A Precursor for Chiral Separation during Crystallization
| Project/Area Number |
23656005
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Applied materials science/Crystal engineering
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| Research Institution | Tohoku University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | キラル / 結晶成長 / その場観察 / 準安定 / 核形成 / 相転移 / 準安定相 |
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| Research Abstract |
To understand the chiral symmetry breaking during crystallization of NaClO3, we directly observed the initial stage of crystallization from an aqueous solution by usingpolarized-light microscopy. Crystallization of an achiral metastable phase and its transformation into a chiral cubic phase were observed in situ for the first time. The crystal structure of the achiral metastable phase was analyzed by cryogenic single-crystal X-ray structural analysis. The achiral metastable phase was monoclinic with a = 8.42, b = 5.26, c = 6.70 A, and = 109.71o, space group P21/a. As they grew larger, the achiral monoclinic crystals transformed into chiral cubic crystals, showing that the achiral phase acts as aprecursor of the chiral phase.
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Report
(3 results)
Research Products
(65 results)
