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Interface structure of organic transistors

Research Project

Project/Area Number 23684026
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Condensed matter physics II
Research InstitutionOsaka University

Principal Investigator

WAKABAYASHI Yusuke  大阪大学, 基礎工学研究科, 准教授 (40334205)

Project Period (FY) 2011-11-18 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords表面・界面物性 / 物性実験 / 固液界面 / 放射光 / 有機デバイス / イオン液体
Research Abstract

Current technology to fabricate electronic devices is based on Si. However, recent study revealed that organic semiconductors can be utilized for making devices with totally different characteristics, such as lightweight, flexible devices. In this study, we performed structural study of interfaces to improve organic devices. High resolution, non-destructive measurements of interfaces were realized by using surface synchrotron X-ray diffraction technique. We clarified two interface structures; one is the surface structure of organic semiconductor tetracene, and the other is the electric double layer structure made of ionic liquid. The latter includes applied electric voltage dependence of the structure. Layered arrangement of the anions/cations was observed, and the ionic arrangement was controlled by the applied voltage.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (48 results)

All 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 6 results) Presentation (37 results) (of which Invited: 15 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Si Doping Effect on the Structure of Multiferroic Mn_2Ge_1-x Si_xO_42014

    • Author(s)
      H. Fqjii, T. Honda, T. Kimura, Y. Wakabayashi
    • Journal Title

      JPS Conference Proceedings

      Volume: vol.1

    • DOI

      10.7566/jpscp.1.012085

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] フラストレート磁性体Ba3CuSb2O9 のスピンと軌道の相関2014

    • Author(s)
      若林裕助
    • Journal Title

      放射光

      Volume: 27

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamical spin-orbital correlation in the frustrated magnet Ba_3CuSb_2O_92013

    • Author(s)
      Y. Ishiguro, K. Kimura, S. Nakatsuji, S. Tsutsui, A. Q. R. Baron T. Kimura, and Y. Wakabayashi
    • Journal Title

      Nature Commun

      Volume: 4 Issue: 1

    • DOI

      10.1038/ncomms3022

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Valence ordering in the intermediate-valence magnet YbPd2013

    • Author(s)
      R. Takahashi, T. Horlda, A. Miyako, T. Kagayama, K. Shimizu, T. Ebihara, T. Kimura, Y. Wakabayashi
    • Journal Title

      Physical Review B

      Volume: vol.88 Issue: 5

    • DOI

      10.1103/physrevb.88.054109

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure Analysis of Transition Metal Oxide Ultrathinfilms by Means of Surface X-ray Diffraction Technique2013

    • Author(s)
      若林裕助
    • Journal Title

      Materia Japan

      Volume: 52 Issue: 12 Pages: 554-557

    • DOI

      10.2320/materia.52.554

    • NAID

      130003388689

    • ISSN
      1340-2625, 1884-5843
    • Related Report
      2013 Annual Research Report
  • [Journal Article] Structural investigation of magnetocapacitive SmMnO<sub>3</sub>2013

    • Author(s)
      H.Maeda, Y.Ishiguro, T.Honda, J.-S.Jung, S.Michimura, T.Inami, T.Kimura and Y.Wakabayashi
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 121 Issue: 1411 Pages: 265-267

    • DOI

      10.2109/jcersj2.121.265

    • NAID

      130004950821

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] External electric field dependence of the structure of the electric double layer at an ionic liquid/Au interface2012

    • Author(s)
      R. Yamamoto, H. Morisaki, O. Sakata, H. Shimotani, H.-T. Yuan, Y. Iwasa, T. Kimura, and Y. Wakabayashi
    • Journal Title

      Appl. Phys. Lett

      Volume: 101 Pages: 53122-53122

    • Related Report
      2013 Final Research Report
  • [Journal Article] External electric field dependence of the structure of the electric double layer at an ionic liquid/Au interface2012

    • Author(s)
      R. Yamamoto, H. Morisaki, O. Sakata, H. Shimotani, H. T. Yuan, Y. Iwasa, T. Kimura, Y. Wakabayashi
    • Journal Title

      Applied Physics Letters

      Volume: 101 Issue: 5 Pages: 053122-053122

    • DOI

      10.1063/1.4742920

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機デバイスの高度化を目指した深さ分解構造解析2014

    • Author(s)
      若林裕助
    • Organizer
      SPRUC拡大研究会・SPring-8利用ワークショップ(SPring-8)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 表面近傍の電気伝導の微視的理解を目指した表面構造解析2014

    • Author(s)
      若林裕助
    • Organizer
      文部科学省ナノテクノロジープラットフォーム事業微細構造解析プラットフォーム「利用研究セミナー」
    • Place of Presentation
      イーグレ姫路
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 分子性界面の電子状態2013

    • Author(s)
      若林裕助
    • Organizer
      日本物理学会第68回年次大会領域7シンポジウム
    • Place of Presentation
      広島大学
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Interfacial Structure Analyses of Metal Oxide Heterostructures2013

    • Author(s)
      Y. Wakabayashi
    • Organizer
      第74回応用物理学会秋季学術講演会企画シンポジウム International Symposium on the Ultra-functionalities of Oxide Heterostructures and Nanocomposites
    • Place of Presentation
      同志社
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 有機トランジスタの伝導層における分子構造の観測2013

    • Author(s)
      若林裕助
    • Organizer
      2013年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Invited
  • [Presentation] Formation of an ionic liquid - gold interface studied by time-resolved X-ray reflectivity2013

    • Author(s)
      W. Voegeli, E. Arakawa, T. Matsushita, Y.F. Yano, O. Sakata and Y. Wakabayashi
    • Organizer
      Light and Particle Beams in Materials Science 2013
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Formation of an ionic liquid - gold interface studied by time-resolved X-ray reflectivity2013

    • Author(s)
      W. Voegeli, E. Arakawa, T. Matsushita, Y.F. Yano, O. Sakata and Y. Wakabayashi
    • Organizer
      Light and Particle Beams in Materials Science 2013
    • Place of Presentation
      Tsukuba International Congress Center
    • Related Report
      2013 Annual Research Report
  • [Presentation] Chiral Domain Imaging in DyFe$_3$(BO$_3$)$_4$ observed by resonant x-ray diffraction2013

    • Author(s)
      T. Usui, Y. Tanaka, H. Nakajima, Y. Wakabayashi, S. Shin, and T. Kimura
    • Organizer
      Workshop on Resonant Elastic X-ray Scattering in Condensed Matter
    • Place of Presentation
      Oxford, UK
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structural study of multiferroic compound Mn$_2$Ge$_{1-x}$Si$_x$O$_4$2013

    • Author(s)
      H. Fujii, T. Honda, T. Kimura and Y. Wakabayashi
    • Organizer
      The 12th Asia Pacific Physics Conference (2013)
    • Place of Presentation
      Makuhari Messe Chiba, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Valence arrangement in the intermediate valence magnet YbPd2013

    • Author(s)
      R. Takahashi, T. Honda, A. Miyake, T. Kagayama, K. Shimizu, T. Ebihara, T. Kimura, and Y. Wakabayashi
    • Organizer
      The International Conference on Strongly Correlated Electron Systems
    • Place of Presentation
      Univ. of Tokyo
    • Related Report
      2013 Annual Research Report
  • [Presentation] テトラセン単結晶の表面電子密度解析2013

    • Author(s)
      森崎はづき,三輪一元,竹谷純一,木村剛,若林裕助
    • Organizer
      日本物理学会 第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 分子性界面の電子状態2013

    • Author(s)
      若林裕助
    • Organizer
      日本物理学会 第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 有機半導体テトラセン単結晶の表面構造2013

    • Author(s)
      森崎はづき,三輪一元,竹谷純一,木村剛,若林裕助
    • Organizer
      第26回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      名古屋大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 界面における特異な物性の放射光CTR散乱ホログラフィによる微視的研究2012

    • Author(s)
      若林裕助
    • Organizer
      日本表面科学会第72回表面科学研究会特定原子周りの構造の三次元可視化~原子分解能ホログラフィーの可能性を探る~
    • Place of Presentation
      東京理科大学
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Interfacial structure of functional metal oxides2012

    • Author(s)
      Y. Wakabayashi
    • Organizer
      6th International Conference on the Science and Technology for Advanced Ceramics
    • Place of Presentation
      Mielparque Yokohama
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Ba_3CuSb_2O_9の軌道短距離秩序2012

    • Author(s)
      若林裕助
    • Organizer
      基研研究会「量子スピン系の物理」
    • Place of Presentation
      京都大学
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Surface structure analysis of the organic semiconductor tetracene single crystals2012

    • Author(s)
      H. Morisaki, K. Miwa, J. Takeya, T. Kimura, and Y. Wakabayashi
    • Organizer
      International workshop on 3D atomic imaging at nano-scale active sites in materials
    • Place of Presentation
      Kashiwa, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Application of surface x-ray scattering holography to complex materials2012

    • Author(s)
      Y.Wakabayashi
    • Organizer
      International workshop on 3D atomic imaging at nano-scale active sites in materials
    • Place of Presentation
      東大物性研
    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
  • [Presentation] Surface structure analysis of the organic semiconductor tetracene single crystals2012

    • Author(s)
      H.Morisaki, K.Miwa, J.Takeya, T.Kimura, and Y.Wakabayashi
    • Organizer
      International workshop on 3D atomic imaging at nano-scale active sites in materials
    • Place of Presentation
      東大物性研
    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
  • [Presentation] External electric field control of the electric double layer structure at an ionic liquid/Au interface2012

    • Author(s)
      Y.Wakabayashi, R.Yamamoto, H.Morisaki, O.Sakata, H.Shimotani, H.T.Yuan, Y.Iwasa and T.Kimura
    • Organizer
      the 11th International Conference on Synchrotron Radiation Instrumentation
    • Place of Presentation
      Lyon, France
    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
  • [Presentation] Interfacial structure of functional metal oxides2012

    • Author(s)
      Y.Wakabayashi
    • Organizer
      6th International Conference on the Science and Technology for Advanced Ceramics
    • Place of Presentation
      メルパルク横浜
    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Invited
  • [Presentation] 界面における特異な物性の放射光CTR散乱ホログラフィによる微視的研究2012

    • Author(s)
      若林裕助
    • Organizer
      日本表面科学会 第72回表面科学研究会 特定原子周りの構造の三次元可視化~原子分解能ホログラフィーの可能性を探る~
    • Place of Presentation
      東京理科大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Voltage dependence of the electric double layer structure at an ionic liquid/Au interface2012

    • Author(s)
      Y.Wakabayashi, R.Yamamoto, H.Morisaki, O.Sakata, H.Shimotani, H.-T.Yuan, Y.Iwasa, and T.Kimura
    • Organizer
      2012 March Meeting, American Physical Society
    • Place of Presentation
      Boston, USA
    • Related Report
      2011 Annual Research Report
  • [Presentation] 電気二重層トランジスタの微視的構造:イオン液体-金(111)界面構造の電圧依存性2012

    • Author(s)
      山本涼介,森崎はづき,坂田修身,下谷秀和,袁洪涛,岩佐義宏,木村剛,若林裕助
    • Organizer
      日本物理学会 第67回年次大会
    • Place of Presentation
      関西学院大
    • Related Report
      2011 Annual Research Report
  • [Presentation] テトラセン単結晶の表面構造2012

    • Author(s)
      森崎はづき,三輪一元,竹谷純一,木村剛,若林裕助
    • Organizer
      日本物理学会 第67回年次大会
    • Place of Presentation
      関西学院大
    • Related Report
      2011 Annual Research Report
  • [Presentation] 界面における特異な物性の放射光CTR散乱ホログラフィによる微視的研究2012

    • Author(s)
      若林裕助
    • Organizer
      日本表面科学会 第72回表面科学研究会 特定原子周りの構造 の三次元可視化&#771;原子分解能ホログラフィーの可能性を探る&#771;
    • Place of Presentation
      東京理科大学
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] イオン液体 金界面に於ける電気二重層形成の時分割観察

    • Author(s)
      Voegeli Wolfgang,荒川悦雄,松下正,坂田修身,若林裕助
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 円偏光共鳴X線回折を用いたRFe3(BO3)4におけるカイラル構造の研究

    • Author(s)
      中島宏,薄井智靖,田中良和,若林裕助,木村剛
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] マルチフェロイックMn2GeO4における電磁場下偏極中性子回折

    • Author(s)
      本田孝志,J. S. White,M. Kenzelmann,L. C. Chapon,若林裕助,木村剛
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 膜厚に依存した伝導性を示すLaNiO3超薄膜の構造

    • Author(s)
      前田裕貴,坂井延寿,組頭広志,坂田修身,木村剛,若林裕助
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Interfacial Structure Analyses of Metal Oxide Heterostructures

    • Author(s)
      Y.Wakabayashi
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機デバイスの高度化を目指した深さ分解構造解析

    • Author(s)
      若林裕助
    • Organizer
      SPRUC拡大研究会・SPring-8利用ワークショップ
    • Place of Presentation
      SPring-8
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 表面近傍の電気伝導の微視的理解を目指した表面構造解析

    • Author(s)
      若林裕助
    • Organizer
      文部科学省ナノテクノロジープラットフォーム事業 微細構造解析プラットフォーム「利用研究セミナー」講演
    • Place of Presentation
      イーグレ姫路
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Near Surface Structure of Organic Semiconductor Tetracene Single Crystal

    • Author(s)
      Y.~Wakabayashi, H.Morisaki, T.Kimura, K.Miwa, T.Koretsune, J.Takeya
    • Organizer
      2014 March Meeting, American Physical Society
    • Place of Presentation
      Denver convention center
    • Related Report
      2013 Annual Research Report
  • [Presentation] 強磁性相転移が電場制御されるCo超薄膜の構造に対する電場効果

    • Author(s)
      藤井宏昌,千葉大地,小山知弘,坂田修身,木村剛,若林裕助
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 円偏光共鳴X線回折によるDyFe3(BO3)4の構造カイラリティの研究 吸収端依存性

    • Author(s)
      中島宏,薄井智靖,田中良和,若林裕助,木村剛
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ba3CuSb2O9のCu/Sb短距離秩序構造

    • Author(s)
      若林裕助,中島大輔,木村健太,木村剛,中辻知
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Book] Chapter "Pico-Scale Electron Density Analysis of Organic Crystals" in "Fundamentals of picoscience", Edited by K. Sattler2013

    • Author(s)
      Y. Wakabayashi
    • Publisher
      CRC press
    • Related Report
      2013 Final Research Report
  • [Book] Fundamentals of picoscience (Chapter "Pico-Scale Electron Density Analysis of Organic Crystals")2013

    • Author(s)
      Y.Wakabayashi (Editor: K.D.Sattler)
    • Publisher
      CRC press
    • Related Report
      2012 Annual Research Report
  • [Remarks] 電子のスピンと軌道の絡み合った共鳴状態の世界初の解明

    • URL

      http://resou.osaka-u.ac.jp/ja/research/2013/20130617_1

    • Related Report
      2013 Annual Research Report

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Published: 2013-05-15   Modified: 2020-05-15  

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