| Project/Area Number |
23656508
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
YAMANAKA Ichirou 東京工業大学, 大学院・理工学研究科, 准教授 (90240051)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | 触媒反応 / ノン / ホスゲン法 / 炭酸ジフェニル / パラジウム / 電極触媒 / ナノ粒子 / カルボニル化 / フェノール / グリーンケミストリー / 電解合成 / ノンホスゲン法 / 電解カルボニル化 / パラジウム触媒 |
|---|
| Research Abstract |
Diphenyl carbonate (DPC) is the essential material for the polycarbonate manufacture in the current chemical industry. DPC is usually produced using deadly poisonous phosgene but a new and phosgene-free method has been developed in this study. Oxidative carbonylation with oxygen can’t use for the DPC synthesis because of highly hydrolysis of DPC. Electrocarbonylation of phenol to DPC was found using a new Pd electrocatalyst. and the reaction mechanism was revealed.
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