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Material conversion and application of cellulosic materials by microwave irradiation in the presence of poly acids

Research Project

Project/Area Number 23655131
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionUniversity of Miyazaki

Principal Investigator

SAKAI Go  宮崎大学, 工学部, 教授 (40284567)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsケイ酸タングステン / マイクロ波 / セルロース / グルコース / 直接糖化 / ヘテロポリ酸 / ポリ酸 / バイオマス / 完全糖化
Research Abstract

In the present study, it is discovered that microwave irradiation to cellulose in the presence of tungstosilicic acid gave glucose (direct saccharification) with highly efficiency. The effects of crystal structure as well as solvent onto direct saccharification by microwave irradiation in the presence of hetero-poly acids such as tungstosilicic acid were investigated. The mixed solvent of water and ethanol could proceed the direct saccharification with highly glucose yield of 80%. The pretreatment on tungstocilicic acid is effective to improve the glucose yield. The direct saccharification of cellulose by the microwave irradiation in the presence of tungstocilicic acid depends strongly on the amount of water and its characteristics in the crystalline of tungstocilicic acid. Thus, it was found that the extremely high glucose yield can be achieved when the suitable condition was adopted. The highest yield of direct saccharification from cellulose to glucose reached 99%.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (10 results)

All 2013 2012 2010

All Presentation (9 results) (of which Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Presentation] ケイ酸タングステン共存下におけるマイクロ波照射による二糖および三糖の分解挙動2013

    • Author(s)
      平川しずか, 松永直樹, 酒井剛
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州
    • Related Report
      2013 Final Research Report
  • [Presentation] ケイ酸タングステン共存下におけるマイクロ波照射による二糖および三糖の分解挙動2013

    • Author(s)
      平川しずか、松永直樹、酒井 剛
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] ケイ酸タングステン共存下でのマイクロ波照射による二糖の分解とセルロース分解メカニズムの解明2012

    • Author(s)
      平川しずか, 酒井剛
    • Organizer
      第49回化学関連支部合同九州大会
    • Place of Presentation
      北九州
    • Related Report
      2013 Final Research Report
  • [Presentation] ヘテロポリ酸を用いたマイクロ波照射によるセルロースの直接糖化2012

    • Author(s)
      酒井剛
    • Organizer
      電気化学会九州支部 トークシャワーイン九州2012
    • Place of Presentation
      直方
    • Related Report
      2013 Final Research Report
  • [Presentation] ケイ酸タングステン共存下でのマイクロ波照射による二糖の分解とセルロース分解メカニズムの解明2012

    • Author(s)
      平川しずか、酒井 剛
    • Organizer
      第49回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2012 Research-status Report
  • [Presentation] ヘテロポリ酸を用いたマイクロ波照射によるセルロースの直接糖化2012

    • Author(s)
      酒井 剛
    • Organizer
      電気化学会九州支部 トークシャワーイン九州2012
    • Place of Presentation
      直方いこいの村
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] ヘテロポリ酸触媒を用いたマイクロ波照射によるセルロースの分2010

    • Author(s)
      山内淳, 奥孝裕, 酒井剛
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Tungstosilicic acid catalyzed cellulose conversion under microwave irradiation2010

    • Author(s)
      Jun Yamauchi, Takahiro Oku, Go Sakai
    • Organizer
      International Symposium on Biomass Conversion -Fundamentals & Applications-
    • Place of Presentation
      Miyazaki, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Study on microwave assisted degradation of cellulose in the presence of tungstosilicic acid2010

    • Author(s)
      Go Sakai, Jun Yamauchi, Takahiro Oku, Toshifumi Yui, Kazuhiro Sugamoto, Yoh-ichi Matsushita, Tsuyoshi Kijima
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] セルロース系物質の分解方法2010

    • Inventor(s)
      酒井剛
    • Industrial Property Rights Holder
      宮崎大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2010-253129
    • Filing Date
      2010-11-11
    • Related Report
      2013 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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