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Construction and STM Investigation of 2D self-assembled structures of ionized heptazine derivatives

Research Project

Project/Area Number 23681016
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Nanostructural science
Research InstitutionKagawa University (2013)
Kumamoto University (2011-2012)

Principal Investigator

UEMURA Shinobu  香川大学, 工学部, 講師 (60423498)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥26,780,000 (Direct Cost: ¥20,600,000、Indirect Cost: ¥6,180,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2011: ¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Keywords2次元自己組織化 / ヘプタジン誘導体 / 走査型プローブ顕微鏡 / 自己組織化 / 固液界面 / ナノ材料 / 超分子構造 / 自己組織化構造
Research Abstract

Heptazine derivatives are candicates as building blocks for functional nano-architectures, because of the monomers of graphitic carbon nitrides as metal-free photocatalysts. In this research, we found the ordered self-assembled structures of melem monocation at the aqueous solution–Au(111) interface. In addition, the adsorbed structures of cyamerulate anions were formed at the aqueous solution–Au(111) interface, and EC-STM revealed that the structures were stable under the electrochemical potential control.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (41 results)

All 2014 2013 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (36 results) (of which Invited: 5 results) Book (1 results) Remarks (1 results)

  • [Journal Article] ヘプタジン環誘導体の固液界面自己組織化挙動2014

    • Author(s)
      上村忍
    • Journal Title

      超分子研究会アニュアルレビュー

      Volume: 34 Pages: 8-9

    • Related Report
      2013 Final Research Report
  • [Journal Article] Thermodynamic Control of 2D Bicomponent Porous Networks of Melamine and Melem : Diverse Hydrogen-Bonded Networks2013

    • Author(s)
      S. Uemura, M. Aono, K. Sakata, T. Komatsu, M. Kunitake
    • Journal Title

      The Journal of Physical Chemistry

      Volume: 117(47) Issue: 47 Pages: 24815-24821

    • DOI

      10.1021/jp406810c

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Self-Assembled Structures of Melamine and Melem at the Aqueous Solution−Au(111) Interface2011

    • Author(s)
      Shinobu Uemura, Masashi Aono, Tamikuni Komatsu, Masashi Kunitake
    • Journal Title

      Langmuir

      Volume: 27 Pages: 1336-1340

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] 固液界面におけるシアメルル酸の2次元自己組織化挙動2014

    • Author(s)
      上村忍,中村優祐,國武雅司
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrochemical STM investigation of hydrogen bonded self-assembled structure at aqueous solutions/electrode interfaces2014

    • Author(s)
      S. Uemura, Y. Nakamura, T. Komatsu, M. Kunitake
    • Organizer
      247^<th> ACS National Meeting
    • Place of Presentation
      Dallas, TX, USA
    • Year and Date
      2014-03-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 固液界面における2次元自己組織化構造の熱力学的制御2014

    • Author(s)
      上村忍
    • Organizer
      高分子学会九州支部フォーラム2014熊本~ポリマーマテリアルの機能化戦略~
    • Place of Presentation
      熊本大学
    • Year and Date
      2014-02-27
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Electrochemical STM Investigation of Hydrogen Bonded Self-Assembled Structures at Aqueous Solutions/Electrode Interfaces2014

    • Author(s)
      Shinobu Uemura, Yusuke Nakamura, Masashi Aono, Masashi Kunitake
    • Organizer
      247th ACS National meeting
    • Place of Presentation
      Dallas Convention Center
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electrochemical STM Investigation of 2D Bicomponent Honeycomb Structures at Aqueous Solutions/Au(111) Interface2013

    • Author(s)
      S. Uemura, Y. Nakamura, T. Komatsu, M. Kunitake
    • Organizer
      ICFPAM2013
    • Place of Presentation
      University of Auckland, Auckland, New Zealand
    • Year and Date
      2013-12-09
    • Related Report
      2013 Final Research Report
  • [Presentation] 2D Bicomponent structures composed of Melamine and Melem at the Solution/Solid Interface2013

    • Author(s)
      S. Uemura, M. Aono, K. Sakata, T. Komatsu, M. Kunitake
    • Organizer
      IVC-19/ICSS-15 and ICN+T 2013
    • Place of Presentation
      Paris Palais des Congrès, Paris, France
    • Year and Date
      2013-09-11
    • Related Report
      2013 Final Research Report
  • [Presentation] 走査型トンネル顕微鏡で見る固液界面での有機分子の挙動2013

    • Author(s)
      上村忍
    • Organizer
      第29回若手化学者のための化学道場
    • Place of Presentation
      KKRホテル広島(依頼講演)
    • Year and Date
      2013-08-30
    • Related Report
      2013 Final Research Report
  • [Presentation] 走査型プローブ顕微鏡による界面における分子挙動の評価2013

    • Author(s)
      上村忍
    • Organizer
      第32回無機高分子シンポジウム「分析・解析技術の最前線」
    • Place of Presentation
      東京理科大学
    • Year and Date
      2013-06-14
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] ヘプタジン環誘導体のナノ集合体の構築とその機能評価2013

    • Author(s)
      中村優佑,上村忍,國武雅司
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2013 Annual Research Report
  • [Presentation] STM Investigation of Self-assemble Behavior of Heptazine Derivatives at Solution-Au(111) Interfaces2013

    • Author(s)
      Yusuke Nakamura, Shinobu Uemura, Masashi Kunitake
    • Organizer
      ICFPAM2013
    • Place of Presentation
      Universitu of Auckland, Newzealand
    • Related Report
      2013 Annual Research Report
  • [Presentation] 自己組織化による界面ナノ構造の構築とその場観察2013

    • Author(s)
      上村 忍
    • Organizer
      第29回若手化学者のための化学道場
    • Place of Presentation
      KKRホテル広島
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 2D Bicomponent structures composed of Melamine and Melem at the Solution/Solid Interface2013

    • Author(s)
      Shinobu Uemura, Masashi Aono, Kenki Sakata, Tamikuni Komatsu, Masashi Kunitake
    • Organizer
      IVC-19
    • Place of Presentation
      Le Palais des Congr&#232;s de Paris, Paris, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] 窒化炭素系分子メレムの自己組織化構造の電気化学的制御とpH依存性2013

    • Author(s)
      坂田憲紀
    • Organizer
      有機エレクトロニクス研究会
    • Place of Presentation
      産総研九州センター
    • Related Report
      2012 Annual Research Report
  • [Presentation] ヘプタジン環含有分子の界面自己組織化挙動におけるpHの影響2013

    • Author(s)
      中村優佑
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・草津キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 多官能性分子から成るハロゲン結合性超分子構造の構築とSTM観察2013

    • Author(s)
      稲尾由佳梨
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・草津キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 固液界面での平衡化学反応による2次元構造体の構築2012

    • Author(s)
      上村忍
    • Organizer
      第3回真空・表面科学若手勉強会
    • Place of Presentation
      甲南大学(神戸市)(依頼講演)
    • Year and Date
      2012-11-12
    • Related Report
      2013 Final Research Report
  • [Presentation] 窒化炭素系分子メレムからなる水素結合性2次元ポーラスネットワークの構2012

    • Author(s)
      上村忍,青野正志,小松民邦,國武雅司
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大
    • Year and Date
      2012-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] 窒化炭素系分子メレムからなる2次元超分子ファイバーの構築2012

    • Author(s)
      上村忍,青野正志,小松民邦,國武雅司
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜,神奈川
    • Year and Date
      2012-05-31
    • Related Report
      2013 Final Research Report
  • [Presentation] 自己組織化を利用した2次元ナノ空間制御2012

    • Author(s)
      上村忍
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(横浜市)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] In-situ Control of 2D Nanoporous Structures Consisted of Melamine and Melem at the Solution-Solid Interface2012

    • Author(s)
      上村忍
    • Organizer
      IACIS2012
    • Place of Presentation
      仙台国際会議場
    • Related Report
      2012 Annual Research Report
  • [Presentation] Construction of melem self-assembled fibers at the solution-solid interface controlled by electrochemical potential2012

    • Author(s)
      上村忍
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 窒化炭素系分子の溶液分散挙動評価2012

    • Author(s)
      西前建吾
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] βシート型ペプチドの会合体構築挙動の評価及びその固定化2012

    • Author(s)
      鋤崎晶彦
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 窒化炭素系分子メレムからなる水素結合性2次元ポーラスネットワークの構築2012

    • Author(s)
      上村忍
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 2D self-assembly of melem at the aqueous solution-Au(111) interface controlled by electrochemical pontential: scanning tunneling microscope study2012

    • Author(s)
      坂田憲紀
    • Organizer
      ICEAN2012
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2012 Annual Research Report
  • [Presentation] メレムから成る水素結合性2成分系自己組織化構造の界面挙動2012

    • Author(s)
      坂田憲紀
    • Organizer
      2012年日本化学会西日本大会
    • Place of Presentation
      佐賀大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Control of 2D Hydrogen-bonded Network Structures Consisted of Triangular Molecules at the Liquid-Solid Interface2011

    • Author(s)
      上村忍
    • Organizer
      ISSS6 (International Symposium on Surface Science -Towards Nano-, Bio-, and Green Innovation-)
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2011-12-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Control of Self-Assembled Structures of Triangular Molecules at the Solution-Solid interface : In-situ Scanning Tunneling Microscope Study2011

    • Author(s)
      上村忍
    • Organizer
      BIT's 1st Annual World Congress of Nano-S&T
    • Place of Presentation
      World EXPO Center (Dalian, China)
    • Year and Date
      2011-10-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 窒化炭素系分子からなる混合ナノ構造の構築2011

    • Author(s)
      上村忍
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学津島キャンパス(岡山市)
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] メラミン・メレム混在自己組織化構造の構築2011

    • Author(s)
      青野正志
    • Organizer
      2011年電気化学秋季大会
    • Place of Presentation
      新潟コンベンションセンター(新潟市)
    • Year and Date
      2011-09-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水素結合系超分子構造の固-液界面での構造制御2011

    • Author(s)
      上村忍
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪市)
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electrochemical control of two dimensional self-assembled structures of triangular molecules at the aqueous solution-Au(111) interface2011

    • Author(s)
      上村忍
    • Organizer
      6th International Symposium on Macrocyclic and Supramolecular Chemistry (6-ISMSC)
    • Place of Presentation
      University of Sussex (Brighton, UK)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 固-液界面におけるヘプタジン環誘導体の自己組織化挙動のSTM観察

    • Author(s)
      中村優佑,上村忍,國武雅司
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場およびAIMビル
    • Related Report
      2013 Annual Research Report
  • [Presentation] 走査型プローブ顕微鏡による界面における分子挙動の評価

    • Author(s)
      上村 忍
    • Organizer
      第32回無機高分子シンポジウム
    • Place of Presentation
      東京理科大学森戸記念館
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Electrochemical STM investigation of 2D bicomponent honeycomb structures at the aqueous solution/Au(111) interface

    • Author(s)
      Shinobu Uemura, Yusuke Nakamura, Masashi Kunitake
    • Organizer
      ICFPAM2013
    • Place of Presentation
      Universitu of Auckland, Newzealand
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固液界面における2次元自己組織化構造の熱力学的制御

    • Author(s)
      上村 忍
    • Organizer
      高分子学会九州支部フォーラム
    • Place of Presentation
      熊本大学百周年記念館
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] "界面その場成長による高分子ナノシートの創成"(高分子ナノテクノロジーハンドブック)2014

    • Author(s)
      國武雅司,上村忍
    • Publisher
      株式会社エヌティーエス
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.eng.kagawa-u.ac.jp/~shinoue/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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