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Search for thermoelectromotive force of thin/bulk interfacial structured film comprised of only single-walled carbon nanotubes

Research Project

Project/Area Number 23656419
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

SATO Yoshinori  東北大学, 大学院・環境科学研究科, 准教授 (30374995)

Co-Investigator(Kenkyū-buntansha) TOHJI Kazuyuki  東北大学, 大学院・環境科学研究科, 教授 (10175474)
高橋 英志  東北大学, 環境科学研究科, 准教授 (90312652)
Co-Investigator(Renkei-kenkyūsha) TAKAHASHI Hideyuki  東北大学, 大学院・環境科学研究科, 准教授 (90312652)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsナノチューブ・フラーレン / 太陽光発電 / 光物性 / 表面・界面物性 / 熱工学 / ① ナノチューブ・フラーレン
Research Abstract

In this study, we prepared high crystalline single-walled carbon nanotube (SWCNT) thin film (transmittance 9.0 %)/bulk film (transmittance 2.3 %) interfacial structured film cells and investigated the photoelectromotive force. When a light (solar simulator AM1.5 with 100 mW/cm2) was irradiated toward the bulk film side (10×10 mm2) of the cells, the photoelectromotive force of 0.90 mV occurred. The Seebeck coefficient was estimated to be +66.4 μV/K, and the carrier of high crystalline SWCNT was a positive hole. Additionally, the interface of thin/bulk film was not Schottky junction but Ohmic since the I-V curve of the cells showed a liner shape. The photoelectromotive force in the SWCNT film/bulk interface cell is considered to be thermoelectromotive force derived from thermal gradient generated by photo-excitation electron converted into heat.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (17 results)

All 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (7 results) (of which Invited: 2 results) Remarks (4 results)

  • [Journal Article] Influence of the structure of the nanotube on the mechanicalproperties of binder-free multi-walled carbon nanotube solids2012

    • Author(s)
      Y.Sato, H.Nishizaka, S.Sawano, A.Yoshinaka, K.Hirano, S.Hashiguchi, T.Arie, S.Akita, G.Yamamoto, T.Hashida, H.Kimura, K.Motomiya, K.Tohji
    • Journal Title

      Carbon

      Volume: 50 Issue: 1 Pages: 34-39

    • DOI

      10.1016/j.carbon.2011.07.047

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitrogen physisorption and site blocking on single-walled carbon nanotubes2011

    • Author(s)
      S.-K. Lee
    • Journal Title

      Surf. Sci.

      Volume: 606 Issue: 3-4 Pages: 293-293

    • DOI

      10.1016/j.susc.2011.10.009

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Boron-Assisted Transformation to Rod-Like Graphitic Carbons from Multi-Walled Carbon Nanotubes in Boron-Mixed Multi-Walled Carbon Nanotube Solids2011

    • Author(s)
      Yoshinori Sato, Hikaru Nishizaka, Kenichi Motomiya, Go Yamamoto, Akira Okubo, Hisamichi Kimura, Mikio Ishikuro, Kazuaki Wagatsuma, Toshiyuki Hashida, Kazuyuki Tohji
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 3巻 Issue: 7 Pages: 2431-2439

    • DOI

      10.1021/am200335n

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influence of carbon structure of the anode on the production of graphite in single-walled carbon nanotube soot synthesized by arc discharge using a Fe-Ni-S catalyst2011

    • Author(s)
      Hikaru Nishizaka, Masaru Namura, Kenichi Motomiya, Yasumasa Ogawa, Yasuo Udagawa, Kazuyuki Tohji, Yoshinori Sato
    • Journal Title

      Carbon

      Volume: 49巻 Issue: 11 Pages: 3607-3614

    • DOI

      10.1016/j.carbon.2011.04.063

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chemical Speciation Analysis for Amorphous Boron and Precipitated Boron Carbide in Sintered Boron-Added Carbon Nanotubes2011

    • Author(s)
      石黒三岐雄,佐藤義倫,田路和幸,我妻和明
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 60 Issue: 10 Pages: 807-811

    • DOI

      10.2116/bunsekikagaku.60.807

    • NAID

      10029482363

    • ISSN
      0525-1931
    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Toxicity evaluations of various carbon nanomaterials2011

    • Author(s)
      Uo M., 他4名
    • Journal Title

      Dental Materials Journal

      Volume: 30 Issue: 3 Pages: 245-263

    • DOI

      10.4012/dmj.2010-039

    • NAID

      10029136414

    • ISSN
      0287-4547, 1881-1361
    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 単層カーボンナノチューブ膜の光熱起電力特性2013

    • Author(s)
      榊原甫,佐藤義倫,伊野浩介,伊藤暁彦,末永智一,後藤孝,本宮憲一,田路和幸
    • Organizer
      第44回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • URL

      http://fullerene-jp.org/jp/sympo44/

    • Place of Presentation
      文京区,東京都
    • Year and Date
      2013-03-13
    • Related Report
      2012 Final Research Report
  • [Presentation] 単層カーボンナノチューブを用いた光起電力材料の探索2012

    • Author(s)
      榊原甫,佐藤義倫,伊野浩介,伊藤暁彦,塗溶,後藤孝,末永智一,田路和幸
    • Organizer
      第5回資源・素材学会東北支部若手の会
    • URL

      http://www.mmij.or.jp/branch/001/wakate.html

    • Place of Presentation
      大潟村,秋田県
    • Year and Date
      2012-10-12
    • Related Report
      2012 Final Research Report
  • [Presentation] 単層カーボンナノチューブを用いた光起電力材料の探索2012

    • Author(s)
      榊原甫,佐藤義倫,伊野浩介,伊藤暁彦,塗溶,後藤孝,末永智一,田路和幸
    • Organizer
      平成24年度資源・素材学会東北支部春季大会
    • URL

      http://www.mmij.or.jp/branch/001/info.html

    • Place of Presentation
      仙台市,宮城県
    • Year and Date
      2012-06-22
    • Related Report
      2012 Final Research Report
  • [Presentation] 単層カーボンナノチューブを用いた光起電力材料の探索

    • Author(s)
      榊原甫、佐藤義倫、伊野浩介、伊藤暁彦、塗溶、後藤孝、末永智一、田路和幸
    • Organizer
      平成24年度 資源・素材学会東北支部 春季大会
    • Place of Presentation
      仙台市、宮城県
    • Related Report
      2012 Annual Research Report
  • [Presentation] 単層カーボンナノチューブを用いた光起電力材料の探索

    • Author(s)
      榊原甫、佐藤義倫、伊野浩介、伊藤暁彦、塗溶、後藤孝、末永智一、田路和幸
    • Organizer
      第5回 資源・素材学会東北支部 若手の会
    • Place of Presentation
      南秋田郡大潟村、秋田県
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 高結晶単層カーボンナノチューブを用いた可視・近赤外光応答型光熱蓄電池の創製に関する研究

    • Author(s)
      佐藤 義倫
    • Organizer
      平成24年度 石田(實)記念財団研究奨励賞
    • Place of Presentation
      仙台市、宮城県
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 単層カーボンナノチューブ膜の光熱起電力特性

    • Author(s)
      榊原甫、佐藤義倫、伊野浩介、伊藤暁彦、末永智一、後藤孝、本宮憲一、田路和幸
    • Organizer
      第44回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      文京区、東京都
    • Related Report
      2012 Annual Research Report
  • [Remarks] 1.佐藤義倫,高結晶単層カーボンナノチューブを用いた可視・近赤外光応答型光熱蓄電池の創製に関する研究,平成24年度石田(實)記念財団研究奨励賞,2012年11月16日. 〔受賞〕

    • Related Report
      2012 Final Research Report
  • [Remarks] 2.榊原甫,佐藤義倫,伊野浩介,伊藤暁彦,塗溶,後藤孝,末永智一,田路和幸,単層カーボンナノチューブを用いた光起電力材料の探索,平成24年度資源・素材学会東北支部春季大会ポスター賞(銅賞),2012年6月22日. 〔受賞〕

    • URL

      http://www.mmij.or.jp/branch/001/info.html

    • Related Report
      2012 Final Research Report
  • [Remarks] 平成24年度 資源・素材学会東北支部 春季大会 ポスター賞受賞

    • URL

      http://www.kankyo.tohoku.ac.jp/kenkyu.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 平成24年度 石田(實)記念財団研究奨励賞受賞

    • URL

      http://ncsimd.kankyo.tohoku.ac.jp/

    • Related Report
      2012 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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