Development of Novel Polymerization System
| Project/Area Number |
23685023
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
SATOH Kotaro 名古屋大学, 工学(系)研究科(研究院), 准教授 (70377810)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥29,380,000 (Direct Cost: ¥22,600,000、Indirect Cost: ¥6,780,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2011: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
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| Keywords | 高分子合成 / 精密重合 / リビング重合 / ラジカル重合 / カチオン重合 / アニオン重合 / 構造・機能材料 / 高分子構造・物性 |
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| Research Abstract |
In the present study, we investigated concurrent mixed polymerizations by interconvertible intermediates via various covalent bond, such as C–S and C-X (X: halogen) bonds. By using C-S bond as the dormant species, we found that concurrent cationic and radical copolymerization prodeeded well in a living fashion to form multiblock-type copolymer consinsting of cationically-and radically-polymerized segments. Furthermore, we achieved that mechanistic transformation from anionic polymerization to radical one with C–X bond as the dormant species.
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Report
(4 results)
Research Products
(27 results)
