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Local doping to organic semiconductors

Research Project

Project/Area Number 23656011
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Applied materials science/Crystal engineering
Research InstitutionTohoku University

Principal Investigator

SHIMOTANI Hidekazu  東北大学, 大学院・理学研究科, 准教授 (60418613)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords有機 / 分子エレクトロニクス / 分子性固体 / 有機トランジスタ / 電気二重奏トランジスタ / 有機半導体 / カーボンナノチューブ / 電界効果トランジスタ / 電気二重層
Research Abstract

Dependence on carrier concentration of carrier mobility and contact resistance of carrier injection from a metal electrode were measured for organic semiconductor single crystals. The carrier concentration was controlled by an electric double-layer transistor (EDLT)structure employing an ionic liquid as an electrolyte. The contact resistance from a gold electrode to the organic semiconductor firstly decreased by increasing the carrier concentration, and then increased by increasing the carrier concentration. The carrier concentration dependence of the contact resistance is inversely proportional to that of carrier mobility. This behavior is well explained by the diffusion-limited thermionic emission model.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (30 results)

All 2012 2011

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (19 results) (of which Invited: 1 results)

  • [Journal Article] Ambipolar Organic Single-Crystal Transistors Based on Ion Gels2012

    • Author(s)
      Y. Yomogida、J. Pu、H. Shimotani、S. Ono 、S. Hotta 、Y. Iwasa 、T.Takenobu
    • Journal Title

      Advanced Materials

      Volume: Vol.24 Issue: 32 Pages: 4392-4397

    • DOI

      10.1002/adma.201200655

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] External electric field dependence of the structure of the electric double layer at an ionic liquid/Au interface2012

    • Author(s)
      R. Yamamoto, H. Morisaki, O. Sakata, H. Shimotani, H. T. Yuan, Y. Iwasa, T. Kimura, Y. Wakabayashi
    • Journal Title

      Applied Physics Letters

      Volume: 101 Issue: 5 Pages: 053122-053122

    • DOI

      10.1063/1.4742920

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electric-field-induced superconductivity at 9.4 K in a layered transition metal disulphide MoS22012

    • Author(s)
      Kouji Taniguchi, Akiyo Matsumoto, Hidekazu Shimotani, Hidenori Takagi
    • Journal Title

      Applied Physics Letters

      Volume: 101 Issue: 4 Pages: 042603-042603

    • DOI

      10.1063/1.4740268

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tunable Spin-Orbit Interaction in Trilayer Graphene Exemplified in Electric-Double-Layer Transistors2012

    • Author(s)
      Z. Y. Chen、H. T. Yuan、Y. F. Zhang、K. Nomura、T. Gao、H. Shimotani、Z. F. Liu 、Y. Iwasa
    • Journal Title

      Nano Letters

      Volume: Vol.12 Issue: 5 Pages: 2212-2216

    • DOI

      10.1021/nl204012c

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Strain-Mediated Phase Control and Electrolyte-Gating of Electron-Doped Manganites2011

    • Author(s)
      P.H.Xiang, S.Asanuma, H.Yamada, I.H. Inoue, H.Sato, H.Akoh, A.Sawa, K.Ueno, H.T.Yuan, H.Shimotani, M.Kawasaki, Y.Iwasa
    • Journal Title

      Advanced Materials

      Volume: 23 Issue: 48 Pages: 5822-5827

    • DOI

      10.1002/adma.201102968

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Molecular thermal contraction of the Ar@C_<60> endohedral fullerene2011

    • Author(s)
      N. Dragoe, A. M. Flank, P. Lagarde, S.Ito, H. Shimotani, H. Takagi
    • Journal Title

      Physical Review B

      Volume: 84巻 Issue: 15 Pages: 155448-155448

    • DOI

      10.1103/physrevb.84.155448

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Accessing the transport properties of graphene and its multilayers at high carrier density2011

    • Author(s)
      J. T. Ye、M. F. Craciun、M. Koshino、S. Russo、S. Inoue、H. T. Yuan、H. Shimotani, A. F. Morpurgo、Y. Iwasa
    • Journal Title

      Proceedings of the National Academy of Sciences of the United States of America

      Volume: Vol.108 Issue: 32 Pages: 13002-13006

    • DOI

      10.1073/pnas.1018388108

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hole reduction and electron accumulation in YBa_2Cu_3O_y thin films using an electrochemical technique : Evidence for an n-type metallic state2011

    • Author(s)
      T. Nojima、H. Tada、S. Nakamura、N. Kobayashi、H. Shimotani、Y. Iwasa
    • Journal Title

      Physical Review B

      Volume: Vol.84 Issue: 2 Pages: 20502-20502

    • DOI

      10.1103/physrevb.84.020502

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Liquid-Gated Ambipolar Transport in Ultrathin Films of a Topological Insulator Bi_2Te_32011

    • Author(s)
      H.T.Yuan, H.W.Liu, H.Shimotani, H.Guo, M.W.Chen, Q.K.Xue, Y.Iwasa
    • Journal Title

      Nano Letters

      Volume: 11 Issue: 7 Pages: 2601-2605

    • DOI

      10.1021/nl201561u

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Discovery of superconductivity in KTaO3 by electrostatic carrier doping2011

    • Author(s)
      K. Ueno、S. Nakamura、H. Shimotani、H. T. Yuan、N. Kimura、T. Nojima、H. Aoki、Y. Iwasa、M. Kawasaki
    • Journal Title

      Nature Nanotechnology

      Volume: Vol.6 Issue: 7 Pages: 408-412

    • DOI

      10.1038/nnano.2011.78

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrically Induced Ferromagnetism at Room Temperature in Gobalt-Doped Titanium Dioxide2011

    • Author(s)
      Y.Yamada, K.Ueno, T.Fukumura, H.T.Yuan, H.Shimotani, Y.Iwasa, L.Gu, S.Tsukimoto, Y.Ikuhara, M.Kawasaki
    • Journal Title

      SCIENCE

      Volume: 332 Issue: 6033 Pages: 1065-1067

    • DOI

      10.1126/science.1202152

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Continuous Carrier Tuning in Metallic and Semiconducting SWNT Film2012

    • Author(s)
      Hidekazu Shimotani, Satoshi Tsuda, Hongtao Yuan, Yohei Yomogida, Rieko Moriya, Taishi Takenobu, Kazuhiro Yanagi, Yoshihiro Iwasa
    • Organizer
      Japan-France Seminar : Physics and Control of Clustering Crystals
    • Place of Presentation
      淡路夢舞台国際会議場(淡路市)
    • Related Report
      2012 Final Research Report
  • [Presentation] EDLT of SWNT: single bundle and thin film2012

    • Author(s)
      Hidekazu Shimotani
    • Organizer
      EDLT TOKYO
    • Place of Presentation
      東京大 学(東京)
    • Related Report
      2012 Final Research Report
  • [Presentation] 固液界面の強電場を利用したキャリア制御による電子相転移の発現2012

    • Author(s)
      下谷秀和
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大(兵庫県)
    • Related Report
      2012 Final Research Report
  • [Presentation] 電気二重層トランジスタによる金属・有機界面のキャリア注入機構の解明2012

    • Author(s)
      下谷秀和
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学ユビキタス元素戦略」配列ナノ空間研究会(第3回)
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Final Research Report
  • [Presentation] One-dimensional nature in transport property of SWNT thin film electrochemical transistor2012

    • Author(s)
      Hidekazu Shimotani, Satoshi Tsuda, Hongtao Yuan, Yohei Yomogida, Rieko Moriya, Taishi Takenobu, Kazuhiro Yanagi, Yoshihiro Iwasa
    • Organizer
      APS March Meeting 2012
    • Place of Presentation
      ボストン(アメリカ)
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属・半導体分離単層カーボンナノチューブ薄膜の連続的キャリア濃度制御2012

    • Author(s)
      下谷秀和
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学ユビキタス元素戦略」第9回領域会議
    • Place of Presentation
      物質・材料研究機構(茨城県)
    • Related Report
      2012 Final Research Report
  • [Presentation] EDLT of SWNT: single bundle and thin film2012

    • Author(s)
      Hidekazu Shimotani
    • Organizer
      EDLT TOKYO
    • Place of Presentation
      東京大学(東京)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Continuous Carrier Tuning in Metallic and Semiconducting SWNT Film2012

    • Author(s)
      Hidekazu Shimotani
    • Organizer
      Japan-France Seminar : Physics and Control of Clustering Crystals
    • Place of Presentation
      淡路夢舞台国際会議場(淡路市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金属・半導体分離単層カーボンナノチューブ薄膜の連続的キャリア濃度制御2012

    • Author(s)
      下谷秀和
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学 ユビキタス元素戦略」第9回領域会議
    • Place of Presentation
      物質・材料研究機構(茨城県)
    • Related Report
      2011 Research-status Report
  • [Presentation] 電気二重層トランジスタによる金属・有機界面のキャリア注入機構の解明2012

    • Author(s)
      下谷秀和
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学 ユビキタス元素戦略」配列ナノ空間研究会(第3回)
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2011 Research-status Report
  • [Presentation] 固液界面の強電場を利用したキャリア制御による電子相転移の発現2012

    • Author(s)
      下谷秀和
    • Organizer
      日本物理学会 第67回年次大会(招待講演)
    • Place of Presentation
      関西学院大(兵庫県)
    • Related Report
      2011 Research-status Report
  • [Presentation] One-dimensional nature in transport property of2012

    • Author(s)
      Hidekazu Shimotani
    • Organizer
      APS March Meeting 2012
    • Place of Presentation
      Boston Convention Center(アメリカ)
    • Related Report
      2011 Research-status Report
  • [Presentation] 金属・半導体分離単層カーボンナノチューブ薄膜の連続的キャリア濃度制御2011

    • Author(s)
      下谷秀和
    • Organizer
      第5回物性科学領域横断研究会
    • Place of Presentation
      東北大学(宮城県)
    • Year and Date
      2011-11-20
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] 金属・半導体分離SWNT薄膜の1次元的伝導特性2011

    • Author(s)
      下谷秀和,津田諭,袁洪涛,蓬田陽平,守屋理恵子,竹延大志,柳和宏,岩佐義宏
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2011-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] One-Dimensional Electronic Transport in Nanotube Random Network Transistors at Room Temperature2011

    • Author(s)
      Hidekazu Shimotani, Satoshi Tsuda, Hongtao Yuan, Yohei Yomogida, Rieko Moriya, Taishi Takenobu, Kazuhiro Yanagi, Yoshihiro Iwasa
    • Organizer
      2011 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Hynes Convention Center、ボストン(アメリカ)
    • Related Report
      2012 Final Research Report
  • [Presentation] Continuous Carrier Tuning in Metallic and Semiconducting SWNT Film2011

    • Author(s)
      下谷秀和
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学」若手研究会
    • Place of Presentation
      東北大学北青葉山キャンパス(宮城県)
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属・半導体分離SWNT薄膜の1次元的伝導特性2011

    • Author(s)
      下谷秀和
    • Organizer
      日本物理学会 2011年秋季大会
    • Place of Presentation
      富山大学(富山県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Continuous Carrier Tuning in Metallic and Semiconducting SWNT Film2011

    • Author(s)
      下谷秀和
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学」若手研究会
    • Place of Presentation
      東北大学(宮城県)
    • Related Report
      2011 Research-status Report
  • [Presentation] One-Dimensional Electronic Transport in Nanotube Random Network Transistors at Room Temperature2011

    • Author(s)
      Hidekazu Shimotani
    • Organizer
      2011 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Hynes Convention Center(アメリカ)
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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