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Molecular recognition of hydrate by controlled micro structure and development of application process

Research Project

Project/Area Number 23656483
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionTohoku University

Principal Investigator

SMITH Richard Lee, Jr.  東北大学, 大学院・環境科学研究科, 教授 (60261583)

Co-Investigator(Kenkyū-buntansha) OTA Masaki  東北大学, 大学院・工学研究科, 助教 (50455804)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsハイドレート / 分離プロセス / ミクロ構造 / 形成速度
Research Abstract

Characteristic structural changes that occur in hydrates and semi-clathrate hydrates are important for understanding hydrate properties for gas separation application. In this work, gas adsorption equilibria for H_2 and for CO_2 with the organic liquids clathrate hydrate particles and with the quaternary ammonium salts semi-clathrate hydrate particles. The higher temperature, the H_2/CO_2 selectivity was higher. In 2.6 mol TBAB semi-clathrate hydrate, this value is higher than 100, the hydrates was confirmed adaptability to the gas separation process.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (14 results)

All 2013 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (11 results)

  • [Journal Article] Review of CO_2-CH_4 clathrate hydrate replacement reaction laboratory studies - Properties and kinetics2013

    • Author(s)
      H. Komatsu, M. Ota, R. L. Smith, Jr., H.Inomata
    • Journal Title

      J. Taiwan Inst. Chem. Eng

      Volume: (in press)

    • URL

      http://dx.doi.org/10.1016/j.jtice.2013.03.010

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Review of CO2-CH4 clathrate hydrate replacement reaction laboratory studies - Properties and kinetics2013

    • Author(s)
      Hiroyuki Komatsu
    • Journal Title

      Journal of the Taiwan Institute of Chemical Engineers

      Volume: in press

    • Related Report
      2012 Annual Research Report
  • [Journal Article] C. J. Peters, Decomposition kinetics and recycle of binary hydrogen-tetrahydrofuran clathrate hydrate2011

    • Author(s)
      H. Yoshioka, M. Ota, Y. Sato, M. Watanabe, H. Inomata, R. L. Smith, Jr
    • Journal Title

      AIChE

      Volume: 57 (1) Issue: 1 Pages: 265-272

    • DOI

      10.1002/aic.12241

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] Measurement of the adsorption equilibria of hydrogen and of carbon dioxide in clathrate and semi-clathrate hydrates2013

    • Author(s)
      H. Komatsu, A. Hayasaka, M. Ota, M. Watanabe, R. L. Smith, Jr
    • Organizer
      6th International Symposium on Molecular Thermodynamics and Molecular Simulation
    • Place of Presentation
      Higashi-Hiroshima, Japan
    • Year and Date
      2013-09-28
    • Related Report
      2012 Final Research Report
  • [Presentation] TBABセミクラスレートハイドレートの相平衡に与えるガス種の影響2013

    • Author(s)
      早坂淳,小松博幸,大田昌樹,渡邉賢,佐藤善之,R.L.Smith,Jr
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2013-03-19
    • Related Report
      2012 Final Research Report
  • [Presentation] TBABセミクラスレートハイドレートの相平衡に関する研究2013

    • Author(s)
      早坂淳,大田昌樹,渡邉賢,R.L.Smith,Jr
    • Organizer
      第12回宮城化学工学懇話会先端研究発表会
    • Place of Presentation
      東北大学青葉山キャンパス
    • Year and Date
      2013-03-07
    • Related Report
      2012 Final Research Report
  • [Presentation] 混合セミクラスレートハイドレート形成機構に与えるイオン液体アニオン種の影響2012

    • Author(s)
      小松博幸,大田昌樹,渡邉賢,佐藤善之,猪股宏,R.L. Smith,Jr
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2012-11-07
    • Related Report
      2012 Final Research Report
  • [Presentation] Effect of Gas Inclusion Behavior on the Phase Equilibrium of (H_2 or CO_2) . Tetra-n-butyl ammonium Bromide Semiclathrate Hydrates2012

    • Author(s)
      A. Hayasaka, H. Komatsu, M. Ota, R. L. Smith, Jr
    • Organizer
      International Symposium on Chemical Environmental Biomedical Technology
    • Place of Presentation
      Tainan, Taiwan
    • Year and Date
      2012-09-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Two Stage Adsorption Model for Formation Kinetics of Hydrogen Binary Clathrate Hydrates2011

    • Author(s)
      H. Komatsu
    • Organizer
      The 7th International Symposium on Chemical Environmental Biomedical Technology
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2011-09-06
    • Related Report
      2012 Final Research Report
  • [Presentation]2011

    • Author(s)
      H. Komatsu, M. Ota, M. Watanabe, Y. Sato, R. L. Smith, Jr
    • Organizer
      The 7 th International Conference on Gas Hydrates
    • Place of Presentation
      Edinburgh, Scotland, United Kingdom
    • Year and Date
      2011-07-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Constituent Molecular Effects on Phase Equilibria and Hydrogen Adsorption Kinetics in Clathrate Hydrates2011

    • Author(s)
      Hiroyuki Komatsu, Masaki Ota, Masaru Watanabe, Yoshiyuki Sato, Richard L. Smith, Jr.
    • Organizer
      The 7th International Conference on Gas Hydrates
    • Place of Presentation
      Edinburgh, Scotland, United Kingdom
    • Related Report
      2011 Research-status Report
  • [Presentation] Two Stage Adsorption Model for Formation Kinetics of Hydrogen Binary Clathrate Hydrates2011

    • Author(s)
      Hiroyuki Komatsu
    • Organizer
      The 7th International Symposium on Chemical-Environmental-Biomedical Technology
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2011 Research-status Report
  • [Presentation] TBABセミクラスレートハイドレートの相平衡に関する研究

    • Author(s)
      早坂淳,大田昌樹,渡邉賢,Richard L. Smith Jr.
    • Organizer
      第12回宮城化学工学懇話会先端研究発表会
    • Place of Presentation
      東北大学青葉山キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] TBABセミクラスレートハイドレートの相平衡に与えるガス種の影響

    • Author(s)
      早坂淳,小松博幸,大田昌樹,渡邉賢,佐藤善之,Richard L. Smith Jr.
    • Organizer
      化学工学会 第78年会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2012 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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