Development and Evaluation of NMR-Qubit Molecules by Reduction of Symmetry
| Project/Area Number |
23655173
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional materials/Devices
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
ITO Shigekazu 東京工業大学, 理工学研究科, 准教授 (00312538)
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| Project Period (FY) |
2011-04-28 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 量子コンピューター / 合成化学 / 核磁気共鳴 / 低配位リン化合物 / 核スピン / 立体化学 / 計算化学 / 立体効果 / 立体配座 / 量子コンピュータ |
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| Outline of Final Research Achievements |
Quantum computer is an information processing technique based on the entanglement of quantum mechanics. In this study, we attempted to develop novel and practical NMR-qubit molecules containing 31P nucleus by utilizing synthetic chemistry. We developed the stereoselective synthesis of phosphaalkenes and the P=P cleavage reaction providing the various organophosphorus compounds bearing the non-equivalent (sp2-)phosphorus atoms. These low coordinated phosphorus compounds exhibited the suitable NMR properties to the quantum information processing. The newly developed phosphorus compounds can be utilized as ligands of metal-complexes, which enable to multiply the number of quibits.
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Report
(5 results)
Research Products
(52 results)
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[Journal Article] Intensive NMR Study of 1-t-Butyl-3-methyl- 2,4-bis(2,4,6-tri-t-butylphenyl)- 1,3-diphosphacyclobutane-2,4-diyl2011
Author(s)
M. Yoshifuji, S. T. Osborn, A. J. Arduengo, III, K. A. Belmore, S. Ito
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Journal Title
Heteroat. Chem.
Volume: 22
Pages: 331-338
Related Report
Peer Reviewed
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