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Construction of Thermo-setting Phenolic Resin Containing Sliding Unit Segments

Research Project

Project/Area Number 23655210
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionKanazawa University

Principal Investigator

OGOSHI Tomoki  金沢大学, 物質化学系, 准教授 (00447682)

Co-Investigator(Kenkyū-buntansha) YAMAGISHI Tada-aki  金沢大学, 物質化学系, 教授 (90220251)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsポリロタキサン / ピラー[5]アレーン / トポロジカルゲル / フェノール樹脂 / Pillar[5]arene / ビオロゲンポリマー / 熱硬化性樹脂 / 環動ゲル / 融点 / ポリエチレン
Research Abstract

We firstly tried to synthesize viologen polymers with high molecular weights. However, due to the low reactivity of the cationic reaction, the degree of polymerization (DP) was found to be 8-10. Thus, we synthesized the other pillar[5]arene-based polyrotaxanes containing polyTHF. By capping polyTHF end groups with bulky stoppers in liquid pillar[5]arene carrying 10 triethylene oxide chains, new nonionic polyrotaxanes consisting of polyTHF and pillar[5]arene wheels carrying 10 triethylene oxide chains could be synthesized.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (21 results)

All 2013 2012 2011 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (13 results) (of which Invited: 3 results) Remarks (1 results)

  • [Journal Article] Extension of Polyethylene Chains byFormation of Polypseudorotaxane Structures with Perpentylated Pillar[5]arenes2013

    • Author(s)
      Ogoshi, T.*; Kayama, H.; Aoki, T.; Yamagishi, T.; Ohashi, R.; Mizuno, M
    • Journal Title

      Polym. J

      Volume: (in press)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Synthetic Hosts Pillararenes: Their Synthesis and Application for Supramolecular Materials2012

    • Author(s)
      Ogoshi, T.*; Yamagishi, T
    • Journal Title

      Bull. Chem. Soc. Jan

      Volume: (in press) Issue: 3 Pages: 312-332

    • DOI

      10.1246/bcsj.20120245

    • NAID

      10031162137

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cyclic Host Liquids for Facile and High-Yield Synthesis of [2]Rotaxanes2012

    • Author(s)
      Ogoshi, T.*; Aoki, T.; Shiga, R.; Iizuka, R.; Ueda, S.; Demachi, K.; Yamafuji, D.; Kayama, H.; Yamagishi, T
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 20322-20325

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoreversible Switching of the Lower Critical Solution Temperature in a Photoresponsive Host-Guest System of Pillar[6]arene with Triethylene Oxide Substituents and an Azobenzene Derivative2012

    • Author(s)
      Ogoshi, T.*; Kida, K.; Yamagishi, T
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 20146-20150

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversibly Tunable Lower Critical Solution Temperature Utilizing Host-Guest Complexation of Pillar[5]arene with Triethylene Oxide Substituents2012

    • Author(s)
      Ogoshi, T.*; Shiga, R.; Yamagishi, T
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 4577-4580

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cyclic host liquids for facile and high-yield synthesis of [2]rotaxanes2012

    • Author(s)
      Tomoki Ogoshi
    • Journal Title

      J Am Chem Soc

      Volume: 134 Issue: 50 Pages: 20322-20325

    • DOI

      10.1021/ja310757p

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction of Emeraldine Base Form of Polyaniline by Pillar[5]arene Based on Formation of Poly(pseudorotaxane) Structure2011

    • Author(s)
      Tomoki Ogoshi, Yuko Hasegawa, Takamichi Aoki, Yusuke Ishimori, Shinsuke Inagi, Tada-aki Yamagishi
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 19 Pages: 7639-7644

    • DOI

      10.1021/ma2016979

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Pillar[5]arene-based Ionics Materials JAIST2013

    • Author(s)
      生越友樹
    • Organizer
      International Symposium on Ionics Materials
    • Place of Presentation
      北陸先端科学技術大学院大学(石川県能美市)
    • Year and Date
      2013-03-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Pillar[5]arene-based Ionics Materials2013

    • Author(s)
      生越友樹
    • Organizer
      JAIST International Symposium on Ionics Materials
    • Place of Presentation
      北陸先端科学技術大学院大学(石川県能美市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Pillararenes, New Synthetic Receptors for Supramolecular Chemistry2012

    • Author(s)
      生越友樹
    • Organizer
      International Symposium on Frontiers of Macrocyclic and Supramolecular Chemistry
    • Place of Presentation
      精華大学(中国・北京)
    • Year and Date
      2012-12-21
    • Related Report
      2012 Final Research Report
  • [Presentation] パラ位連結環状ホスト分子Pillarareneを基にした超分子材料の創成2012

    • Author(s)
      生越友樹
    • Organizer
      関東東海若手高分子研究会2012ミニシンポジウム
    • Place of Presentation
      犬山館(愛知県犬山市)
    • Year and Date
      2012-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] 一置換Pillar[5]areneを基とした超分子形成2012

    • Author(s)
      出町一樹、北島啓資、生越友樹、山岸忠明
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県名古屋市
    • Year and Date
      2012-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] Pillar[5]areneユニットとPillar[6]areneユニットが交互に配列した超分子ポリマーの形成2012

    • Author(s)
      香山仁志、山藤大紀、青木崇倫、生越友樹、山岸忠明
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県名古屋市)
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Pillar[5]areneをビルディングブロックとした超分子形成2012

    • Author(s)
      生越友樹、志賀稜平、上島矢奨、青木崇倫、山岸忠明
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県名古屋市)
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] 溶融状態におけるポリエチレンとPillar[5]areneからなるポリ擬ロタキサンの合成2012

    • Author(s)
      香山仁志、青木崇倫、生越友樹、山岸忠明
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県名古屋市)
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] ポリエチレンとpillar[5]arene からなるポリロタキサンの合成2012

    • Author(s)
      香山仁志、青木崇倫 、生越友樹、山岸忠明
    • Organizer
      第61回高分子年次会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2012-05-29
    • Related Report
      2012 Final Research Report
  • [Presentation] パラ位連結環状ホスト分子Pillarareneを基にした超分子材料の創成2012

    • Author(s)
      生越友樹
    • Organizer
      関東東海若手高分子研究会2012ミニシンポジウム
    • Place of Presentation
      犬山館(愛知県犬山市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Pillararenes, New Synthetic Receptors for Supramolecular Chemistry2012

    • Author(s)
      生越友樹
    • Organizer
      International Symposium on Frontiers of Macrocyclic and Supramolecular Chemistry
    • Place of Presentation
      精華大学(中国・北京)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ポリエチレンとPillar[5]areneからなるポリロタキサンの合成2012

    • Author(s)
      香山仁志・青木宗倫・生越友樹・山岸忠明
    • Organizer
      日本化学会年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(神奈川県)
    • Related Report
      2011 Research-status Report
  • [Presentation] 新規勘定ホスト分子Pillar[5]areneを基にした超分子材料の創成2012

    • Author(s)
      生越友樹
    • Organizer
      日本化学会年会(招待講演)
    • Place of Presentation
      慶應義塾大学日吉キャンパス(神奈川県)
    • Related Report
      2011 Research-status Report
  • [Remarks] ホームページ

    • URL

      http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html

    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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