Fabrication of one-dimensionally aligned reactive sites with non-contact process
Project/Area Number |
23655186
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Organic industrial materials
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Research Institution | Kobe University |
Principal Investigator |
UEDA Yasukiyo 神戸大学, 大学院・工学研究科, 教授 (40116190)
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Co-Investigator(Kenkyū-buntansha) |
MISAKI Masahiro 神戸大学, 自然科学研究科, 助教 (00462862)
KOSHIBA Yasuko 神戸大学, 大学院・工学研究科, 助手 (70243326)
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Project Period (FY) |
2011 – 2012
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Project Status |
Completed (Fiscal Year 2012)
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Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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Keywords | 分子配向反応場 / 非接触プロセス / 光異性 / 一軸配向 / 有機トランジスタ / 光異性化 / 有機薄膜トランジスタ |
Research Abstract |
With the aim of fabrication of one-dimensionally oriented reaction site, we studied on photo-induced orientation behavior of polyamic acid with azo-benzene moiety (Azo-PAA), introduction of reaction site into silicon substrate, synthesis of fluorene derivatives with azo-benzene moiety and introduction of reaction site into partially imidized Azo-PAA. Partially imidized Azo-PAA with 3-aminopropyl-triethoxysilane aligned one-dimensionally by irradiation of polarized UV light with trans-cis isomerization of azo-benzene moiety. Triethoxysilane groups at top surface of aligned Azo-PAA may act as reaction sites with various functional groups
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Report
(3 results)
Research Products
(22 results)
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[Journal Article] Synthesis, Characterization, Photo-induced Alignment, and Surface Orientation of Poly(9,9-dioctylfluorene-alt-azobenzene)s2012
Author(s)
K. Kinashi, Yuki Kambe, M. Misaki, Y. Koshiba, K. Ishida, Y. Ueda
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Journal Title
J.Polym. Sci., Part A, Polym. Chem.
Volume: 50
Issue: 24
Pages: 5107-5114
DOI
Related Report
Peer Reviewed
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