| Budget Amount *help |
¥29,380,000 (Direct Cost: ¥22,600,000、Indirect Cost: ¥6,780,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2011: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
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| Research Abstract |
In the present study, we investigated concurrent mixed polymerizations by interconvertible intermediates via various covalent bond, such as C–S and C-X (X: halogen) bonds. By using C-S bond as the dormant species, we found that concurrent cationic and radical copolymerization prodeeded well in a living fashion to form multiblock-type copolymer consinsting of cationically-and radically-polymerized segments. Furthermore, we achieved that mechanistic transformation from anionic polymerization to radical one with C–X bond as the dormant species.
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