Effective photo-reduction of carbon dioxide by using ionic liquids
Project/Area Number |
23655144
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Environmental chemistry
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Research Institution | Hosei University (2012) Kyoto University (2011) |
Principal Investigator |
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Project Period (FY) |
2011 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | イオン液体 / 二酸化炭素 / 光還元 / レニウム錯体 / レニウム触媒 |
Research Abstract |
We have investigated the photo-reduction of carbon dioxide in room temperature ionic liquids. Using triethanolamine as the electron donor, under the existence of rhenium catalysis the photo-reduction of carbon dioxide has been tested for several ionic liquids with a variety of cations and anions at different temperatures and pressures. It has been revealed that the solutions of imidazolium cations of short alkyl-chains with hydrophobic anions are suitable for the photo-reduction of carbon dioxide.
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Report
(3 results)
Research Products
(5 results)