| Project/Area Number |
23656242
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Electron device/Electronic equipment
|
|---|
| Research Institution | Yamaguchi University |
|---|
Principal Investigator |
HONDA Kensuke 山口大学, 大学院・理工学研究科, 准教授 (60334314)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
|---|
| Keywords | ダイヤモンドライクカーボン / 半導体 / センサー材料 / アモルファスカーボン / ホウ素 / 電気化学触媒 / マンガンイオン検出 / ナノ微粒子 / 電気化学ガスセンサー / 半導体材料ガス / 高感度検出 |
|---|
| Research Abstract |
The objective of this study was to create a-C surface with higher electro-catalytic activity by controlling chemical compositions and sizes of amorphous carbon nano-particles, and to establish the electrochemical method to detect hazardous materials like AsH3and PH3quantitatively. The concentration of dopant atoms showing p type conductivity was tried to be controlled. Carrier concentration of p-type a-C could be successfully varied in the range from 1014cm-3to 1.3×1019cm-3 by changing the ratio of trimethyl borateand n-hexane used as source materials. Boron atoms were confirmed to serve as an electro-catalyst for hydrogen evolution. Since the reactivity to hydrogen evolution could be suppressed at a-C films doped with tiny amounts of boron, Mn2+ion could be efficiently reduced. It results that Mn2+ion at extremely lower concentration (0.02 mM) than discharge standard (0.2 mM) could be detected quantitatively.
|
