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Low temperature synthesis of ZnO films

Research Project

Project/Area Number 23656505
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionOsaka University

Principal Investigator

NISHIYAMA Norikazu  大阪大学, 基礎工学研究科, 教授 (10283730)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords酸化亜鉛 / 水熱合成 / 透明電極 / 太陽電池
Research Abstract

ZnO is a promising material for ultraviolet optoelectronics, transparent electrodes, light emitting diodes, solar cells and so on. In this study, we have developed a simple synthesis method for ZnO nanorods without any calcination processes. This method enables the use of various substrates with low thermal stability.
First, zinc oxide nanorods were synthesized by using the zinc/sodium dodecyle sulfate composite seed. Second, the morphology of the zinc oxide was controlled with the difference by using various alcohols as a solvent. The sheet-like ZnO films were synthesized when ethanol was used as a solvent. The ZnO nanosheet films had higher transparency and conductivity than that of ZnO nanorods. Third, mesoporous zinc oxide films were synthesized by using a triblock copolymer (Pluronic F127: EO106PO70EO106) as a soft template agent. Al or b-doped mesoporous ZnO films show high transparency and low sheet resistance (0.017 ohm cm).

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (12 results)

All 2013 2012 2011

All Journal Article (6 results) (of which Peer Reviewed: 3 results) Presentation (6 results)

  • [Journal Article] Synthesis of mesoporous ZnO, AZO, and BZO transparent conducting films using nonionic triblock copolymer as template2013

    • Author(s)
      Naoyuki Ueno, Bram Dwijaya, Yoshiaki Uchida, Yasuyuki Egashira, Norikazu Nishiyama
    • Journal Title

      Mat. Lett

      Volume: 100 Pages: 111-114

    • Related Report
      2013 Final Research Report
  • [Journal Article] Synthesis of mesoporous ZnO, AZO, and BZO transparent conducting films using nonionic triblock copolymer as template2013

    • Author(s)
      Naoyuki Ueno, Bram Dwijaya, Yoshiaki Uchida, Yasuyuki Egashira, Norikazu Nishiyama
    • Journal Title

      Mat. Lett.

      Volume: 100 Pages: 111-114

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature hydrothermal synthesis of ZnO nanosheet using organic/inorganic composite as seed layer2012

    • Author(s)
      Naoyuki Ueno, Akinobu Yamamoto, Yoshiaki Uchida, Yasuyuki Egashira, Norikazu Nishiyama
    • Journal Title

      Mat. Lett

      Volume: 86 Pages: 65-68

    • Related Report
      2013 Final Research Report
  • [Journal Article] Low-temperature synthesis of ZnO nanorods using organic-inorganic composite as seed layer2012

    • Author(s)
      Naoyuki Ueno, Kouji Nakanishi, Toshiaki Ohta, Yasuyuki Egashira, Norikazu Nishiyama
    • Journal Title

      Thin Solid Films

      Volume: 520 Pages: 4291-4296

    • Related Report
      2013 Final Research Report
  • [Journal Article] Low-temperature hydrothermal synthesis of ZnO nanosheet using organic/inorganic composite as seed layer2012

    • Author(s)
      Naoyuki Ueno, Akinobu Yamamoto, Yoshiaki Uchida, Yasuyuki Egashira, Norikazu Nishiyama
    • Journal Title

      Materials Letters

      Volume: 86 Pages: 65-68

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low-Temperature synyjesis of ZnO nanorods...2012

    • Author(s)
      N. Ueno et al.
    • Journal Title

      Thin Solid Films

      Volume: 520 Issue: 13 Pages: 4291-4295

    • DOI

      10.1016/j.tsf.2012.02.054

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 導電性ポーラス酸化亜鉛薄膜の合成2012

    • Author(s)
      上野直遵, 内田幸明, 江頭靖幸, 西山憲和
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学(東京都)
    • Year and Date
      2012-03-15
    • Related Report
      2013 Final Research Report
  • [Presentation] 酸化亜鉛ナノ薄膜の低温水熱合成2012

    • Author(s)
      上野直遵, 江頭靖幸, 西山憲和
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 導電性ポーラス酸化亜鉛薄膜の合成2012

    • Author(s)
      上野直遵,内田 幸明,江頭 靖幸,西山 憲和
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学(東京都)
    • Related Report
      2011 Research-status Report
  • [Presentation] 酸化亜鉛ナノ薄膜の低温水熱合成2011

    • Author(s)
      上野直遵, 江頭靖幸, 西山憲和
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Year and Date
      2011-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] 酸化亜鉛ナノ薄膜の低温水熱合成2011

    • Author(s)
      上野直遵, 江頭靖幸, 西山憲和
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      化学工学会第43 回秋季大会
    • Year and Date
      2011-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] 酸化亜鉛ナノ薄膜の低温水熱合成2011

    • Author(s)
      上野直遵, 江頭靖幸, 西山憲和
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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