| Project/Area Number |
23655147
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Environmental chemistry
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| Research Institution | Meijo University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
MASATO Sakaguchi 静岡県立大学, 環境科学研究所, 教授 (40113328)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
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| Keywords | メカノケミカル / セルロース / HEMA / 立体規則性 / ブロック共重合体 / メカノケミカル反応 / 機械的破壊 / 糖化 / メカノラジカル |
|---|
| Research Abstract |
In this study, we investigated the degradation and surface modification of cellulose using mechano-chemical reaction. The mechano-chemically degradation of cellulose proceeded from the surface at the molecular level. Next, mechano-chemical reaction of cellulose and 2-hydroxyethyl methacrylate (HEMA) in a tube under vacuum showed the production of block copolymer of cellulose-block-poly(HEMA). Furthermore mechano-chemical reaction of benzyl cellulose and HEMA in a tube under vacuum also produced the block copolymer, whereas the tacticity of HEMA polymerized varied as compared with the case of cellulose.
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