organizer
      XXIV IUPAC Symposium on Photochemistry
    • Place of Presentation
      Coimbra, Portogal
    • Related Report
      2012 Research-status Report
  • [Presentation] アゾベンゼン結晶の配向膜の光メカニカル運動2012

    • Author(s)
      小島秀子・松冨正文・松浦大輔・中村純・木村史子・木村恒久
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] サリチリデンアニリン結晶の磁場配向膜の光屈曲運動2012

    • Author(s)
      小島秀子・植村雄太郎・松冨正文・中村純・木村史子・木村恒久
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] サリチリデンフェニルエチルアミン結晶の磁場配向ポリマー膜の光屈曲運動2012

    • Author(s)
      小島秀子・松冨正文・松浦大輔・中村純・木村史子・木村恒久
    • Organizer
      第21回有機結晶シンポジウム
    • Place of Presentation
      横浜
    • Related Report
      2012 Research-status Report
  • [Presentation] Photomechanical Function of Molecular Crystals2012

    • Author(s)
      Hideko Koshima, Naoko Ojima, Kyoko Takechi, Hidetaka Uchimoto
    • Organizer
      7th Asian Photochemistry Conference (APC2012)
    • Place of Presentation
      Osaka
    • Related Report
      2012 Research-status Report
  • [Presentation] アミノアゾベンゼン類の結晶におけるフォトメカニカル機能とメカニズム2012

    • Author(s)
      中村 純・小島直子・佐藤浩一・小島秀子
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Related Report
      2011 Research-status Report
  • [Presentation] サリチリデンアニリン微結晶の磁場配向ポリマー膜の作製と光屈曲2012

    • Author(s)
      小島秀子・松冨正文・植村雄太郎・中村純・木村史子・木村恒久
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Related Report
      2011 Research-status Report
  • [Presentation] アントリルメチレンインダノン結晶の光屈曲における置換基効果2012

    • Author(s)
      中村 純・石橋禎大・小島秀子
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Related Report
      2011 Research-status Report
  • [Presentation] ミクロの動きからマクロの動きへ2011

    • Author(s)
      小島秀子, キラル結晶
    • Organizer
      The Symposium on Chiral Science & Technology : Mesochemistry & Chemical Wisdom, Waseda University Global COE, 早稲田大学グローバルCOE「実践的化学知」
    • Place of Presentation
      東京
    • Year and Date
      2011-03-02
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 種々のサリチリデンアニリン結晶のフォトメカニカル機能2011

    • Author(s)
      小島秀子・武智恭子・松冨正文・中村 純
    • Organizer
      光化学討論会
    • Place of Presentation
      宮崎
    • Related Report
      2011 Research-status Report
  • [Presentation] アントリルメチレンインダノンにおける結晶の光屈曲特性2011

    • Author(s)
      中村 純・内本英孝・石橋禎大・小島秀子
    • Organizer
      光化学討論会
    • Place of Presentation
      宮崎
    • Related Report
      2011 Research-status Report
  • [Presentation] キラルなサリチリデンアニリン結晶のフォトメカニカル運動2011

    • Author(s)
      松冨正文・松尾理沙・植村雄太郎・中村 純・小島秀子
    • Organizer
      光化学討論会
    • Place of Presentation
      宮崎
    • Related Report
      2011 Research-status Report
  • [Presentation] アゾベンゼン微結晶の磁場配向ポリマー膜の作製と光屈曲2011

    • Author(s)
      小島秀子・松冨正文・佐藤浩一・中村 純・木村史子・木村恒久
    • Organizer
      第20回有機結晶シンポジウム
    • Place of Presentation
      富山
    • Related Report
      2011 Research-status Report
  • [Presentation] アントリルメチレンインダノン結晶の光屈曲運動とそのメカニズム2011

    • Author(s)
      中村 純・内本英孝・小島秀子
    • Organizer
      第20回有機結晶シンポジウム
    • Place of Presentation
      富山
    • Related Report
      2011 Research-status Report
  • [Presentation] アミノアゾベンゼン誘導体における結晶のフォトメカニカル機能2011

    • Author(s)
      中村 純・小島直子・佐藤浩一・小島秀子
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      徳島
    • Related Report
      2011 Research-status Report
  • [Presentation] 分子結晶のフォトメカニカル機能2010

    • Author(s)
      小島秀子
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      筑波
    • Related Report
      2013 Final Research Report
    • Invited
  • [Book] New Frontiers in Photochromism2013

    • Author(s)
      Hideko Koshima, et al
    • Publisher
      Springer
    • Related Report
      2013 Final Research Report
  • [Book] マイクロ波化学プロセス技術II2013

    • Author(s)
      小島秀子
    • Total Pages
      300
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report 2012 Research-status Report
  • [Book] New Frontiers in Photochromism2013

    • Author(s)
      Hideko Koshima
    • Total Pages
      225
    • Publisher
      Springer
    • Related Report
      2013 Annual Research Report 2012 Research-status Report
  • [Book] フォトクロミズムの新展開と光メカニカル機能材料2011

    • Author(s)
      小島秀子, 他
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report
  • [Book] マイクロ波の化学プロセスへの応用2011

    • Author(s)
      小島秀子, 他
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report
  • [Book] フォトクロミズムの新展開と光メカニカル機能材料2011

    • Author(s)
      小島秀子
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Research-status Report
  • [Remarks] Ehime University, Koshima Laboratory

    • URL

      http://www.ehime-u.ac.jp/~achem/kino/

    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.ehime-u.ac.jp/research/news/detail.html?new_rec=9067

    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] 光駆動装置2014

    • Inventor(s)
      池滝慶記, 小島秀子
    • Industrial Property Rights Holder
      オリンパス株式会社, 愛媛大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-075516
    • Filing Date
      2014-04-01
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 光駆動装置2014

    • Inventor(s)
      池滝慶記、小島秀子
    • Industrial Property Rights Holder
      オリンパス株式会社、国立大学法人愛媛大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-075516
    • Filing Date
      2014-04-01
    • Related Report
      2013 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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