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Control of electrochemical reaction by amorphous carbon nano-particles and development of high-sensitive gas sensor

Research Project

Project/Area Number 23656242
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electron device/Electronic equipment
Research InstitutionYamaguchi University

Principal Investigator

HONDA Kensuke  山口大学, 大学院・理工学研究科, 准教授 (60334314)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsダイヤモンドライクカーボン / 半導体 / センサー材料 / アモルファスカーボン / ホウ素 / 電気化学触媒 / マンガンイオン検出 / ナノ微粒子 / 電気化学ガスセンサー / 半導体材料ガス / 高感度検出
Research Abstract

The objective of this study was to create a-C surface with higher electro-catalytic activity by controlling chemical compositions and sizes of amorphous carbon nano-particles, and to establish the electrochemical method to detect hazardous materials like AsH3and PH3quantitatively. The concentration of dopant atoms showing p type conductivity was tried to be controlled. Carrier concentration of p-type a-C could be successfully varied in the range from 1014cm-3to 1.3×1019cm-3 by changing the ratio of trimethyl borateand n-hexane used as source materials. Boron atoms were confirmed to serve as an electro-catalyst for hydrogen evolution. Since the reactivity to hydrogen evolution could be suppressed at a-C films doped with tiny amounts of boron, Mn2+ion could be efficiently reduced. It results that Mn2+ion at extremely lower concentration (0.02 mM) than discharge standard (0.2 mM) could be detected quantitatively.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (39 results)

All 2012 2011 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (24 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] High Sensitive Amperometric Detection of Glucose using Conductive DLC Electrode in Higher Potential Region2012

    • Author(s)
      Kensuke Honda, Akira Nakahara, Hiroshi Naragino, Kohsuke Yoshinaga, Sakuya Tanaka
    • Journal Title

      ECS transactions

      Volume: Vol. 50 (12) Pages: 377-383

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of Conductivity by incorporation of Boron atoms in Hydrogenated Amorphous Carbon Films fabricated by Plasma CVD methods and its Electrochemical Properties2012

    • Author(s)
      Hiroshi Naragino, Kohsuke Yoshinaga, Seiji Tatsuta, Kensuke Honda
    • Journal Title

      ECS transactions

      Volume: 41 (20) Pages: 59-68

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of porous platinum-ion-doped titanium dioxide and the photocatalytic degradation of 4-chlorophenol under visible light irradiation2012

    • Author(s)
      Suzuko Yamazaki, Yuhei Fujiwara, Shinya Yabuno, Kenta Adachi, Kensuke Honda
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: Vol. 121-122 Pages: 148-153

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Detection of Sugar-related Compounds Using Boron-doped Diamond Electrodes2012

    • Author(s)
      Tomohisa HAYASHI, Ikuo SAKURADA, Kensuke HONDA, Shigeyasu MOTOHASHI and Kazuo UCHIKURA
    • Journal Title

      Analytical Sciences

      Volume: Vol. 28 No. 2 Pages: 127-133

    • NAID

      10030446584

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic characteristics of enhanced photochromism in tungsten oxide nanocolloid adsorbed on cellulose substrates, studied by total internal reflection Raman Spectroscopy2012

    • Author(s)
      Kenta Adachi, Tomohiro Mita, Shohei Tanaka, Kensuke Honda, Suzuko Yamazaki, Masaharu Nakayama, Takeyosi Goto, Hiroshi Watarai
    • Journal Title

      RSC Advances

      Volume: 2 Pages: 2128-2136

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Controllable Electrochemical Activities by Oxidative Treatment toward Inner Sphere Redox Systems at N-doped Hydrogenated Amorphous Carbon Films2012

    • Author(s)
      Yoriko Tanaka, Hiroshi Naragino, Kohsuke Yoshinaga, Akira Nakahara, Takeshi Kondo, Akira Fujishima, Kensuke Honda
    • Journal Title

      International Journal of Electrochemistry

      Volume: Vol. 2012 Pages: 14-14

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] High Sensitive Amperometric Detection of Glucose using Conductive DLC Electrode in Higher Potential Region2012

    • Author(s)
      Kensuke Honda
    • Journal Title

      ECS transactions

      Volume: Vol. 50 Pages: 377-383

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of Conductivity by incorporation of Boron atoms in Hydrogenated Amorphous Carbon Films fabricated by Plasma CVD methods and its Electrochemical Properties2012

    • Author(s)
      Hiroshi Naragino
    • Journal Title

      ECS transactions

      Volume: Vol. 41 Pages: 59-68

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Detection of Sugar-related Compounds Using Boron-doped Diamond Electrodes2012

    • Author(s)
      Tomohisa HAYASHI, Ikuo SAKURADA, Kensuke HONDA, Shigeyasu
    • Journal Title

      Analytical Sciences

      Volume: 28 Issue: 2 Pages: 127-127

    • DOI

      10.2116/analsci.28.127

    • NAID

      130004827193

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Kinetic characteristics of enhanced photochromism in tungsten oxide nanocolloid adsorbed on cellulose substrates, studied by total internal2012

    • Author(s)
      Kenta Adachi, Tomohiro Mita, Shohei Tanaka, Kensuke Honda
    • Journal Title

      RSC Advances

      Volume: 2 Issue: 5 Pages: 2128-2136

    • DOI

      10.1039/c2ra00217e

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controllable Electrochemical Activities by Oxidative Treatment toward Inner Sphere Redox Systems at N-doped Hydrogenated Amorphous Carbon Films2012

    • Author(s)
      Yoriko Tanaka, Hiroshi Naragino, Kosuke Yoshinaga, Akira Nakahara, Takeshi Kondo, Akira Fujishima, Kensuke Honda
    • Journal Title

      International Journal of Electrochemistry

      Volume: Vol.2012 Pages: 14-27

    • DOI

      10.1155/2012/369130

    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrically-Switchable, Permselective Membranes Prepared from Nano-structured N-doped DLC2011

    • Author(s)
      Kensuke Honda, Masayoshi Yoshimatsu, Koichi Kuriyama, Ryosuke Kuwabara,a Hiroshi Naragino, Kosuke Yoshinaga, Takeshi Kondo, Akira Fujishima
    • Journal Title

      Diamond and Related Materials

      Volume: 20 Pages: 1110-1120

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrically-Switchable, Permselective Membranes Prepared from Nano-structured N-doped DLC2011

    • Author(s)
      Kensuke Honda, Masayoshi Yoshimatsu, Koichi Kuriyama, Ryosuke Kuwabara, Hiroshi Naragino, Kosuke Yoshinaga, Takeshi Kondo, Akira Fujishima
    • Journal Title

      Diamond and Related Materials

      Volume: 20 Issue: 8 Pages: 1110-1120

    • DOI

      10.1016/j.diamond.2011.06.017

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Fabrication of N-Type Semiconductive Polycrystalline Diamond by incorprating Phosphorous Atoms2012

    • Author(s)
      Akira Nakahara, Hiroshi Naragino, Kousuke Yoshinaga, Sakuya Tanaka, Kensuke Honda
    • Organizer
      PRiME 2012
    • Place of Presentation
      Honolulu, 米国
    • Year and Date
      2012-10-10
    • Related Report
      2012 Final Research Report
  • [Presentation] Enhancement of Electrical Conductivity and Electrochemical Activity of Hydrogenated Amorphous Carbon by incorporating Boron Atoms2012

    • Author(s)
      Hiroshi Naragino, Kohsuke Yoshinaga, Akira Nakahara, Sakuya Tanaka, Kensuke Honda
    • Organizer
      PRiME 2012
    • Place of Presentation
      Honolulu, 米国
    • Year and Date
      2012-10-10
    • Related Report
      2012 Final Research Report
  • [Presentation] High Sensitive Amperometric Detection of Glucose using Conductive DLC Electrode in Higher Potential Region2012

    • Author(s)
      Kensuke Honda, Hiroshi Naragino, Kohsuke Yoshinaga, Akira Nakahara, Sakuya Tanaka
    • Organizer
      PRiME 2012
    • Place of Presentation
      Honolulu, 米国
    • Year and Date
      2012-10-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication of Silicon and Carbon Based Wide-Gap Semiconductor Thin Films for High Conversion Efficiency2012

    • Author(s)
      Kohsuke Yoshinaga, Hiroshi Naragino, Akira Nakahara, Sakuya Tanaka, Kensuke Honda
    • Organizer
      PRiME 2012
    • Place of Presentation
      Honolulu, 米国
    • Year and Date
      2012-10-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Enhancement of Electrical Conductivity and Electrochemical Activity of Hydrogenated Amorphous Carbon by incorporating Boron Atoms2012

    • Author(s)
      Hiroshi Naragino, Kohsuke Yoshinaga, Akira Nakahara, Sakuya Tanaka, Kensuke Honda
    • Organizer
      The 11th APCPST and 25th SPSM
    • Place of Presentation
      京都
    • Year and Date
      2012-10-04
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication of N-Type Semiconductive Polycrystalline Diamond by incorprating Phosphorous Atoms2012

    • Author(s)
      Akira Nakahara, Hiroshi Naragino, Kousuke Yoshinaga, Sakuya Tanaka, Kensuke Honda
    • Organizer
      The 11th APCPST and 25th SPSM
    • Place of Presentation
      京都大学桂キャンパス 京都
    • Year and Date
      2012-10-04
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication of Silicon and Carbon Based Wide-Gap Semiconductor Thin Films for High Conversion Efficiency2012

    • Author(s)
      Kohsuke Yoshinaga, Hiroshi Naragino, Akira Nakahara, Sakuya Tanaka, Kensuke Honda
    • Organizer
      The 11th APCPST and 25th SPSM
    • Place of Presentation
      京都大学桂キャンパス 京都
    • Year and Date
      2012-10-04
    • Related Report
      2012 Final Research Report
  • [Presentation] High Sensitive Amperometric Detection of Glucose using Conductive DLC Electrode in Higher Potential Region2012

    • Author(s)
      Kensuke Honda, Hiroshi Naragino, Kohsuke Yoshinaga, Akira Nakahara, Sakuya Tanaka
    • Organizer
      The 11th APCPST and 25th SPSM
    • Place of Presentation
      京都大学桂キャンパス 京都
    • Year and Date
      2012-10-04
    • Related Report
      2012 Final Research Report
  • [Presentation] ホウ素ドープdiamond-like carbon薄膜のホウ素添加量に対する電気化学反応性2012

    • Author(s)
      楢木野宏・吉永浩亮・中原亮・本多謙介
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学日吉キャンパス 横浜市
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 不純物原子添加による n 型半導体性多結晶ダイヤモンドの作製と物理デバイスへの応用2012

    • Author(s)
      中原亮・本多謙介・楢木野 宏・吉永浩亮
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学日吉キャンパス 横浜市
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] High Sensitive Amperometric Detection of Glucose using Conductive DLC Electrode in Higher Potential Region2012

    • Author(s)
      Kensuke Honda
    • Organizer
      PRiME 2012
    • Place of Presentation
      ホノルル(アメリカ合衆国)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication of Silicon and Carbon Based Wide-Gap Semiconductor Thin Films for High Conversion Efficiency2012

    • Author(s)
      Kohsuke Yoshinaga
    • Organizer
      PRiME 2012
    • Place of Presentation
      ホノルル(アメリカ合衆国)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication of N-Type Semiconductive Polycrystalline Diamond by incorprating Phosphorous Atoms2012

    • Author(s)
      Akira Nakahara
    • Organizer
      PRiME 2012
    • Place of Presentation
      ホノルル(アメリカ合衆国)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Enhancement of Electrical Conductivity and Electrochemical Activity of Hydrogenated Amorphous Carbon by incorporating Boron Atoms2012

    • Author(s)
      Hiroshi Naragino
    • Organizer
      PRiME 2012
    • Place of Presentation
      ホノルル(アメリカ合衆国)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Enhancement of Electrical Conductivity and Electrochemical Activity of Hydrogenated Amorphous Carbon by incorporating Boron Atoms2012

    • Author(s)
      Hiroshi Naragino
    • Organizer
      11th Asia Pacific Conference on Plasma Science and Technology
    • Place of Presentation
      京都大学桂キャンパスローム記念館(京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication of N-Type Semiconductive Polycrystalline Diamond by incorprating Phosphorous Atoms2012

    • Author(s)
      Akira Nakahara
    • Organizer
      11th Asia Pacific Conference on Plasma Science and Technology
    • Place of Presentation
      京都大学桂キャンパスローム記念館(京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication of Silicon and Carbon Based Wide-Gap Semiconductor Thin Films for High Conversion Efficiency2012

    • Author(s)
      Kohsuke Yoshinaga
    • Organizer
      11th Asia Pacific Conference on Plasma Science and Technology
    • Place of Presentation
      京都大学桂キャンパスローム記念館(京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] High Sensitive Amperometric Detection of Glucose using Conductive DLC Electrode in Higher Potential Region2012

    • Author(s)
      Kensuke Honda
    • Organizer
      11th Asia Pacific Conference on Plasma Science and Technology
    • Place of Presentation
      京都大学桂キャンパスローム記念館(京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ホウ素ドープdiamond-like carbon薄膜のホウ素添加量に対する電気化学反応性2012

    • Author(s)
      楢木野宏・吉永浩亮・中原亮・本多謙介
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学日吉キャンパス 横浜市
    • Related Report
      2011 Research-status Report
  • [Presentation] 不純物原子添加によるn型半導体性多結晶ダイヤモンドの作製と物理デバイスへの応用2012

    • Author(s)
      中原亮・本多謙介・楢木野 宏・吉永浩亮
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学日吉キャンパス 横浜市
    • Related Report
      2011 Research-status Report
  • [Presentation] 楢木野宏,吉永浩亮,中原亮,本多謙介2011

    • Author(s)
      楢木野宏,吉永浩亮,中原亮,本多謙介
    • Organizer
      2011 年日本化学会西日本大会
    • Place of Presentation
      徳島大学工学部 徳島市
    • Year and Date
      2011-11-12
    • Related Report
      2012 Final Research Report
  • [Presentation] Improvement of Conductivity by incorporation of Boron atoms in Hydrogenated Amorphous Carbon Films fabricated by Plasma CVD methods and Electrochemical Properties of the films2011

    • Author(s)
      Kensuke Honda, Hiroshi Naragino, Kosuke Yoshinaga, Seiji Tastuta
    • Organizer
      220th Meeting of The Electrochemical Society
    • Place of Presentation
      Boston, 米国
    • Year and Date
      2011-10-12
    • Related Report
      2012 Final Research Report
  • [Presentation] ホウ素ドーピングによるDLC 薄膜の高導電化と分極性電極としての電気化学応答性2011

    • Author(s)
      楢木野宏,吉永浩亮,中原亮,本多謙介
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学工学部 徳島市
    • Related Report
      2011 Research-status Report
  • [Presentation] Improvement of Conductivity by incorporation of Boron atoms in Hydrogenated Amorphous Carbon Films fabricated by Plasma CVD methods and Electrochemical Properties of the films2011

    • Author(s)
      Kensuke Honda, Hiroshi Naragino, Kosuke Yoshinaga, Seiji Tastuta
    • Organizer
      220th Meeting of The Electrochemical Society
    • Place of Presentation
      ボストン アメリカ合衆国
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.honda-lab.sci.yamaguchi-u.ac.jp/top.html

    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 窒素がドープされたアモルファスシリコンカーバイトよりなるn型半導体素子及びその製造方法2011

    • Inventor(s)
      本多 謙介
    • Industrial Property Rights Holder
      国立大学法人山口大学
    • Industrial Property Number
      2011-241063
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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