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A resource-saving technology for high corrosion-resistant steels by improving electrochemical property of non-metallic inclusions

Research Project

Project/Area Number 23656447
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Material processing/treatments
Research InstitutionTohoku University

Principal Investigator

MUTO Izumi  東北大学, 大学院・工学研究科, 准教授 (20400278)

Co-Investigator(Kenkyū-buntansha) HARA Nobuyoshi  東北大学, 大学院・工学研究科, 教授 (40111257)
SUGAWARA Yu  東北大学, 大学院・工学研究科, 助教 (40599057)
AKAO Noboru  東北大学, 大学院・工学研究科, 助手 (80222503)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords腐食防食 / 介在物 / 孔食 / ステンレス鋼 / マイクロ電気化学セル / 材料加工・処理
Research Abstract

To analyze microscopic corrosion mechanisms of metals, a microelectrochemical system for in situ high-resolution optical microscopy was developed and applied to the real-time observation of pit initiation at MnS inclusion in stainless steels. It was directly observed that pits were initiated at the MnS/steel boundaries, and that deep trenches were generated at these boundaries during anodic polarization. The metal-oxide enriched surface layer on inclusions was found to be the predominant factor affecting the electrochemical properties and the corrosion protection ability of the inclusions.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (16 results)

All 2013 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (13 results) (of which Invited: 1 results)

  • [Journal Article] The Role of Oxide Films on TiS and Ti4C2S2 Inclusions in the Pitting Corrosion Resistance of Stainless Steels2013

    • Author(s)
      Naoya Shimahashi, Izumi Muto, Yu Sugawara, Nobuyoshi Hara
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 第160巻 Issue: 6 Pages: C262-C269

    • DOI

      10.1149/2.089306jes

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Microelectrochemical System for In Situ High-Resolution Optical Microscopy : Morphological Characteristics of Pitting at MnS Inclusion in Stainless Steel2012

    • Author(s)
      Aya Chiba, Izumi Muto, Yu Sugawara, and Nobuyoshi Hara
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 159 Issue: 8 Pages: C341-C350

    • DOI

      10.1149/2.054208jes

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of a New Microelectrochemical Measurement System for In-situ Optical Microscopic Observation of Pit Initiation Processes2012

    • Author(s)
      Aya Chiba, Izumi Muto, Yu Sugawara, and Nobuyoshi Hara
    • Journal Title

      ECS Transactions

      Volume: 41 Issue: 25 Pages: 237-245

    • DOI

      10.1149/1.3697593

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] In situ光学顕微鏡観察機能を備えたマイクロ電気化学計測システムによるMnS介在物を起点とした孔食発生機構の形態的解析2013

    • Author(s)
      千葉亜耶、武藤泉、菅原優、原信義
    • Organizer
      日本鉄鋼協会第165回春季講演大会
    • Place of Presentation
      東京(東京電機大学東京千住キャンパス)
    • Year and Date
      2013-03-28
    • Related Report
      2012 Final Research Report
  • [Presentation] マイクロ電気化学プローブによるステンレス鋼のMnS介在物を起点とする孔食発生に及ぼす応力の影響解明2013

    • Author(s)
      島橋直也、武藤泉、菅原優、原信義
    • Organizer
      日本金属学会2013年春期講演大会(第152回)
    • Place of Presentation
      東京(東京理科大学,神楽坂キャンパス)
    • Year and Date
      2013-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] マイクロ電気化学プローブによるステンレス鋼のMnS 介在物を起点とする孔食発生に及ぼす応力の影響解明2013

    • Author(s)
      島橋直也、武藤 泉、菅原 優、原 信義
    • Organizer
      日本金属学会2013年 春期講演大会(第152 回)
    • Place of Presentation
      東京(東京理科大学, 神楽坂キャンパス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] In situ光学顕微鏡観察機能を備えたマイクロ電気化学計測システムによるMnS介在物を起点とした孔食発生機構の形態的解析2013

    • Author(s)
      千葉亜耶、武藤 泉、菅原 優、原 信義
    • Organizer
      日本鉄鋼協会 第165回春季講演大会
    • Place of Presentation
      東京(東京電機大学 東京千住キャンパス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] The Role of Elemental Sulfur and Chloride Ions on Pit Initiation at MnS Inclusion in Stainless Steel2013

    • Author(s)
      Aya Chiba, Izumi Muto, Yu Sugawara, Nobuyoshi Hara
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      San Francisco (The Hilton San Francisco Hotel)(USA)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Microscopic Polarization Behavior and Thermodynamic Stability of TiS and Ti4C2S2 Inclusions in Stainless Steels2012

    • Author(s)
      Naoya Shimahashi, Izumi Muto, Yu Sugawara, Nobuyoshi Hara
    • Organizer
      222nd Meeting of ECS (The Electrochemical Society)
    • Place of Presentation
      USA (Honolulu, HawaiiConvention Center)
    • Year and Date
      2012-10-11
    • Related Report
      2012 Final Research Report
  • [Presentation] Microelectrochemical Investigation of Pit Initiation and Selective Dissolution between MnS and Stainless Steel2012

    • Author(s)
      Aya Chiba, Izumi Muto, Yu Sugawara 、Nobuyoshi Hara
    • Organizer
      222nd Meeting of ECS (The Electrochemical Society)
    • Place of Presentation
      USA (Honolulu, HawaiiConvention Center)
    • Year and Date
      2012-10-11
    • Related Report
      2012 Final Research Report
  • [Presentation] マイクロ電気化学プローブによる介在物/鋼境界領域の溶解特性解明と局部腐食防止技術の開発2012

    • Author(s)
      武藤泉
    • Organizer
      学振176委員会(加工プロセスによる材料新機能発現委員会)第21回研究会
    • Place of Presentation
      東京(東京理科大学、森戸会館)
    • Year and Date
      2012-07-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Microscopic Polarization Behavior and Thermodynamic Stability of TiS and Ti4C2S2 Inclusions in Stainless Steels2012

    • Author(s)
      Naoya Shimahashi、Izumi Muto、Yu Sugawara、Nobuyoshi Hara
    • Organizer
      222nd Meeting of ECS
    • Place of Presentation
      Hawaii Convention Center、Honolulu, Hawaii(USA)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Microelectrochemical Investigation of Pit Initiation and Selective Dissolution between MnS and Stainless Steel2012

    • Author(s)
      Aya Chiba、Izumi Muto、Yu Sugawara、Nobuyoshi Har
    • Organizer
      222nd Meeting of ECS
    • Place of Presentation
      Hawaii Convention Center、Honolulu, Hawaii(USA)
    • Related Report
      2012 Annual Research Report
  • [Presentation] マイクロ電気化学プローブによるTiS系介在物のアノード分極特性の解析2011

    • Author(s)
      島橋直也、武藤泉、菅原優、原信義
    • Organizer
      第58回材料と環境討論会(腐食防食境界)
    • Place of Presentation
      名古屋市(名古屋大学、東山キャンパス)
    • Year and Date
      2011-09-28
    • Related Report
      2012 Final Research Report
  • [Presentation] マイクロ電気化学プローブによるTiS系介在物のアノード分極特性の解析2011

    • Author(s)
      島橋直也、武藤 泉、菅原 優、原 信義
    • Organizer
      第58回材料と環境討論会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] マイクロ電気化学プローブによる介在物/鋼境界領域の溶解特性解明と局部腐食防止技術の開発

    • Author(s)
      武藤 泉
    • Organizer
      学振176委員会(加工プロセスによる材料新機能発現委員会)第21回研究会
    • Place of Presentation
      東京、森戸会館(東京理科大、神楽坂)
    • Related Report
      2012 Annual Research Report
    • Invited

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Published: 2011-08-05   Modified: 2019-07-29  

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