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Study on carrier recombination kinetics in bulk-heterojunction solar cells

Research Project

Project/Area Number 23684021
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Condensed matter physics I
Research InstitutionOsaka Prefecture University

Principal Investigator

KOBAYASHI Takashi  大阪府立大学, 工学(系)研究科(研究院), 准教授 (10342784)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥28,210,000 (Direct Cost: ¥21,700,000、Indirect Cost: ¥6,510,000)
Fiscal Year 2013: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Fiscal Year 2012: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2011: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Keywords有機薄膜太陽電池 / 光物性 / 緩和過程 / 太陽電池 / 有機デバイス / 非線形分光
Research Abstract

We developed experimental and analytical methods that can be applied to working organic solar cells to reveal the carrier recombination kinetics. We also fabricated solar cells with a solar conversion efficiency up to 7%, and used them as samples. It has been found that under open-circuit conditions carriers recombine via an ideal bimolecular recombination manner, whereas carriers formed in crystalline regions are extracted without a loss under short-circuit conditions. In addition, we elucidated the recombination kinetics at working points between open and short-circuit conditions, where trapped carriers play an important role.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (36 results)

All 2014 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (26 results) (of which Invited: 1 results) Book (2 results)

  • [Journal Article] Third-order optical susceptibility in polythiophene thin films prepared by spin-coating from high-boiling-point solvents2014

    • Author(s)
      T. Kobayashi, W. Shinke, T. Nagase, S. Murakami, H. Naito
    • Journal Title

      Thin Solid Films

      Volume: 554 Pages: 106-109

    • DOI

      10.1016/j.tsf.2013.05.166

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Continuous-wave photoinduced absorption study on trapped carriers in bulk- heterojunction solar cells connected to load2014

    • Author(s)
      Y. Terada, T. Kobayashi, E. Nakatsuka, T. Nagase, H. Naito
    • Journal Title

      Thin Solid Films

      Volume: 554 Pages: 209-212

    • DOI

      10.1016/j.tsf.2013.08.017

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Third-order optical susceptibility of ordered and disordered polyfluorene thin films2012

    • Author(s)
      T. Kobayashi, T. Endo, T. Nagasea, S. Murakami, and H. Naito
    • Journal Title

      J. Non-Crystalline Solids

      Volume: 358 Issue: 17 Pages: 2530-2533

    • DOI

      10.1016/j.jnoncrysol.2011.12.107

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of third-order optical susceptibility in polythiophene thin films fabricated by drop casting using anhydrous solvent2011

    • Author(s)
      T. Kobayashi, T. Endo, W. Shinke, T. Nagase, S. Murakami, and H. Naito
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 50 Issue: 7R Pages: 72601-72601

    • DOI

      10.1143/jjap.50.072601

    • NAID

      40018915974

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of carrier lifetime in bulk- heterojunction solar cells by continuous-wave photoinduced absorption spectroscopy2011

    • Author(s)
      T. Kobayashi, Y. Terada, T. Nagase, and H. Naito
    • Journal Title

      Applied Physics Express

      Volume: 4 Issue: 12 Pages: 126602-126602

    • DOI

      10.1143/apex.4.126602

    • NAID

      10030154431

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature dependence of photoluminescence properties in a thermally activated delayed fluorescence emitter

    • Author(s)
      A. Niwa, T. Kobayashi, T. Nagase, K. Goushi, C. Adachi, and H. Naito
    • Journal Title

      Applied Physics Letters

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 光誘導吸収測定による有機薄膜太陽電池の移動度評価

    • Author(s)
      小林隆史, 永瀬隆, 内藤裕義
    • Journal Title

      有機分子・バイオエレクトロニクス分科会会誌

      Volume: 25 (in press)

    • Related Report
      2013 Final Research Report
  • [Journal Article] Third-order optical susceptibility of ordered and disordered polyfluorene thin films

    • Author(s)
      T.Kobayashi, et al
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: (印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 光誘導吸収測定を用いたPTB7:PC71BMバルクヘテロ接合太陽電池の物性評価2014

    • Author(s)
      砂原智徳, 大面隆範, 中塚英美, 林隆史, 永瀬隆, 内藤裕義
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学(神奈川)
    • Year and Date
      2014-03-19
    • Related Report
      2013 Final Research Report
  • [Presentation] 光誘導吸収測定を用いたPTB7:PC71BMバルクヘテロ接合太陽電池の物性評価2014

    • Author(s)
      砂原智徳, 大面隆範, 中塚英美, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光誘導吸収測定によるPTB7:PC71BMバルクヘテロ接合太陽電池のキャリア寿命の評価2013

    • Author(s)
      砂原智徳, 小林隆史, 永瀬隆, 内藤裕義
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都)
    • Year and Date
      2013-09-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocarrier recombination kinetics in a bulk heterojunction solar cell studied by a frequency-domain measurement2013

    • Author(s)
      T. Kobayashi, T. Nagase, H. Naito
    • Organizer
      The 25th International Conference on Amorphous and Nano- crystalline Semiconductors
    • Place of Presentation
      University of Toronto (Canada)
    • Year and Date
      2013-08-22
    • Related Report
      2013 Final Research Report
  • [Presentation] 光誘導吸収によるP3HT : ICBAバルクヘテロ接合太陽電池の評価2013

    • Author(s)
      寺田洋介, 中塚英美, 小林隆史, 永瀬隆, 内藤裕義
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川)
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocarrier recombination kinetics in a bulk heterojunction solar cell studied by a frequency-domain measurement2013

    • Author(s)
      T. Kobayashi, T. Nagase, H. Naito
    • Organizer
      The 25th International Conference on Amorphous and Nano-crystalline Semiconductors
    • Place of Presentation
      Toronto, Canada
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 光誘導吸収測定によるPTB7:PC71BMバルクヘテロ接合太陽電池のキャリア寿命の評価2013

    • Author(s)
      砂原智徳, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光誘導吸収によるP3HT:ICBAバルクヘテロ接合太陽電池の評価2013

    • Author(s)
      寺田洋介, 中塚英美, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Related Report
      2012 Annual Research Report
  • [Presentation] Photoinduced absorption study on bulk- heterojunction solar cells connected to load resistance2012

    • Author(s)
      Y. Terada, T. Kobayashi, T. Nagase, and H. Naito
    • Organizer
      The 4th Asian Conference on Organic Electronics
    • Place of Presentation
      Yamagata University (Japan)
    • Year and Date
      2012-12-20
    • Related Report
      2013 Final Research Report
  • [Presentation] Continuous-wave photoinduced absorption study on trapped carriers in bulk heterojunction solar cells connected to load resistances2012

    • Author(s)
      Y. Terada, T. Kobayashi, T. Nagase, and H. Naito
    • Organizer
      10th International Conference on Nano- Molecular Electronics
    • Place of Presentation
      Awaji Yumebutai International Conference Center (Japan)
    • Year and Date
      2012-12-12
    • Related Report
      2013 Final Research Report
  • [Presentation] 負荷を接続したバルクヘテロ接合太陽電池におけるキャリアの緩和過程2012

    • Author(s)
      寺田洋介, 小林隆史, 永瀬隆, 内藤裕義
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学(愛媛)
    • Year and Date
      2012-09-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocarrier recombination mechanism in a working bulk-heterojunction solar cell studied by continuous-wave photoinduced absorption spectroscopy2012

    • Author(s)
      T. Kobayashi, Y. Terada, T. Nagase, and H. Naito
    • Organizer
      The 10th International Conference on Excitonic Processes in Condensed matter, Nanostructured and Molecular Materials
    • Place of Presentation
      University of Groningen (Netherlands)
    • Year and Date
      2012-07-05
    • Related Report
      2013 Final Research Report
  • [Presentation] 光誘導吸収分光による二分子再結合キャリアの寿命決定2012

    • Author(s)
      寺田洋介, 小林隆史, 永瀬隆, 内藤裕義
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2012-03-16
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocarrier recombination mechanism in a working bulk-heterojunction solar cells studied by cw-PIA spectroscopy2012

    • Author(s)
      T. Kobayashi, T. Nagase, and H. Naito
    • Organizer
      EXCON 2012
    • Place of Presentation
      オランダ
    • Related Report
      2012 Annual Research Report
  • [Presentation] 負荷を接続したバルクヘテロ接合太陽電池におけるキャリアの緩和過程2012

    • Author(s)
      寺田洋介, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      徳島
    • Related Report
      2012 Annual Research Report
  • [Presentation] Continuous-wave photoinduced absorption study on trapped carriers in bulk heterojunction solar cells connected to load resistances2012

    • Author(s)
      Y. Terada, T. Kobayashi, T. Nagase, and H. Naito
    • Organizer
      The 10th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      神戸
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electroabsorption study of P3HT : PCBM bulk heterojunction solar cells2011

    • Author(s)
      W. Shinke, T. Kobayashi, T. Nagase, and H. Naito
    • Organizer
      21st International Photovoltaic Science and Engineering Conference
    • Place of Presentation
      Hilton Fukuoka Sea Hawk (Japan)
    • Year and Date
      2011-11-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Electroabsorption study of P3HT:PCBM bulk heterojunction solar cells2011

    • Author(s)
      W.Shinke, T.Kobayashi, et al
    • Organizer
      21st International Photovoltaic Science and Engineering Conference
    • Place of Presentation
      福岡
    • Year and Date
      2011-11-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 変調分光法による有機薄膜太陽電池におけるキャリア寿命の見積もり2011

    • Author(s)
      小林隆史, 寺田洋介, 永瀬隆, 内藤裕義
    • Organizer
      薄膜材料デバイス研究会第8回研究集会
    • Place of Presentation
      龍谷大学アバンティ響都ホール(京都)
    • Year and Date
      2011-11-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Determination of Carrier Lifetime in Bulk- heterojunction Solar Cells by Continuous-wave Photoinduced Absorption Spectroscopy2011

    • Author(s)
      Y. Terada, W. Shinke, T. Kobayashi, T. Nagase, H. Naito
    • Organizer
      2011 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Aichi Industry & Labor Center (Japan)
    • Year and Date
      2011-09-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Determination of Carrier Lifetime in Bulk-heterojunction Solar Cells by Continuous-wave Photoinduced Absorption Spectroscopy2011

    • Author(s)
      Y.Terada, W.Shinke, T.Kobayashi, et al
    • Organizer
      International Conference on Solid State Devices and Materials (SSDM2011)
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Photocarrier recombination dynamics studied by continuous-wave photoinduced absorption spectroscopy in bulk heterojunction solar cells2011

    • Author(s)
      T. Kobayashi, Y. Terada, T. Nagase, H. Naito
    • Organizer
      The 11th European Conference on Molecular Electronics
    • Place of Presentation
      Aduitorio Axa (Spain)
    • Year and Date
      2011-09-07
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocarrier recombination dynamics studied by continuous-wave photoinduced absorption spectroscopy in bulk heterojunction solar cells2011

    • Author(s)
      T.Kobayashi, et al
    • Organizer
      The 11th European Conference on Molecular Electronics
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2011-09-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] P3HT : PCBMバルクへテロ接合型有機太陽電池における電場変調吸収分光2011

    • Author(s)
      新家渉, 小林隆史, 永瀬隆, 内藤裕義
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形)
    • Year and Date
      2011-09-02
    • Related Report
      2013 Final Research Report
  • [Presentation] Carrier dynamics in bulk heterojunction solar cells studied by modulation spectroscopy2011

    • Author(s)
      T. Kobayashi, Y. Terada, T. Nagase, H. Naito
    • Organizer
      The 24th International Conference on Amorphous and Nanocrystalline Semiconductors
    • Place of Presentation
      Nara Prefecture Public New Hall (Japan)
    • Year and Date
      2011-08-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Carrier dynamics in bulk heterojunction solar cells studied by modulation spectroscopy2011

    • Author(s)
      T.Kobayashi, et al
    • Organizer
      The 24th International Conference on Amorphous and Nanocrystalline Semiconductors (ICANS 24)
    • Place of Presentation
      奈良
    • Year and Date
      2011-08-25
    • Related Report
      2011 Annual Research Report
  • [Book] "Electronic Structures of Planar and Nonplanar Polyfluorene" in "Excitonic and Photonic Processes in Materials" ed. by J.Singh and R.T. Williams2014

    • Author(s)
      T. Kobayashi, T. Nagase, H. Naito
    • Total Pages
      10
    • Publisher
      Springer
    • Related Report
      2013 Annual Research Report
  • [Book] "Electronic Structures of Planar and Nonplanar Polyfluorene,"Ch.3 in"Excitonic and Photonic Processes in Materials"ed. by J. Singh and R.T. Williams

    • Author(s)
      T. Kobayashi, T. Nagase, and H. Naito
    • Publisher
      Springer (in press)
    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-04-06   Modified: 2020-05-15  

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