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Pursuit of the performance limit of organic FETs by fabricating ideal MIS interfaces

Research Project

Project/Area Number 23655171
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials/Devices
Research InstitutionNara Institute of Science and Technology

Principal Investigator

NAKAMURA Masakazu  奈良先端科学技術大学院大学, 物質創成科学研究科, 特任教授 (80332568)

Co-Investigator(Kenkyū-buntansha) MATSUBARA Ryosuke  奈良先端科学技術大学院大学, 物質創成科学研究科, 特任助教 (60611530)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords有機半導体 / 理想界面 / 半導体物性 / 有機トランジスタ / 結晶工学
Research Abstract

Aiming at producing an ideal MIS interfaces by an organic semiconductor layer and a flat gate insulator with an atom scale, a technique of forming a 1 micrometer or less-thick mica insulating layer on a conductive substrate has been established. Unlike the poor reproducibility of molecular orientation in conventional experiments, it has been shown that the thin-film-phase polycrystalline film with vertical molecular orientation, which is suitable for carrier transport, epitaxially grows by treating the cleaved mica surface with sodium persulfate aqueous solution. New analytical models for carrier mobility that can be used generally in such polycrystalline films have been proposed. By these models, influence of the epitaxial growth on the carrier transport was discussed.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (34 results)

All 2014 2013 2012 2011 Other

All Journal Article (4 results) (of which Peer Reviewed: 1 results) Presentation (24 results) (of which Invited: 5 results) Book (3 results) Remarks (3 results)

  • [Journal Article] Scaling limits of organic digital circuits2014

    • Author(s)
      A. Risteska, K. Myny, S. Steudel, M. Nakamura, and D. Knipp
    • Journal Title

      Org. Electron

      Volume: 15 (2) Issue: 2 Pages: 461-469

    • DOI

      10.1016/j.orgel.2013.11.028

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 有機多結晶膜における移動度制限要因の新規解析方法2013

    • Author(s)
      松原亮介, 中村峻介, 落合慧紀, 中村雅一
    • Journal Title

      電子情報通信学会信学技報

      Volume: Vol. 113, No. 243 Pages: 39-43

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Journal Article] ペンタセン多結晶膜の結晶学的階層構造とキャリア輸送バンドに対する絶縁膜表面の影響2012

    • Author(s)
      松原亮介, 坂井祐貴, 野村俊夫, 真島豊, 酒井正俊, 工藤一浩, 中村雅一
    • Journal Title

      電子情報通信学会信学技報

      Volume: Vol. 112, No. 5 Pages: 19-23

    • NAID

      110009564212

    • Related Report
      2013 Final Research Report
  • [Journal Article] ペンタセン多結晶膜の結晶学的階層構造とキャリア輸送バンドに対する絶縁膜表面の影響2012

    • Author(s)
      松原亮介, 坂井祐貴, 野村俊夫, 真島豊, 酒井正俊, 工藤一浩, 中村雅一
    • Journal Title

      信学技報

      Volume: 112

    • NAID

      110009564212

    • Related Report
      2012 Research-status Report
  • [Presentation] AFMポテンショメトリによる有機薄膜トランジスタの評価2014

    • Author(s)
      松原亮介, 中村雅一
    • Organizer
      平成25年度顕微鏡学会走査型プローブ顕微鏡分科会オープン研究会
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2014-03-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 新規多結晶モデルによる有機多結晶膜における移動度制限要因の解析2014

    • Author(s)
      松原亮介,中村峻介,小島広孝,中村雅一
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県相模原市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Analysis of mobility limiting factors in epitaxially grown pentacene polycrystalline films on atomically flat mica surface2013

    • Author(s)
      R. Matsubara, S. Ochiai, N. Ohashi, S. Nakamura, and M. Nakamura
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2013-09-18
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] A New Analytical Method of Mobility Limiting Factors in Polycrystalline Organic Films : Influence of Epitaxial Growth of Pentacene Crystals Using Atomically Flat Substrates2013

    • Author(s)
      R. Matsubara and M. Nakamura
    • Organizer
      The 11th China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena
    • Place of Presentation
      Changchun, China
    • Year and Date
      2013-09-03
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Crystal structures and carrier transport properties of pentacene polycrystalline films grown on atomically flat mica surfaces2013

    • Author(s)
      R. Matsubara, S. Ochiai, S. Nakamura, and M. Nakamura
    • Organizer
      9th International Conference on Organic Electronics (ICOE 2013)
    • Place of Presentation
      Grenoble, France
    • Year and Date
      2013-06-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation of organic thin film transistor with ideally flat semiconductor/insulator interface using cleaved mica surface2013

    • Author(s)
      S. Ochiai, S. Nakamura, R. Matsubara, and M. Nakamura
    • Organizer
      Seventh International Conference on Molecular Electronics and Bioelectronics (M&BE7)
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2013-03-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Interface Gap States in Pentacene Thin-Film Transistors Measured by Gate-Field-Modulated Thermally-Stimulated-Current Method2013

    • Author(s)
      M. Nakamura
    • Organizer
      Workshop on the Nature of Gap States in Organic Devices
    • Place of Presentation
      Chiba, Japan.
    • Year and Date
      2013-01-18
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 新規多結晶モデルによる有機薄膜トランジスタにおける温度依存キャリア移動度の解析2013

    • Author(s)
      中村峻介, 松原亮介, 中村雅一
    • Organizer
      第10回薄膜材料デバイス研究会
    • Place of Presentation
      アバンティ響都ホール(京都市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] A New Analytical Method of Mobility Limiting Factors in Polycrystalline Organic Films: Influence of Epitaxial Growth of Pentacene Crystals Using Atomically Flat Substrates2013

    • Author(s)
      R. Matsubara and M. Nakamura
    • Organizer
      The 11th China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena
    • Place of Presentation
      Changchun, China
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Crystal structures and carrier transport properties of pentacene polycrystalline films grown on atomically flat mica surfaces2013

    • Author(s)
      R. Matsubara, S. Ochiai, S. Nakamura, and M. Nakamura
    • Organizer
      9th International Conference on Organic Electronics
    • Place of Presentation
      Grenoble, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] マイカ劈開面におけるペンタセン多結晶膜のエピタキシャル成長2012

    • Author(s)
      落合慧紀, 松原亮介, 大橋昇, 中村雅一
    • Organizer
      第9回薄膜材料デバイス研究会
    • Place of Presentation
      奈良県奈良市
    • Year and Date
      2012-11-03
    • Related Report
      2013 Final Research Report
  • [Presentation] マイカ劈開面上でのペンタセン結晶成長2012

    • Author(s)
      落合慧紀,松原亮介,中村雅一
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      東京都新宿区
    • Related Report
      2011 Research-status Report
  • [Presentation] Interface State Density in Pentacene Thin - Film Transistors Analyzed by Field - Effect Thermally - Stimulated - Current Method: Variation by Air Exposure2011

    • Author(s)
      T. Fujii, S. Kuniyoshi, M. Sakai, K. Kudo, R. Matsubara, and M. Nakamura
    • Organizer
      2011 MRS Fall Meeting
    • Place of Presentation
      Boston, USA
    • Related Report
      2011 Research-status Report
  • [Presentation] ホットプレス法による薄板状有機結晶デバイスの作製2011

    • Author(s)
      井上敦夫,岡本樹宣,城寶祐輝,酒井正俊,山内博,中村雅一,工藤一浩
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形市
    • Related Report
      2011 Research-status Report
  • [Presentation] Determining Factor of Carrier Mobility in Pentacene Thin-Film Transistors: Influence of Substrate Surface and Growth Rate2011

    • Author(s)
      R. Matsubara, T. Nomura, M. Sakai, K. Kudo, M. Nakamura
    • Organizer
      24th International Conference on Amorphous and Nanocrystalline Semiconductors (ICANS 24)
    • Place of Presentation
      Nara, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] AFMポテンショメトリによる有機薄膜トランジスタの評価

    • Author(s)
      松原亮介、中村雅一
    • Organizer
      顕微鏡学会走査型プローブ顕微鏡分科会オープン研究会
    • Place of Presentation
      物質・材料研究機構(茨城県つくば市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 原子フラットなマイカ劈開面上にエピタキシャル成長したペンタセン多結晶膜における移動度制限要因の解析

    • Author(s)
      松原亮介, 落合慧紀,大橋昇, 中村俊介, 中村雅一
    • Organizer
      応用物理学会関西支部 平成25年度第2回講演会
    • Place of Presentation
      奈良先端科学技術大学院大学(生駒市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] マイカをゲート絶縁膜に用いたペンタセンTFTの作製およびキャリア輸送制限要因の評価

    • Author(s)
      中村峻介,落合慧紀,松原亮介,中村雅一
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of organic thin film transistor with ideally flat semiconductor/insulator interface using cleaved mica surface

    • Author(s)
      S. Ochiai, S. Nakamura, R. Matsubara, and M. Nakamura
    • Organizer
      Seventh International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      福岡県福岡市
    • Related Report
      2012 Research-status Report
  • [Presentation] Interface Gap States in Pentacene Thin-Film Transistors Measured by Gate-Field-Modulated Thermally-Stimulated-Current Method

    • Author(s)
      M. Nakamura
    • Organizer
      Workshop on the Nature of Gap States in Organic Devices
    • Place of Presentation
      千葉県千葉市
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Crystal structures of pentacene polycrystalline films grown on cleaved-mica surface and its influence on carrier transport

    • Author(s)
      R. Matsubara, S. Ochiai, and M. Nakamura
    • Organizer
      2012 MRS Fall Meeting
    • Place of Presentation
      Boston, USA
    • Related Report
      2012 Research-status Report
  • [Presentation] マイカ劈開面におけるペンタセン多結晶膜のエピタキシャル成長

    • Author(s)
      落合慧紀,松原亮介,大橋昇,中村雅一
    • Organizer
      第9回薄膜材料デバイス研究会
    • Place of Presentation
      奈良県奈良市
    • Related Report
      2012 Research-status Report
  • [Presentation] Mobility Limiting Factors in Pentacene Thin-Film Transistors: Influence of the Film Growth Rate

    • Author(s)
      R. Matsubara, T. Nomura, M. Sakai, K. Kudo, and M. Nakamura
    • Organizer
      2012 International Conference on Solid State Devices and Materials
    • Place of Presentation
      京都府京都市
    • Related Report
      2012 Research-status Report
  • [Presentation] マイカ劈開面上に成長したペンタセン薄膜の結晶構造

    • Author(s)
      松原亮介,落合慧紀,中村雅一
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Research-status Report
  • [Book] 薄膜の評価技術ハンドブック : 第4章第6節第1項走査型プローブ顕微鏡による電荷/電位マッピング2013

    • Author(s)
      中村雅一
    • Publisher
      テクノシステム
    • Related Report
      2013 Final Research Report
  • [Book] 薄膜の評価技術ハンドブック:第4章第6節第1項走査型プローブ顕微鏡による電荷/電位マッピング2013

    • Author(s)
      中村雅一
    • Total Pages
      2
    • Publisher
      テクノシステム
    • Related Report
      2013 Annual Research Report
  • [Book] "PART II, Chapter 10, Mobility limiting factors in practical polycrystalline organic thin films" in "Electronic processes in organic electronics : Bridging electronic states and device properties"

    • Author(s)
      R. Matsubara, N. Ohashi, S.-G. Li, and M. Nakamura
    • Publisher
      Springer(in press)
    • Related Report
      2013 Final Research Report
  • [Remarks] ホームページアドレス

    • URL

      http://mswebs.naist.jp/LABs/greendevice/

    • Related Report
      2013 Final Research Report
  • [Remarks] 有機固体素子科学研究室 研究の具体例

    • URL

      http://mswebs.naist.jp/LABs/greendevice/research/example.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 有機固体素子科学研究室

    • URL

      http://mswebs.naist.jp/LABs/greendevice/

    • Related Report
      2012 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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