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Accelerating Dynamic Analysis of Molecules by Electron Microscopy

Research Project

Project/Area Number 23681026
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Nanomaterials/Nanobioscience
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

KOSHINO MASANORI  独立行政法人産業技術総合研究所, ナノチューブ応用研究センター, 研究チーム長 (00505240)

Project Period (FY) 2011-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Keywordsナノ・マイクロ科学 / ナノ材料 / ナノバイオサイエンス / ナノ構造科学 / フラーレン・ナノチューブ・グラフェン / 電子顕微鏡 / 高速撮影 / 可視化 / 単分子 / 高感度撮影 / 有機分子
Outline of Final Research Achievements

Aiming at the visualization of individual molecules and atoms with their structural transformation or chemical reactions at atomic level, the analytical method and its peripheral elemental techniques of high-resolution transmission electron microscopy (TEM) has been developed. Imaging with high temporal resolution enhances the reliability of image quality by applying image alignment of molecular and atomic positions. Simultaneous analysis of scanning transmission electron microscopy and electron energy-loss spectroscopy (STEM-EELS) has clarified bonding states of individual atoms, distinguished different elements and different molecules. In particular, elevated temperature reduces the transformation of atomic structures, which has realized the acquisition of experimental data with atomic position and its energy states. Further study by theoretical calculations has verified the feasibility of the STEM-EELS technique.

Report

(4 results)
  • 2014 Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (12 results)

All 2014 2013 2012 2011

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (8 results) (of which Invited: 5 results) Book (2 results)

  • [Journal Article] Multiple reaction pathways of metallofullerenes investigated by transmission electron microscopy2014

    • Author(s)
      Masanori Koshino
    • Journal Title

      Dalton Trans.

      Volume: X Issue: 20 Pages: 7359-7365

    • DOI

      10.1039/c3dt53639d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic imaging and spectroscopy of low-dimensional materials with interrupted periodicities2012

    • Author(s)
      Kazu Suenaga, Kotone Akiyama-Hasegawa, Yoshiko Niimi, Haruka Kobayashi, Midori Nakamura, Zheng Liu, Yuta Sato, Masanori Koshino, and Sumio Iijima
    • Journal Title

      J Electron Microsc.

      Volume: 61 Issue: 5 Pages: 285-291

    • DOI

      10.1093/jmicro/dfs054

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 原子ひとつから化学結合情報を検出する!?2013

    • Author(s)
      越野雅至
    • Organizer
      第29 回分析電子顕微鏡討論会
    • Place of Presentation
      幕張メッセ
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 加速電圧,分解能,感度,観察試料のダメージ2012

    • Author(s)
      越野 雅至
    • Organizer
      第68回日本顕微鏡学会(指定講演)
    • Place of Presentation
      つくば国際会議場,茨城県つくば市
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Atomic level imaging and spectroscopy of nano-carbon materials2012

    • Author(s)
      Masanori Koshino
    • Organizer
      Simposia Metrology & Methodology: Thirteenth International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 実験的な単分子・単原子解析とそのエネルギー状態の理論解釈2012

    • Author(s)
      越野 雅至
    • Organizer
      第25回DV-Xα研究会
    • Place of Presentation
      福岡大学,福岡県福岡市
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Atomic level imaging and spectroscopy of nano materials2012

    • Author(s)
      Masanori Koshino
    • Organizer
      AtMol conference series 2012
    • Place of Presentation
      福岡大学,福岡県福岡市
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ナノカーボン材料を用いた単分子・単原子の挙動解析2011

    • Author(s)
      越野雅至
    • Organizer
      フラーレン・ナノチューブ・グラフェン若手研究会
    • Place of Presentation
      東京,東京大学(招待講演)
    • Year and Date
      2011-09-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] Molecular Orbital Calculations of Small Graphene-Like Species to Interpret Their Site-Dependent EELS2011

    • Author(s)
      Masanori Koshino, Hiroki Kurata, Seiji Isoda, Kazutomo Suenaga
    • Organizer
      CCTN11 : Seventh International Symposium on Computational Challenges and Tools for Nanotubes
    • Place of Presentation
      Cambridge, UK
    • Year and Date
      2011-07-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Molecular Orbital Calculations of Small Graphene-Like Species to Interpret Their Site-Dependent EELS2011

    • Author(s)
      Masanori Koshino, Hiroki Kurata, Seiji Isoda, Kazutomo Suenaga
    • Organizer
      NT11 International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Cambridge, UK
    • Year and Date
      2011-07-12
    • Related Report
      2011 Annual Research Report
  • [Book] Motional Analysis of a Single Organic Molecule by TEM Using Nanocarbon Materials: Scope of Atomic Level Imaging and Spectroscopy. in Imaging and Manipulating Molecular Orbitals (L. Grill & C. Joachim Eds).2013

    • Author(s)
      M. Koshino & K. Suenaga
    • Publisher
      Springer
    • Related Report
      2013 Annual Research Report
  • [Book] Advances in Atom and Single Molecule Machines2013

    • Author(s)
      Masanori Koshino & Kazutomo Suenaga
    • Publisher
      Springer
    • Related Report
      2012 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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