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Preparation of Nanoparticles of Electrochemically Reactive Transition Metal Compounds in Molten Aquacomplexes

Research Project

Project/Area Number 23655193
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionYokohama National University

Principal Investigator

DOKKO Kaoru  横浜国立大学, 大学院・工学研究院, 准教授 (70438117)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords電気化学 / 水熱合成 / リチウム二次電池 / オリビン / ナノ粒子 / マイクロ波 / 電池
Research Abstract

Nanoparticles of olivine-type compound, LiMnPO_4, was synthesized in molten aquacomplex of MnSO_4・xH_2O. Nanoparticles of LiMnPO_4 can be synthesized rapidly by a heat-treatment of precursor with microwave irradiation. The obtained LiMnPO4 exhibited a high electrochemical reactivity. As decreasing the particle size of LiMnPO_4, the electrochemical reactivity was increased.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (12 results)

All 2013 2012 2011

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (8 results) (of which Invited: 1 results)

  • [Journal Article] 溶融アクア錯体を用いたLiMnPO4ナノ粒子の合成2013

    • Author(s)
      獨古薫
    • Journal Title

      電池技術委員会資料

      Volume: 25-01巻 Pages: 1-8

    • Related Report
      2012 Final Research Report
  • [Journal Article] 溶融アクア錯体を用いたLiMnPO4ナノ粒子の合成2013

    • Author(s)
      獨古 薫
    • Journal Title

      電池技術委員会資料

      Volume: 25-01 Pages: 1-8

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Masayoshi Watanabe, LiMnPO4 Nanoparticles Prepared through the Reaction between Li_3PO_4 and Molten Aqua-complex of MnSO_4,2011

    • Author(s)
      Kaoru Dokko, Takeshi Hachida
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 158巻

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] LiMnPO_4 Nanoparticles Prepared through Reaction between Li_3PO_4 and Molten Aqua-complex of Mn(II)for High-Performance Cathode of Lithium Batteries2011

    • Author(s)
      K.Dokko, T.Hachida, M.Watanabe
    • Journal Title

      J.Electrochem.Soc.

      Volume: 158 Issue: 12 Pages: A1275-A1275

    • DOI

      10.1149/2.015112jes

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 溶融アクア錯体を 用いたLiMnPO4ナノ粒子の合成2013

    • Author(s)
      獨古 薫
    • Organizer
      第365回電池技術委員会
    • Place of Presentation
      大阪府豊中市
    • Year and Date
      2013-02-08
    • Related Report
      2012 Final Research Report
  • [Presentation] 溶融アクア錯体を用いたLiMnPO4ナノ粒子の合成2013

    • Author(s)
      獨古 薫
    • Organizer
      第365回電池技術委員会
    • Place of Presentation
      大阪府豊中市
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 水熱合成法によるLiMnP_O4の粒子径制御と電池特性2012

    • Author(s)
      谷中 秀輔,吉田 和生, 獨古 薫, 渡邉 正義
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松
    • Year and Date
      2012-03-30
    • Related Report
      2012 Final Research Report
  • [Presentation] マイクロ波を用いた水熱法によるLiMnPO4の合成と電池特性2012

    • Author(s)
      獨古 薫
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Effect of HydrothermalSynthesis Conditions on LiMnPO_4Particle Size2012

    • Author(s)
      Kaoru Dokko
    • Organizer
      222nd Meeting of TheElectrochemical Society
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Effect of Hydrothermal Synthesis Conditions on LiMnPO4 Particle Size2012

    • Author(s)
      Kaoru Dokko
    • Organizer
      222nd Meeting of The Electrochemical Society
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] 水熱合成法によるLiMnPO4の粒子径制御と電池特性2012

    • Author(s)
      谷中 秀輔,吉田 和生, 獨古 薫, 渡邉 正義
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松
    • Related Report
      2011 Research-status Report
  • [Presentation] 溶融アクア錯体を用いたLiMnPO4ナノ粒子の合成2011

    • Author(s)
      獨古 薫,八田 剛志,渡邉 正義
    • Organizer
      第52回電池討論会
    • Place of Presentation
      東京
    • Year and Date
      2011-10-18
    • Related Report
      2012 Final Research Report 2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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