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Preparation of sulfide-based lithium ion conducting materials by a solution process

Research Project

Project/Area Number 23656403
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionOsaka Prefecture University

Principal Investigator

TATSUMISAGO Masahiro  大阪府立大学, 大学院・工学研究科, 教授 (50137238)

Co-Investigator(Kenkyū-buntansha) TADANAGA Kiyoharu  大阪府立大学, 大学院・工学研究科, 准教授 (90244657)
HAYASHI Akitoshi  大阪府立大学, 大学院・工学研究科, 助教 (10364027)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords液相合成 / リチウムイオン伝導体 / 固体電解質 / 硫化物 / 薄膜
Research Abstract

The purpose of the present study is the preparation of sulfide-based lithium ion conductive solid electrolyte from liquid phase. Powders of sulfide-based solid electrolyte (SE) with high lithium concentration were dissolved into N-methylformamide (NMF) and a homogeneous solution was obtained. The NMF solution was dried at 150°C for 3 hours under vacuum to obtain precipitates. The ionic conductivity of the precipitates was 3×10^<-6>S cm^<-1>. Sulfide-based SE was coated onto positive electrode particles by using an NMF solution of SE.The all-solid-state cell using the electrode particles coated with the SE showed good charge-discharge behavior.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (7 results)

All 2013 Other

All Presentation (4 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Presentation] Preparation of Li2S-P2S5solid electrolyte from liquid phase and application for all-solid state battery2013

    • Author(s)
      S. Teragawa, K. Aso, K. Tadanaga, A. Hayashi, and M. Tatsumisago
    • Organizer
      The 19^<th>International Conference on Solid State Ionics
    • Place of Presentation
      京都国際会議場
    • Related Report
      2012 Final Research Report
  • [Presentation] N-メチルホルムアミド溶液を用いたLi_2S-P_2S_5系固体電解質の作製2013

    • Author(s)
      寺川真悟,麻生圭吾,忠永清治,林 晃敏,辰巳砂昌弘
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学
    • Related Report
      2012 Final Research Report
  • [Presentation] N-メチルホルムアミド溶液を用いたLi2S-P2S5系固体電解質の作製2013

    • Author(s)
      寺川真悟,麻生圭吾,忠永清治,林晃敏,辰巳砂昌弘
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation of Li2S-P2S5 solid electrolyte from liquid phase and application for all-solid state battery2013

    • Author(s)
      S. Teragawa, K. Aso, K. Tadanaga, A. Hayashi, and M. Tatsumisago
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      京都国際会議場
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka2/

    • Related Report
      2012 Final Research Report
  • [Remarks] 大阪府立大学 大学院工学研究科 応用化学分野 無機化学研究グループ

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka2/index.html

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 全固体リチウム二次電池の固体電解質を含む層の形成用溶液、全固体リチウム二次電池及びその製造方法2013

    • Inventor(s)
      林晃敏、辰巳砂昌弘、忠永清治
    • Industrial Property Rights Holder
      大阪府立大学
    • Industrial Property Number
      2013-064161
    • Filing Date
      2013-03-26
    • Related Report
      2012 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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