| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
|---|
| Research Abstract |
The periphery of the poly(propylene imine) (PPI) dendrimers were functionalizedwith bulky substituents to form capsular dendrimers. Within the nanovoids of the dendrimers, subnano ordered palladium clusters could be prepared by precise controlof the preorganized Pd ions. The electronic state of Pd cluster could be tuned with the interaction of the dendrimers, which affected the catalytic performances of the Pd clusters in the hydrogenation of olefins and allylic substitution reactions.
|
