Synthesis of Heterographenes via Tandem Hetero-Friedel-Crafts Reactions
| Project/Area Number |
23685020
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kwansei Gakuin University (2013)
Kyoto University (2011-2012) |
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Principal Investigator |
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥29,250,000 (Direct Cost: ¥22,500,000、Indirect Cost: ¥6,750,000)
Fiscal Year 2013: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2012: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2011: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
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| Keywords | グラフェン / π共役化合物 / フリーデルクラフツ / ヘテロ原子 |
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| Research Abstract |
We have developed tandem hetero-Friedel Crafts reactions and multiple cross-coupling reactions toward synthesis of heterographene, which attracts the interest of chemists and physicists in recent years. Using these reactions, we have succeeded in short-step synthesis of heteronanographenes, substructure molecules of heterographenes. These molecules showed high charge transport ability and fluorescence property and thus enabled us to fabricate phosphorescent OLED with high efficiency. Heteronanographenes are new and promising materials for organic electronics.
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Report
(4 results)
Research Products
(48 results)
