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Creation of bio-inspired dye mixture for water splitting photocatalysts

Research Project

Project/Area Number 23656606
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionKyushu University

Principal Investigator

HAGIWARA Hidehisa  九州大学, 工学(系)研究科(研究院), 助教 (30574793)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords水の光分解反応 / 色素修飾 / ポルフィリン / 電荷移動 / 無機半導体光触媒 / 有機色素
Research Abstract

In our previous study, it was found that the photocatalytic activity of GaN:ZnO was improved by modification with porphyrin dyes. In this study, the dye mixing effect on the photocatalytic water splitting activity was investigated. The mixture of Cr-TPPCl and coronen showed the most positive effect on the water splitting activity of GaN:ZnO photocatalyst. The mixing effect was attributed to the excitation energy transfer from coronen to Cr-TPPCl, because photo-excited charges which can reach to the reaction sites of dye-modified GaN:ZnO photocatalyst, was much increased by mixing modification dyes. This study revealed that the mixing modification dyes has a potential for the improvement of the photocatalytic activity of inorganic semiconductor photocatalysts.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (23 results)

All 2014 2013 2012 2011 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (15 results) Remarks (3 results)

  • [Journal Article] Dye-modification effects on water splitting activity of GaN:ZnOphotocatalyst2013

    • Author(s)
      Hidehisa Hagiwara, Masakiyo Nagatomo, Chihiro Seto, Shintaro Ida,Tatsumi Ishihara
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 272 Pages: 41-48

    • DOI

      10.1016/j.jphotochem.2013.08.022

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dye Modification Effects on TaON for Photocatalytic Hydrogen Production from Water2013

    • Author(s)
      Hidehisa Hagiwara, Masakiyo Nagatomo, Chihiro Seto, Shintaro Ida, Tatsumi Ishiahara
    • Journal Title

      Catalyst

      Volume: 3 Issue: 3 Pages: 614-624

    • DOI

      10.3390/catal3030614

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 色素修飾GaN:ZnOにおける水の光分解反応と電荷移動機構2012

    • Author(s)
      石原達己、萩原英久、伊田進太郎
    • Journal Title

      AIP Conference Proceedings

      Volume: 1482 Pages: 515-518

    • DOI

      10.1063/1.4757525

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Modification Effect of Organic Dyes on Photocatalytic Water Splitting Activity of KTa(Zr)O_32011

    • Author(s)
      M.Nagatomo, H.Hagiwara, S.Ida, T.Ishihara
    • Journal Title

      The Electrochemical Society of Japan

      Volume: 79 Issue: 40 Pages: 779-782

    • DOI

      10.1039/c1cp22425e

    • NAID

      10029482717

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Modification Effect of Organic Dyes on Photocatalytic Water Splitting Activity of KTa(Zr)O<sub>3</sub>2011

    • Author(s)
      長友真聖, 萩原英久, 伊田進太郎, 石原達己
    • Journal Title

      Electrochemistry

      Volume: 79 Issue: 10 Pages: 779-782

    • DOI

      10.5796/electrochemistry.79.779

    • NAID

      130002150471

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Modification Effects of Expanded Porphyrin on Photocatalytic Activity of GaN:ZnO for Solar Water Splitting2014

    • Author(s)
      Hidehisa Hagiwara, Motonori Watanabe, Chihiro Seto, Shintaro Ida, Tatsumi Ishihara
    • Organizer
      International Conference on Hydrogen Production 2014
    • Place of Presentation
      九州大学I2CNERホール
    • Related Report
      2013 Annual Research Report
  • [Presentation] Dye-modified photocatalysts for solar energy conversion2014

    • Author(s)
      Hidehisa Hagiwara, Shintaro Ida, Tatsumi Ishihara
    • Organizer
      Energy Technology Workshop Japan-Switzerland
    • Place of Presentation
      Gstaad-Saanen, Switzerland
    • Related Report
      2013 Annual Research Report
  • [Presentation] 色素で修飾したGaN : ZnO 固溶体光触媒による水の光完全分解(5)色素の中心金属の効果2013

    • Author(s)
      萩原英久, 瀬戸千尋, 酒井孝明, 伊田進太郎, 石原達己
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学手形キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocatalytic Water Splitting on GaN : ZnO Modified With Expanded Porphyrin for Solar Energy Harvesting2013

    • Author(s)
      萩原英久, 瀬戸千尋, 伊田進太郎, 石原達己
    • Organizer
      246th American Chemical Society National Meeting & Exposition
    • Place of Presentation
      Indianapolis, The United States of America
    • Related Report
      2013 Final Research Report
  • [Presentation] Modification Effect on Photocatalytic Activity of GaN : ZnO Solid Solution for Water Splitting2013

    • Author(s)
      萩原英久, 井上高教, 長友真聖, 伊田進太郎, 石原達己
    • Organizer
      European Materials Research Society (E-MRS)
    • Place of Presentation
      Strasbourg, France
    • Related Report
      2013 Final Research Report
  • [Presentation] Modification effect on photocatalytic activity of GaN:ZnO solid solution for water splitting2013

    • Author(s)
      Hidehisa Hagiwara, Takanori Inoue, Masakiyo Nagatomo, Shintaro Ida, Tatsumi Ishihara
    • Organizer
      European Materials Research Society (E-MRS)
    • Place of Presentation
      Strasbourg, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Photocatalytic Water Splitting on GaN:ZnO Modified With Expanded Porphyrin for Solar Energy Harvesting2013

    • Author(s)
      Hidehisa Hagiwara, Chihiro Seto, Shintaro Ida, Tatsumi Ishihara
    • Organizer
      The 1st International Symposium on Chemical Energy Conversion Processes (ISCECP-1)
    • Place of Presentation
      九州大学伊都キャンパス、箱崎キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Photocatalytic Water Splitting on GaN:ZnO Modified With Expanded Porphyrin for Solar Energy Harvesting2013

    • Author(s)
      Hidehisa Hagiwara, Chihiro Seto, Shintaro Ida, Tatsumi Ishihara
    • Organizer
      246th American Chemical Society National Meeting & Exposition
    • Place of Presentation
      Indianapolis, The United States of America
    • Related Report
      2013 Annual Research Report
  • [Presentation] 色素で修飾したGaN:ZnO固溶体光触媒による水の光完全分解(5)色素の中心金属の効果2013

    • Author(s)
      萩原英久・瀬戸千尋・酒井孝明・伊田進太郎・石原達己
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学手形キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Dye-Modified KTaO3 Photocatalyst for Solar Water Splitting2013

    • Author(s)
      Hidehisa Hagiwara, Takanori Inoue, Shintaro Ida, Tatsumi Ishihara
    • Organizer
      The 6th Japan-China Workshop on Environmental Catalysis and Eco-Materials
    • Place of Presentation
      愛媛大学南加記念ホール
    • Related Report
      2013 Annual Research Report
  • [Presentation] 色素で修飾したGaN:ZnO固溶体 光触媒による水の光完全分解2013

    • Author(s)
      萩原英久、瀬戸千尋、長友真聖、伊田進太郎、石原達己
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 色素で修飾したGaN : ZnO 固溶体光触媒による水の光完全分解(4)色素錯体の効果2012

    • Author(s)
      萩原英久, 瀬戸千尋, 伊田進太郎, 石原達己
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学伊都キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] 色素で修飾したGaN:ZnO固溶体光触媒による水の光完全分解(4)色素錯体の効果2012

    • Author(s)
      萩原英久、瀬戸千尋、伊田進太郎、石原達己
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 色素で修飾したGaN : ZnO 固溶体光触媒による水の光完全分解2011

    • Author(s)
      長友真聖, 萩原英久, 伊田進太郎, 石原達己
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 色素で修飾したZnO:GaN固溶体光触媒による水の光完全分解

    • Author(s)
      長友真聖、萩原英久、伊田進太郎、石原達己
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.cstf.kyushu-u.ac.jp/~ishihara-lab/

    • Related Report
      2013 Final Research Report
  • [Remarks] 九州大学 石原研究室

    • URL

      http://www.cstf.kyushu-u.ac.jp/~ishihara-lab/index2.html

    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.cstf.kyushu-u.ac.jp/~ishihara-lab/

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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