| Project/Area Number |
23656218
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Electronic materials/Electric materials
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| Research Institution | Osaka University |
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Principal Investigator |
KAJII Hirotake 大阪大学, 大学院・工学研究科, 助教 (00324814)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
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| Keywords | 電子・電気材料 / 電子デバイス / 有機導体 / 分子性固体 / 光物性 / 有機発光トランジスタ |
|---|
| Research Abstract |
In order to obtain phosphorescent emission from organic field-effect transistors, thermal diffusion of a phosphorescent dye at the interface between the active layer and gate insulator was controlled by utilizing the fact that liquid-crystalline semiconducting polymers self-organize due to reorientation of the molecules and increase in the size of the crystalline regions during thermal annealing. For top-gate type devices using poly(alkylfluorene) doped with a red emissive phosphorescent material, ambipolar characteristics and red emission from the phosphorescent material were clearly observed. We demonstrate the possibility of producing phosphorescent organic light-emitting transistors using a liquid-crystalline semiconducting polymer doped with phosphorescent emissive dopants by the thermal diffusion method.
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