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Development of Ultra-sensitive Analysis System Based on Confined Ionic Liquids on Nanostructures Surface

Research Project

Project/Area Number 23655130
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionKyushu University

Principal Investigator

MORIKAWA Masa-aki  九州大学, 工学(系)研究科(研究院), 助教 (10363384)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords表面・界面 / イオン液体 / 分析化学 / 分子情報変換 / 高比表面積 / ナノワイヤーアレイ構造 / 表面ナノ空間 / 高次構造 / エネルギー移動 / 超高感度分析
Research Abstract

ZnO or Si nanowire arrays with a large-area and high-density were fabricated on glass or Si substrates. After spin-coating a hydrophobic ionic liquid (IL) on the nanostructured surface, aqueous solution of rhodamine B was placed on it. As a result, rhodamine B was efficiently concentrated more than 1,000 times by extracting into the thin layer of IL on the substrate, and it can be detected by fluorescence with high sensitivity.
On the other hand, we have also utilized photofunctional molecular assemblies to convert and amplify molecular information of target biomolecules. The appropriate combination of cationic lipids and anionic dyes affords unique superstructures simply by being in contact with aqueous dye with the cast-film of cationic lipids. The anionic dyes adsorbed on the lipid film as J-aggregates, and they were used as fluorescence donor to detect 7-nitrobenzofurazan-labeled biomolecules based on the fluorescence resonance energy transfer on the composite films.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (17 results)

All 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results) Presentation (10 results) (of which Invited: 2 results)

  • [Journal Article] Self-Assembly of Azobenzene Bilayer Membranes in Binary Ionic Liquid-Water Nanostructured Media2014

    • Author(s)
      T. K. Singh, K. Ishiba, M-a. Morikawa and N. Kimizuka
    • Journal Title

      Langmuir

      Volume: 30 Issue: 9 Pages: 2376-2384

    • DOI

      10.1021/la405010f

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Controlled Self-assembly and Luminescence Characteristics of Eu(III) Complexes in Binary Aqueous/Organic Media2013

    • Author(s)
      M-a. Morikawa, S. Tsunofuri and N. Kimizuka
    • Journal Title

      Langmuir

      Volume: 29 Issue: 42 Pages: 12930-12935

    • DOI

      10.1021/la403216e

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Redox-Active Microcapsules of Cytochrome c Formed at the Ionic Liquid-Water Interface2013

    • Author(s)
      M-a. Morikawa, R. Nii and N. Kimizuka
    • Journal Title

      Chem. Lett

      Volume: 42 Issue: 8 Pages: 788-790

    • DOI

      10.1246/cl.130249

    • NAID

      10031189249

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Controlled Formation of Microspheres from Ferrocene- Derivatized Amino Acids in Binary Aqueous-Organic Media2013

    • Author(s)
      M-a. Morikawa, K. Murata, K. Yamada and N. Kimizuka
    • Journal Title

      Chem. Lett

      Volume: 42 Issue: 5 Pages: 501-503

    • DOI

      10.1246/cl.130050

    • NAID

      10031167804

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Biopolymer-Encapsulated Protein Microcapsules Spontaneously Formed at the Ionic Liquid-Water Interface2012

    • Author(s)
      M. Morikawa, A. Takano, S. Tao, N. Kimizuka
    • Journal Title

      Biomacromolecules

      Volume: 13 Issue: 12 Pages: 4075-4080

    • DOI

      10.1021/bm301371t

    • Related Report
      2013 Final Research Report
  • [Journal Article] Converting Molecular Information of Redox Coenzymes via Self-Assembly2012

    • Author(s)
      M. Morikawa, N. Kimizuka
    • Journal Title

      Chem.Commun

      Volume: 48 (90) Issue: 90 Pages: 11106-11108

    • DOI

      10.1039/c2cc35827a

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ionic Liquids Induced Structural Changes of Bovine Serum Albumin in Aqueous Media : A Detailed Physicochemical and Spectroscopic Study2012

    • Author(s)
      Singh T, Bharmoria P, Morikawa MA, Kimizuka N, Kumar A.
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 116(39) Issue: 39 Pages: 1924-11935

    • DOI

      10.1021/jp303609h

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] Supramolecular Engineering of Nanostructures by Interfacial Self-assembly of Amphiphilic Building Blocks2014

    • Author(s)
      Masa-aki Morikawa
    • Organizer
      The Polymer Society of Korea, 2014 Spring Meeting, Korea-Japan Joint Symposium: Assembly Technology in Polymer Science
    • Place of Presentation
      Daejeon, Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 固-液界面系における脂質-色素超構造の特異的形成と機能(1)2013

    • Author(s)
      角振将平・森川全章・君塚信夫
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 固-液界面系における脂質-色素超構造の特異的形成と機能(2)2013

    • Author(s)
      森川全章・沖崎剛士・君塚信夫
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 固-液界面における特異な脂質-色素超構造体の形成と機能性2013

    • Author(s)
      角振将平・森川全章・君塚信夫
    • Organizer
      第58回高分子夏季大学
    • Place of Presentation
      広島国際会議場
    • Related Report
      2013 Final Research Report
  • [Presentation] 固-液界面系の自己集合による脂質-シアニン色素超構造体の形成2013

    • Author(s)
      角振将平・森川全章・君塚信夫
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 固―液界面系における脂質―色素超構造の特異的形成と機能(2)2013

    • Author(s)
      森川全章・沖崎剛士・君塚信夫
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固―液界面系における脂質―色素超構造の特異的形成と機能(1)2013

    • Author(s)
      角振将平・森川全章・君塚信夫
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固-液界面における特異な脂質-色素超構造体の形成と機能性2013

    • Author(s)
      角振将平・森川全章・君塚信夫
    • Organizer
      第58回高分子夏季大学
    • Place of Presentation
      広島国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 非平衡系の動的な分子の自己組織化に基づく高次構造の形成と機能2012

    • Author(s)
      森川全章・君塚信夫
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業
    • Related Report
      2013 Final Research Report
  • [Presentation] 散逸系界面の自己組織化とナノ構造エンジニアリング

    • Author(s)
      森川全章
    • Organizer
      文部科学省「卓越した大学院拠点形成支援補助金」事業 シンポジウム 「超分子化学と分子システム科学のクロスオーバー」
    • Place of Presentation
      九州大学
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2011-08-05   Modified: 2019-07-29  

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