Development of Oxidative Carbon-Carbon Bond Forming Reactions Based on the Concept of Site Isolation
| Project/Area Number |
23685036
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Environmental chemistry
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| Research Institution | Shibaura Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2011-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥28,730,000 (Direct Cost: ¥22,100,000、Indirect Cost: ¥6,630,000)
Fiscal Year 2014: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2013: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2012: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2011: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
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| Keywords | 有機化学 / 活性点分離 / 炭素カチオン / 合成化学 / 炭素-炭素結合形成反応 / 固体酸 / 固体塩基 |
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| Outline of Final Research Achievements |
We have successfully developed direct oxidative carbon-carbon bond forming reactions based on the concept of site isolation. We have also developed indirect oxidative carbon-carbon bond forming reactions using anodic hydroxylation as a key step. Furthermore, one-pot electrosynthesis (paired electrosynthesis) of β-nitroalcohols using benzylalcohols as a starting material has been achieved based on the site isolation between an anode and a cathode in electrochemical reactions.
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Report
(5 results)
Research Products
(15 results)
