Development of Catalytic Transformations of Carbon-Carbon, Carbon-Oxygen and Carbon-Silicon Bonds
| Project/Area Number |
23685021
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
TOBISU Mamoru 大阪大学, 工学(系)研究科(研究院), 准教授 (60403143)
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| Project Period (FY) |
2011-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥28,990,000 (Direct Cost: ¥22,300,000、Indirect Cost: ¥6,690,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2012: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2011: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
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| Keywords | 均一系触媒 / 不活性結合活性化 / 炭素－酸素結合活性化 / 炭素－窒素結合活性化 / 炭素－リン結合活性化 / クロスカップリング / 炭素－炭素結合活性化 / 不活性結合切断 |
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| Outline of Final Research Achievements |
Current synthetic methods depend on the ue of reactive chemical bonds. To change this situation, we have developed catalytic trasnformations of strong sigma bonds, in paricular those other than carbon-hydrogen bonds, which are the subject of intensive studies. Specific chemical bonds that we successfully used for catalytic transformations include carbon-carbon, carbon-oxygen, carbon-nitrogen, and carbon-phosphorus bonds. Through this study, we have expanded our own strategy for the activation of strong sigma bonds via the mechanism other than classical oxidative addition.
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Report
(5 results)
Research Products
(10 results)
