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Composite electrodes of iron oxides and carbons for high rate electrochemical reactions of lithium-oxygen batteries

Research Project

Project/Area Number 23656603
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionThe University of Tokyo

Principal Investigator

HIBINO Mitsuhiro  東京大学, 大学院・工学系研究科, 研究員 (20270910)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsエネルギー生成 / 変換 / 空気電池 / 二次電池 / 複合体電極 / 電気化学触媒
Research Abstract

Composite electrode materials of iron-based oxides and carbons for lithium-air batteries were investigated. Among various iron-based oxides investigated inthis study, perovskite-related A_0.5La_0.5FeO_z(A = Ca, Sr)underwent extraction and insertion of oxideions stably in wide range of oxygen composit~ion. Because of it allows reversible and repeatable extraction/reinsertion of oxide ions at fast rate ( D = 1.2×10^-13 cm^2 s^-1), Ca_0.5La_0.5FeO_2.863 was foundto be expected as an oxygen reduction catalyst (or a mediator) for air electrode of lithium-air batteries.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (8 results)

All 2013 2012 Other

All Journal Article (2 results) Presentation (2 results) (of which Invited: 1 results) Book (2 results) Remarks (2 results)

  • [Journal Article] 酸素ロッキング電池2013

    • Author(s)
      日比野光宏,水野哲孝
    • Journal Title

      未来材料

      Volume: 13(1) Pages: 42-47

    • Related Report
      2012 Annual Research Report
  • [Journal Article] リチウム─空気二次電池─原理から最近の動向まで─2012

    • Author(s)
      日比野光宏
    • Journal Title

      触媒

      Volume: 54 Pages: 203-208

    • NAID

      10030518664

    • Related Report
      2011 Research-status Report
  • [Presentation] Electrode property of A_0.5La_0.5FeO_z (A = Ca, Sr) for rocking chair type oxide ion batteries2012

    • Author(s)
      Mitsuhiro Hibino, Yosuke Suga, Takeshi Kimura, ryota Kido, Tetsuichi Kudo, Noritaka Mizuno
    • Organizer
      The 13th Asian Conference on Solid State Ionics
    • Place of Presentation
      東北大学さくらホール,宮城(招待講演)
    • Year and Date
      2012-07-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Electrode property of A0.5La0.5FeOz (A = Ca, Sr) for rocking chair type oxide ion batteries2012

    • Author(s)
      Mitsuhiro Hibino, Yosuke Suga, Takeshi Kimura, ryota Kido, Tetsuichi Kudo, Noritaka Mizuno
    • Organizer
      The 13th Asian Conference on Solid State Ionics
    • Place of Presentation
      東北大学さくらホール,宮城
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] 酸素ロッキング電池2013

    • Author(s)
      日比野光宏,水野哲孝
    • Publisher
      未来材料13
    • Related Report
      2012 Final Research Report
  • [Book] リチウム-空気二次電池-原理から最近の動向まで-2012

    • Author(s)
      日比野光宏
    • Publisher
      触媒54
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://park.itc.u-tokyo.ac.jp/mizuno

    • Related Report
      2012 Final Research Report
  • [Remarks] 水野研究室

    • URL

      http://park.itc.u-tokyo.ac.jp/mizuno

    • Related Report
      2012 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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