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Recovery of half-metallicity of oxide surfaces and its application to spin injection

Research Project

Project/Area Number 23656034
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

KURAHASHI Mitsunori  独立行政法人物質・材料研究機構, 極限計測ユニット, 主席研究員 (10354359)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords表面・界面物性 / 磁性 / 酸化物
Research Abstract

Half-metallic ferromagnets are important materials in the field of spintronics, but the spin polarization at their surfaces or interfaces is usually much lower than 100%, causing the transport properties of the devices much lower than expected from the bulk spin polarization. We have previously reported that the surface spin polarization of Fe3O4(100) can be drastically improved by hydrogen termination. In this study, we analyzed this phenomena for an Fe3O4(111) surface and tried to utilize it for inducing high spin polarization to adsorbed molecules. We clarified that the spin polarization at the (111) surface is positive unexpectedly and is not improved by H termination. This would originate from the fact that the tetrahedrally-cordinated Fe terminates the (111) surface.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (36 results)

All 2014 2013 2012 2011 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (19 results) (of which Invited: 1 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Significant variation of surface spin polarization through group IV atom (C Si Ge Sn) adsorption on Fe_3O_4(100)2014

    • Author(s)
      X. Sun, S. D. Li, B. Wang, M. Kurahashi, A. Pratt, Y . Yamauchi
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 16[1] Pages: 95-102

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Significant variation of surface spin polarization through group IV atom (C Si Ge Sn) adsorption on Fe3O4(100)2014

    • Author(s)
      X. Sun, S. D. Li, B. Wang, M. Kurahashi, P. Andrew, Y. Yamauchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 16 Issue: 1 Pages: 95-102

    • DOI

      10.1039/c3cp53272k

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin polarization of single-layer graphene epitaxially grown on Ni(111) thin film2013

    • Author(s)
      S. Entani, M. Kurahashi, X. Sun, Y. Yamauchi
    • Journal Title

      Carbon

      Volume: 61 Pages: 134-139

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spin polarization study of graphene on the Ni(111) surface by density functional theory calculations with a semiempirical long-range dispersion correction2013

    • Author(s)
      X. Sun, S Entani, Y . Yamauchi, A. Pratt, M. Kurahashi
    • Journal Title

      J. Appl. Phys

      Volume: 114[14] Pages: 143713-143713

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spin polarization study of graphene on the Ni(111) surface by density functional theory calculations with a semiempirical long-range dispersion correction2013

    • Author(s)
      X. Sun, S Entani, Y. Yamauchi, P. Andrew, M. Kurahashi
    • Journal Title

      J. Appl. Phys.

      Volume: 114 Issue: 14 Pages: 143713-1

    • DOI

      10.1063/1.4824186

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Energy-level alignment at the Alq3/Fe_3O_4(001) interface2012

    • Author(s)
      A. Pratt, L. Dunne, X. Sun, M. Kurahashi and Y . Yamauchi
    • Journal Title

      J. Appl. Phys

      Volume: 111[7]

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of a positive spin polarization at the (111) surface of magnetite2012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, D. Gilks and Y . Yamauchi
    • Journal Title

      Phys. Rev. B

      Volume: 85 Pages: 180409-180409

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic properties of O_2 adsorbed on Cu(100) : A spin-polarized metastable He beam study2012

    • Author(s)
      M. Kurahashi, X. Sun, Y . Yamauchi
    • Journal Title

      Phys. Rev . B

      Volume: 86[24] Pages: 245421-245421

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic properties of O2 adsorbed on Cu(100): A spin-polarized metastable He beam study2012

    • Author(s)
      M. Kurahashi, X. Sun, Y. Yamauchi
    • Journal Title

      Physical Review B

      Volume: 86 Issue: 24

    • DOI

      10.1103/physrevb.86.245421

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct observation of a positive spin polarization at the (111) surface of magnetite2012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, D. Gilks and Y. Yamauchi
    • Journal Title

      Physical Review B

      Volume: 85 Issue: 18

    • DOI

      10.1103/physrevb.85.180409

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Energy-level alignment at the Alq3/Fe3O4(001) interface2012

    • Author(s)
      A. Pratt, L. Dune, X. Sun. M. Kurahashi. Y. Yamauchi
    • Journal Title

      Journal of Applied Physics

      Volume: 111 Issue: 7

    • DOI

      10.1063/1.3677768

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Spin polarization of the Si(111)-7x7 surface: A study with a spin-polarized metastable helium atom beam2011

    • Author(s)
      M. Kurahashi, A. Pratt, Y. Yamauchi
    • Journal Title

      Surface science

      Volume: 605 Issue: 5-6 Pages: 612-615

    • DOI

      10.1016/j.susc.2010.12.027

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] First-principles study of atomic hydrogen adsorption on Fe3O4(100)2011

    • Author(s)
      X. Sun, M. Kurahashi, Y. Yamauchi
    • Journal Title

      Surface science

      Volume: 605 Issue: 11-12 Pages: 1067-1073

    • DOI

      10.1016/j.susc.2011.03.006

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Adsorbate-induced spin-polarization enhancement of Fe3O4(0 0 1)2011

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, Y.Yamauchi
    • Journal Title

      Journal of Applied Physics

      Volume: 44 Issue: 6 Pages: 640101-640105

    • DOI

      10.1088/0022-3727/44/6/064010

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Advances in the use of a spin-polarized metastable helium beam to characterize surface magnetic properties2014

    • Author(s)
      A. Pratt, M. Kurahashi, Xia Sun, Y . Yamauchi
    • Organizer
      20th International Workshop on Inelastic Ion-Surface Collisions
    • Place of Presentation
      Adelaide
    • Related Report
      2013 Final Research Report
  • [Presentation] Advances in the use of a spin-polarized metastable helium beam to characterize surface magnetic properties2014

    • Author(s)
      P. Andrew, M. Kurahashi, Xia Sun, Y. Yamauchi
    • Organizer
      20th International Workshop on Inelastic Ion-Surface Collisions
    • Place of Presentation
      Adelaide, Australia
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Tailoring surface properties for molecular spintronics2013

    • Author(s)
      A. Pratt, M.Kurahashi, Y . Yamauchi
    • Organizer
      Invited seminar at EWHA University Seoul Korea
    • Place of Presentation
      Seoul
    • Year and Date
      2013-05-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 磁性体に接する単層グラフェンのスピン偏極2013

    • Author(s)
      孫霞, 圓谷志郎, 倉橋光紀, 山内泰
    • Organizer
      2013年真空・表面科学合同講演会
    • Place of Presentation
      つくば
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 有機半導体/酸化物界面における分子配向の温度依存性2013

    • Author(s)
      Andrew Pratt, Y u Jeong Bae, Xia Sun, 倉橋光紀, Nyun Jong Lee, T ae Hee Kim, 山内泰
    • Organizer
      Japan Society of Applied Physics Autumn Meeting
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Tailoring surface properties for molecular spintronics2013

    • Author(s)
      A. Pratt, M. Kurahashi, Xia Sun, Y . Yamauchi
    • Organizer
      JSPS York-Tohoku Symposium on Spintronics
    • Place of Presentation
      York
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] intrinsic spin polarity at the surface of ferrite thin films2013

    • Author(s)
      P. Andrew, M. Kurahashi, Xia Sun, Y. Yamauchi
    • Organizer
      58th MMM Conference 2013
    • Place of Presentation
      Denver,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Tailoring the spin polarization at the surface of Fe_3O_42012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, Y . Yamauchi
    • Organizer
      IUMRS-International Conference on Electronic Materials
    • Place of Presentation
      Yokohama
    • Related Report
      2013 Final Research Report
  • [Presentation] A spin-polarized metastable helium beam for organic spintronics2012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, Y . Y amauchi
    • Organizer
      4th International Meeting on Spins in Organic Semiconductors
    • Place of Presentation
      London
    • Related Report
      2013 Final Research Report
  • [Presentation] Intrinsic spin polarity at the magnetite Fe_3O_4 surface2012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, Y . Yamauchi
    • Organizer
      The 24th conference of the EPS condensed matter division
    • Place of Presentation
      Edinburgh
    • Related Report
      2013 Final Research Report
  • [Presentation] Direct evidence for positive spin polarization at the Fe_3O_4(111) surface2012

    • Author(s)
      A. Pratt, 倉橋光紀 , 孫霞 , 山内泰
    • Organizer
      日本物理学会年次大会
    • Place of Presentation
      神戸
    • Related Report
      2013 Final Research Report
  • [Presentation] Tailoring the spin polarization at the surface of Fe3O42012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, Y. Yamauchi
    • Organizer
      IUMRS-International Conference on Electronic Materials 2012
    • Place of Presentation
      PACIFICO YOKOHAMA,yokohama,Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] 低濃度オゾンを用いたビーム生成技術2012

    • Author(s)
      山内泰, AndrewPratt, 倉橋光紀
    • Organizer
      2012年 秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学、松山
    • Related Report
      2012 Research-status Report
  • [Presentation] A spin-polarized metastable helium beam for organic spintronics2012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun
    • Organizer
      4th International Meeting on Spins in Organic Semiconductors
    • Place of Presentation
      Queen Mary University of London,London,UK
    • Related Report
      2012 Research-status Report
  • [Presentation] Intrinsic spin polarity at the magnetite Fe3O4 surface2012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, Y. Yamauchi
    • Organizer
      The 24th conference of the EPS condensed matter division
    • Place of Presentation
      Edinburgh convention center, Edinburgh, UK
    • Related Report
      2012 Research-status Report
  • [Presentation] Direct evidence for positive spin polarization at the Fe3O4(111) surface2012

    • Author(s)
      A. Pratt, M. Kurahashi, X. Sun, D. Gilks, Y. Yamauchi
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 表面修飾によるFe3O4最表面ハーフメタル性回復現象2011

    • Author(s)
      倉橋光紀
    • Organizer
      PF研究会(招待講演)
    • Place of Presentation
      高エネルギー物理学研究所
    • Related Report
      2011 Research-status Report
  • [Presentation] Surface sensitive determination of energy-level alignment at organic semiconductor/ferromagnetic interfaces2011

    • Author(s)
      A. Pratt, X. Sun, L. Dune, M. Kurahashi, Y. Yamauchi
    • Organizer
      56th Annual Conference on Magnetism and Magnetic Materials
    • Place of Presentation
      The JW Marriot Desert Ridge Resort,Scottsdale, Arizona
    • Related Report
      2011 Research-status Report
  • [Presentation] Hybridization and exchange coupling at organic semiconductor/ferromagnetic heterojunctions2011

    • Author(s)
      A. Pratt, X. Sun, L. Dune, M. Kurahashi, Y. Yamauchi
    • Organizer
      56th Annual Conference on Magnetism and Magnetic Materials
    • Place of Presentation
      The JW Marriot Desert Ridge Resort,Scottsdale, Arizona
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/KURAHASHI_Mitsunori-j.html

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/KURAHASHI_Mitsunori-j.html

    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] オゾンビーム発生装置2012

    • Inventor(s)
      山内泰, プラットアンドリュー, 倉橋光紀
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2013-256398
    • Filing Date
      2012-06-12
    • Related Report
      2013 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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