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Development of hydrogen reduction system of metal sulfide under submarine hydrothermal conditions

Research Project

Project/Area Number 23656558
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Earth system and resources enginnering
Research InstitutionTohoku University

Principal Investigator

TSUCHIYA Noriyoshi  東北大学, 大学院・環境科学研究科, 教授 (40207410)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords海底熱水鉱床 / 水素製造 / 硫化鉱物 / 酸化鉱物 / 水熱反応 / 熱水鉱床 / 硫化物 / バイオマス / アクティブ・マイニング / 硫化物鉱床 / レアメタル
Research Abstract

Seafloor and oceanic crust are geologically young compared with continental crust, and hydrothermal vents are located at extensional tectonic setting. Ore deposit within the seafloor could be estimated to form at shallower part compared with ore deposit in land, even for open and/or hidden deposits. According to geological characteristics of seafloor ore deposits, active mining technology, which is applied by hydrogen reduction system of metal sulfide, was studied.
Pyrite (representative iron sulfide) could be reduced into pyrrhotite and magnetite by hydrothermal reaction, and hydrogen sulfide could produce hydrogen by hydrothermal reaction, and then produced sulfur oxides could be converted into hydrogen sulfide mixed with other biomass (or organic compounds). Those results could extend to establish active mining technology.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (8 results)

All 2012 2011 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Remarks (1 results)

  • [Journal Article] Temperature- and pH-dependent mechanism of hydrogen production from hydrothermal reactions of sulfide2012

    • Author(s)
      Putri Setiani, Noriaki Watanabe, Atsushi Kishita, and Noriyoshi Tsuchiya
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 37 Pages: 18679-18687

    • URL

      http://dx.doi.org/10.1016/j.ijhydene.2012.10.013

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Supercritical Methanol Method for Direct Conversion of Microalgae Biomasses into Biodiesel2012

    • Author(s)
      DiahAjeng Setiawati, Arief Nuryadi, Noriaki Watanabe, Atsushi Kishita, Noriyoshi Tsuchiya
    • Journal Title

      International Journal of Environment and Bioenergy

      Volume: 3(1) Pages: 34-45

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sustainable and Enhanced Hydrogen Production from Biomass through Sulfur Redox Cycle using Georeactor2011

    • Author(s)
      Putri Setiani, Javier Vilcaez, Noriaki Watanabe, Atsushi Kishita, and Noriyoshi Tsuchiya
    • Journal Title

      Geothermal Resources Council Transaction

      Volume: 35 Pages: 135-138

    • URL

      http://www.geothermal.org/transactions.html

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced hydrogen production from biomass via the sulfur redox cycle under hydrothermal conditions2011

    • Author(s)
      P. Setiani, J. Vilcaez, N. Watanabe, A. Kishita, N. Tsuchiya
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36(17) Issue: 17 Pages: 10674-10682

    • DOI

      10.1016/j.ijhydene.2011.06.012

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of generalzero-valent metals power of Co/W/Ni/Fe on hydrogen production with H2S as a reductant under hydrothermal conditions2011

    • Author(s)
      Shiping Zhang, Fangming Jin, Xu Zeng, Jiajun Hu, Zhibao Huo, Yuanqing Wang,Noriaki Watanabe Nobuo Hirano, and Noriyoshi Tsuchiya
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36 Issue: 15 Pages: 8878-8884

    • DOI

      10.1016/j.ijhydene.2011.04.227

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced hydrogen production from biomass via the sulfur redox cycle2011

    • Author(s)
      Putri Setiani, Javier Vilcaez, Noriaki Watanabe, Atsushi Kishita,
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36 Pages: 10674-10682

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of general zero-valent metals power of Co/W/Ni/Fe on hydrogen2011

    • Author(s)
      Shiping Zhang, Fangming Jin, Xu Zeng, Jiajun Hu, Zhibao Huo, Yuanqing
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36 Pages: 8878-8884

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Remarks]

    • URL

      http://geoserv.kankyo.tohoku.ac.jp/

    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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