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Attempt of in-situ observation of intercalation process in S/TEMby electron nano-probe

Research Project

Project/Area Number 23656398
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionNagoya University

Principal Investigator

MUTO Shunsuke  名古屋大学, 工学研究科, 教授 (20209985)

Co-Investigator(Renkei-kenkyūsha) KONDO Hiroki  豊田中央研究所, 研究員 (60394904)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsリチウムイオン二次電池 / 透過型電子顕微鏡 / 電子エネルギー損失分光 / その場観察 / 正極活物質 / 透過電子顕微鏡 / 可視化 / 電子顕微鏡 / ナノ材料 / リチウム電池
Research Abstract

Cathode active materials of lithium ion secondary batteries in practical use, LiNi0.8Co0.15Al0.05O2 (LNCA)LiFePO4 (LFPO) were investigated using scanning transmission electron microscopy (STEM) and electron energy-loss spectroscopy (EELS). We have clarified a dopant effect on suppression of degradation associated with many cycling at elevated temperatures and the origin of characteristic hysteresis in the charge -discharge process.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (29 results)

All 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (19 results) (of which Invited: 3 results) Remarks (4 results)

  • [Journal Article] 電子顕微鏡分光と第一原理計算によるリチウム電池正極の機能元素電子状態解析2012

    • Author(s)
      巽一厳, 武藤俊介, 近藤広規, 佐々木厳, 右京良雄
    • Journal Title

      セラミックス

      Volume: 47巻 Pages: 528-533

    • NAID

      10031155577

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] STEM-EELS 多変量解析を用いた Li 化学状態マッピング2012

    • Author(s)
      武藤俊介, 巽一厳, 近藤広規, 堀渕嘉代,右京良雄
    • Journal Title

      顕微鏡

      Volume: 47巻 No.3 Pages: 127-130

    • NAID

      10031121394

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Mg-doping on the degradation of LiNiO2-based cathode materials by combined spectroscopic methods2012

    • Author(s)
      S. Muto, K. Tatsumi, Y. Kojima, H. Oka, H. Kondo, K. Horibuchi, Y. Ukyo
    • Journal Title

      Journal of Power Sources

      Volume: Vol. 205 Pages: 449-455

    • NAID

      120005510919

    • URL

      http://dx.doi.org/10.1016/j.jpowsour.2012.01.071

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] STEM-EELS多変量解析を用いたLi化学状態マッピング2012

    • Author(s)
      武藤俊介,巽一厳,近藤広規,堀渕嘉代,右京良雄
    • Journal Title

      顕微鏡

      Volume: 47 Pages: 127-130

    • NAID

      10031121394

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Degradation analysis of a Ni-based layered positive-electrode active material cycled at elevated temperatures studied by scanning transmission electron microscopy and electron energy-loss spectroscopy2011

    • Author(s)
      Y. Kojima, S. Muto, K. Tatsumi, H. Kondo, H. Oka, K. Horibuchi, Y. Ukyo
    • Journal Title

      Journal of Power Sources

      Volume: Vol. 196 Pages: 7721-7727

    • URL

      http://dx.doi.org/10.1016/j.jpowsour.2011.05.017

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Degradation analysis of a Ni-based layered positive-electrode active material cycled at elevated temperatures studied by scanning transmission electron microscopy and electron energy-loss spectroscopy2011

    • Author(s)
      Y. Kojima, S. Muto, K. Tatsumi, H. Kondo, H. Oka, K. Horibuchi and Y. Ukyo
    • Journal Title

      Joumal of Power Sources

      Volume: 196 Issue: 18 Pages: 7721-7727

    • DOI

      10.1016/j.jpowsour.2011.05.017

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] グリーンビーグル材料の特性と局所電子状態可視化2013

    • Author(s)
      武藤俊介
    • Organizer
      日本金属学会2013年春期大会
    • Place of Presentation
      東京理科大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] セラミックス担持金属微粒子触媒における局所電子状態の可視化へ-化学反応は TEM で「見えるか」-2012

    • Author(s)
      武藤俊介
    • Organizer
      日本顕微鏡学会 第56回シンポジウム
    • Place of Presentation
      北海道大学学術交流会館(北海道)
    • Year and Date
      2012-11-20
    • Related Report
      2012 Final Research Report
  • [Presentation] 複合電子分光による物性画像診断とそのリチウム電池材料への応用2012

    • Author(s)
      武藤俊介
    • Organizer
      高分子分析研究懇談会第362回例会
    • Place of Presentation
      ゆうぽうと(東京都)
    • Year and Date
      2012-04-26
    • Related Report
      2012 Final Research Report
  • [Presentation] LiFePO4正極における電位調整時の充放電履歴と粒内相分布2012

    • Author(s)
      小嶌悠 嗣 , 武藤俊介 , 巽一厳 , 近藤広規 , 大砂哲 , 右京良雄
    • Organizer
      日本金属学会 2012 年度春期講演大会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Year and Date
      2012-03-28
    • Related Report
      2012 Final Research Report
  • [Presentation] グリーンビーグル材料の特性と局所電子状態可視化2012

    • Author(s)
      武藤俊介
    • Organizer
      日本金属学会2013 年春期大会
    • Place of Presentation
      東京理科大学(東京都)
    • Year and Date
      2012-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Diagnostic STEM-EELS Analysis of Cathodes in Lithium-Ion Secondary Batteries2012

    • Author(s)
      S. Muto, K. Tatsumi, Y. Kojima, H. Kondo, T. Sasaki, K. Horibuchi, Y. Ukyo
    • Organizer
      International Symposium on Role of Electron Microscopy in Industry ~Toward genuine collaboration between academia and industry~
    • Place of Presentation
      名古屋大学 (愛知県)
    • Year and Date
      2012-01-19
    • Related Report
      2012 Final Research Report
  • [Presentation] セラミックス担持金属微粒子触媒における局所電子状態の可視化へ-化学反応はTEMで「見えるか」-2012

    • Author(s)
      武藤俊介
    • Organizer
      日本顕微鏡学会 第56回シンポジウム
    • Place of Presentation
      北海道大学学術交流会館
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 複合電子分光による物性画像診断とそのリチウム電池材料への応用2012

    • Author(s)
      武藤俊介
    • Organizer
      高分子分析研究懇談会第362回例会
    • Place of Presentation
      ゆうぽうと(東京都)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Diagnostic STEM-EELS Analysis of Cathodes in Lithium-Ion Secondary Batteries2012

    • Author(s)
      S. Muto, K. Tatsumi, Y. Kojima, H. Kondo, T. Sasaki, K. Horibuchi and Y. Ukyo
    • Organizer
      International Symposium on Role of Electron Microscopy in Industry~Toward genuine collaboration between academia and industry~(招待講演)
    • Place of Presentation
      名古屋大学
    • Related Report
      2011 Research-status Report
  • [Presentation] LiFePO4正極における電位調整時の充放電履歴と粒内相分布2012

    • Author(s)
      小嶌悠嗣、武藤俊介、巽一厳、近藤広規、大砂哲、右京良雄
    • Organizer
      日本金属学会2012年度春期講演大会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Related Report
      2011 Research-status Report
  • [Presentation] LiFePO4 正極における充放電履歴と粒内相分布2011

    • Author(s)
      小嶌悠嗣, 武藤俊介, 巽一厳, 近藤広規, 大砂哲, 右京良雄
    • Organizer
      日本金属学会第149回 秋期講演大会
    • Place of Presentation
      沖縄コンベンショ ンセンター (沖縄県)
    • Year and Date
      2011-11-07
    • Related Report
      2012 Final Research Report
  • [Presentation] TEM 法による蓄電池材料解析技術2011

    • Author(s)
      武藤俊介
    • Organizer
      第27回格子欠陥フォーラム
    • Place of Presentation
      立山国際ホテル (富山 県)
    • Year and Date
      2011-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] 化学状態から探るリチウムイオン二次電池正極の相分布マッピング2011

    • Author(s)
      武藤俊介
    • Organizer
      第27回分析電子顕微鏡討論会
    • Place of Presentation
      幕張メッセ国際会議場(千葉県)
    • Year and Date
      2011-09-06
    • Related Report
      2012 Final Research Report
  • [Presentation] Diagnostic STEM-EELS Analysis of Cathodes Degradation in Lithium-Ion Secondary Batteries2011

    • Author(s)
      S.Muto
    • Organizer
      Microscopy &Microanalysis 2011
    • Place of Presentation
      Nashville, Tennessee(USA)
    • Year and Date
      2011-08-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Phase distribution and cycling history in the LiFePO4electrode2011

    • Author(s)
      小嶌悠嗣, 武藤俊介, 巽一厳, 近藤広規, 堀淵嘉代, 右京良雄
    • Organizer
      日本顕微鏡学会(第67回)学術 講演会
    • Place of Presentation
      福岡国際会議場(福岡県)
    • Year and Date
      2011-05-18
    • Related Report
      2012 Final Research Report
  • [Presentation] Phase distribution and cycling history in the LiFePO4 electrode2011

    • Author(s)
      小嶌悠嗣、武藤俊介、巽一厳、近藤広規、堀淵嘉代、右京良雄
    • Organizer
      日本顕微鏡学会(第67回)学術講演会
    • Place of Presentation
      福岡国際会議場(福岡県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Diagnostic STEM-EELS Analysis of Cathodes Degradation in Lithium-Ion Secondary Batteries2011

    • Author(s)
      S. Muto
    • Organizer
      Microscopy & Microanalysis 2011(招待講演)
    • Place of Presentation
      Nashville, Tennessee (USA)
    • Related Report
      2011 Research-status Report
  • [Presentation] 化学状態から探るリチウムイオン二次電池正極の相分布マッピング2011

    • Author(s)
      武藤俊介
    • Organizer
      第27回分析電子顕微鏡討論会(招待講演)(招待講演)
    • Place of Presentation
      幕張メッセ 国際会議場(千葉県)
    • Related Report
      2011 Research-status Report
  • [Presentation] LiFePO4正極における充放電履歴と粒内相分布2011

    • Author(s)
      小嶌悠嗣、武藤俊介、巽一厳、近藤広規、大砂哲、右京良雄
    • Organizer
      日本金属学会第149回秋期講演大会
    • Place of Presentation
      沖縄コンベンションセンター(沖縄県)
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://reginnovations.com/key-scientific-articles/degradation-analysis-of-a-ni-based-layered-positive-electrode-active-material-cycled-at-elevated-temperatures-studied-by-scanning-transmission-electron-microscopy-and-electron-energy-loss-spectroscopy/

    • Related Report
      2012 Final Research Report
  • [Remarks] 海外 Web サ イ ト Renewable Energy Global Innovations に注目論文として feature された

    • Related Report
      2012 Final Research Report
  • [Remarks] Key Scientific Articles

    • URL

      http://reginnovations.com/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://reginnovations.com/key-scientific-articles

    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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