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Propose of Melt Electro-Spinning Method and Fabrication ofLithium Ion Conductive Nano-Scale Glass

Research Project

Project/Area Number 23655194
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionNagaoka University of Technology

Principal Investigator

KOMATSU Takayuki  長岡技術科学大学, 工学部, 教授 (60143822)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsガラス / リチウムイオン伝導ガラス / 形態制御 / ナノガラス粉末 / ガラス融液 / 静電噴霧法 / リチウムイオン電池
Research Abstract

The purpose of this study is to synthesize nano-scale glass particle by using melt electro-spinning (MES) method and to develop a new morphology control method. A MES apparatus was made, and it was confirmed that fibers were drawn in the low melting Bi_2O_3-B_2O_3 system. For lithium iron phosphate melts, MES phenomenon was not observed, in which electric field was applied to platinum crucible with melts as anode. It was suggested that for realization of MES phenomenon melts having more large electronic polarization is required. Through the study of glass composition design, new spinel-type LiFeSiO_4 and Na_2FeP_2O_7 crystals were discovered.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (24 results)

All 2013 2012 2011 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (11 results) Remarks (2 results)

  • [Journal Article] Triclinic Na_2-xFe_1+x/2P_2O_7/C glass-ceramics with high current density performance for sodium ion battery2013

    • Author(s)
      T. Honma, N. Ito, T. Togashi, A. Sato, T. Komatsu
    • Journal Title

      Journal of Power Sources

      Volume: 227巻 Pages: 31-34

    • URL

      http://dx.doi.org/10.1016/j/jpowersour.2012.11.030

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Na_2FeP_2O_7 glass-ceramics for sodium ion battery2012

    • Author(s)
      T. Honma, T. Togashi, N. Ito, T. Komatsu
    • Journal Title

      Journal of Ceramic Society of Japan

      Volume: 120巻 Pages: 344-346

    • URL

      http://dx.doi.org/10.2109/jcersj2.120.344

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spinel-type crystals based on LiFeSiO_4 with high electrical conductivity for lilthium ion battery formed by melt-quenching method2012

    • Author(s)
      T. Honma, T. Togashi, T. Komatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 120巻 Pages: 93-97

    • URL

      http://dx.doi.org/10.2109/jcersj2.120.93

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation mechanism of LiFePO_4 in crystallization of lithium iron phosphate glass particles2012

    • Author(s)
      K. Nagamine, K. Oh-ishi, T. Honma, T. Komatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 120巻 Pages: 193-198

    • URL

      http://dx.doi.org/10.2109/jcersj2.120.193

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Na<sub>2</sub>FeP<sub>2</sub>O<sub>7</sub> glass-ceramics for sodium ion battery2012

    • Author(s)
      T. Honma, T. Togashi, N. Ito, T. Komatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 120 Issue: 1404 Pages: 344-346

    • DOI

      10.2109/jcersj2.120.344

    • NAID

      130004480080

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation mechanism of LiFePO<sub>4</sub> in crystallization of lithium iron phosphate glass particles2012

    • Author(s)
      K. Nagamine, K. Oh-ishi, T. Honma, T. Komatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 120 Issue: 1401 Pages: 193-198

    • DOI

      10.2109/jcersj2.120.193

    • NAID

      130004480053

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Spinel-type crystals based on LiFeSiO4 with high electrical conductivity for lithium ion battery formed by melt-quenching method2012

    • Author(s)
      T. Honma, T. Togashi, T. Komatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 120 Issue: 1399 Pages: 93-97

    • DOI

      10.2109/jcersj2.120.93

    • NAID

      130002067600

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Glass-ceramic LiFePO4 for lithium –ion rechargeable battery2012

    • Author(s)
      T. Nagakane, H. Yamauchi, M. Ohji, A. Sakamoto, T. Komatsu, T. Honma
    • Journal Title

      Solid State Ionics

      Volume: 206 Pages: 78-83

    • DOI

      10.1016/j.ssi.2011.10.017

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A fast synthesis of Li_3V_2(PO_4)_3 crystals via glass-ceramic processing and their battery performance2011

    • Author(s)
      K. Nagamine, T. Honma, T. Komatsu
    • Journal Title

      Journal of Power Sources

      Volume: 196巻 Pages: 9618-9624

    • URL

      http://dx.doi.org/10.1016/j/jpowersour.2011.06.094

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A fast synthesis of Li_3V_2(PO_4)_3 crystals via glass-ceramic processing and their battery performance2011

    • Author(s)
      K.Nagamine, et al
    • Journal Title

      Journal of Power Sources

      Volume: 196[22] Issue: 22 Pages: 9618-9624

    • DOI

      10.1016/j.jpowsour.2011.06.094

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystallization behavior of lithium iron phosphate glasses in different atmospheres2011

    • Author(s)
      K. Nagamine, S. Reinsch, R. Mueller, T. Honma, T. Komatsu
    • Journal Title

      Journal of the American

      Volume: 94 Issue: 9 Pages: 2890-2895

    • DOI

      10.1111/j.1551-2916.2011.04579.x

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Glass-ceramics for the innovative secondary batteries2013

    • Author(s)
      T. Honma, T. Komatsu
    • Organizer
      Functional Glasses : Properties and Applications for Energy and Information
    • Place of Presentation
      Sicily, Italy
    • Related Report
      2012 Annual Research Report
  • [Presentation] Relationship between the formation behavior of spinel-type lithium iron silicate crystals and cooling condition in melting method2012

    • Author(s)
      T. Togashi, T. Honma, T. Komatsu
    • Organizer
      10th International Symposium on Crystallization in Glasses and Liquids
    • Place of Presentation
      Goslar, Germany
    • Related Report
      2012 Final Research Report
  • [Presentation] Glass-ceramics for the active materials for lithium ion battery2012

    • Author(s)
      T. Honma, T. Togashi, T. Komatsu
    • Organizer
      XIII International Conference on the Physics of Non-Crystalline Solids
    • Place of Presentation
      Hubei, China
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Relationship between the formation behavior of spinel-type lithim iron silicate crystals and cooling condition in melting method2012

    • Author(s)
      T. Togashi, T. Honma, T. Komatsu
    • Organizer
      10th International Symposium on Crystallization in Glasses and Liquids
    • Place of Presentation
      Goslar, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] High-performance glass-ceramic LiFePO4 for lithium-ion rechargeable battery2012

    • Author(s)
      A.Sakamoto, T. Nagakane, T. Sakai, T. Honma, T. Komatsu
    • Organizer
      The 1st International GIGAKU Conference in Nagaoka(招待講演)
    • Place of Presentation
      Nagaoka, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] Fabrication of LiMPO4 Glass Ceramics for Rechargeable Lithium Ion Battery2011

    • Author(s)
      T. Honma, T. Komatsu
    • Organizer
      3rd International symposium on Advanced Ceramics and Technology for sustainable Energy Applications
    • Place of Presentation
      Pingtung, Taiwan, R.O.C
    • Year and Date
      2011-10-02
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication of LiMn_xFe_1_xPO_4 glass and glass-ceramics for lithium ion battery2011

    • Author(s)
      T. Honma, T. Komatsu
    • Organizer
      Materials Science & Technology 2011 (MS&T11) Conference & Exhibition
    • Place of Presentation
      Columbus,OH USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication and Characterization of lithiumvanadium phosphate glass-ceramics for lithiumion battery2011

    • Author(s)
      K. Nagamine, T. Honma, T. Komatsu
    • Organizer
      12th Conference of the EuropeanCeramic Society
    • Place of Presentation
      Stockholm, Sweden
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication and characterization of lithium vanadium phosphate glass-ceramics for lithium ion battery2011

    • Author(s)
      K. Nagamine, T. Honma, T. Komatsu
    • Organizer
      12th Conference of the European Ceramic Society
    • Place of Presentation
      Sweden, Stockholm
    • Related Report
      2011 Research-status Report
  • [Presentation] Fabrication of LiMnxFe1-xPO4 glass and glass-ceramics for lithium ion battery2011

    • Author(s)
      T. Honma, T. Komatsu
    • Organizer
      Materials Science & Technology 2011 (MS&T11) Conference & Exhibition
    • Place of Presentation
      Columbus, USA
    • Related Report
      2011 Research-status Report
  • [Presentation] Fabrication of LiMPO4 Glass Ceramics for Rechargeable Lithium Ion Battery2011

    • Author(s)
      T.Honma, T. Komatsu
    • Organizer
      3rd International symposium on Advanced Ceramics and Technology for sustainable Energy Applications
    • Place of Presentation
      Pingtun, Taiwan
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://mst.nagaokaut.ac.jp/amorph

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://mst.nagaokaut.ac.jp/amorph

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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