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Elucidation of Micro and Nano Freezing in Catalyst Layer and Water Transfer in PEFC

Research Project

Project/Area Number 23686034
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionHokkaido University

Principal Investigator

TABE Yutaka  北海道大学, 工学(系)研究科(研究院), 准教授 (80374578)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2013: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2011: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Keywords燃料電池 / 水輸送現象 / 凍結
Research Abstract

The objective of this study is to elucidate the freezing mechanism in the catalyst layer (CL) at cold start and water transport phenomena in the vicinity of the micro-porous layer (MPL) in PEFC. The freezing model was developed, and the detailed observation of the MPL cross-section was conducted. These showed that the ice distribution formed during the -20 degree C cold start strongly depends on the current density, but not on the oxygen supply condition. This study also identified the factor controlling the ice distribution, and the liquid water distribution under normal operations above freezing temperature.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (27 results)

All 2014 2013 2012 2011 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Open Access: 1 results) Presentation (14 results)

  • [Journal Article] Observation of water transport in the micro-porous layer of a polymer electrolyte fuel cell with a freezing method and cryo-scanning electron microscope2014

    • Author(s)
      Y. Aoyama, K. Suzuki, Y. Tabe, T. Chikahisa
    • Journal Title

      Electrochemistry Communications

      Volume: 41巻 Pages: 72-75

    • DOI

      10.1016/j.elecom.2013.12.029

    • NAID

      120005462412

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of interfacial structure between micro-porous layer and catalyst layer on water on transport in PEFC2013

    • Author(s)
      Y. Aoyama, K. Suzuki, Y. Tabe, T. Chikahisa, T. Tanuma
    • Journal Title

      ECS Transactions

      Volume: 58巻 Issue: 1 Pages: 1383-1390

    • DOI

      10.1149/05801.1383ecst

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of Ice Distribution in Cathode Catalyst Layer and Shutdown Mechanism at PEFC Cold Start2013

    • Author(s)
      M. Yamada, K. Suzuki, Y. Tabe, T. Chikahisa
    • Journal Title

      ECS Transactions

      Volume: 58巻 Issue: 1 Pages: 463-471

    • DOI

      10.1149/05801.0463ecst

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Water Transfer Phenomena in Micro-Porous Layer of PEFC2012

    • Author(s)
      Y. Aoyama, K. Kadowaki, Y. Tabe, T. Chikahisa
    • Journal Title

      ECS Transactions

      Volume: 50巻 Issue: 2 Pages: 445-452

    • DOI

      10.1149/05002.0445ecst

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Analysis and Experiments of Major Parameters in Catalyst Layer Structure Affecting on PEFC Performance2012

    • Author(s)
      M. Kobayashi, Y. Tabe, T. Chikahisa
    • Journal Title

      ECS Transactions

      Volume: 50巻 Issue: 2 Pages: 415-422

    • DOI

      10.1149/05002.0415ecst

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of ice formation process in cathode catalyst layer of PEFC at cold start2012

    • Author(s)
      Y. Tabe, R. Ichikawa, T. Chikahisa
    • Journal Title

      Energy Procedia

      Volume: 28巻 Pages: 20-27

    • DOI

      10.1016/j.egypro.2012.08.036

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cold start characteristics and freezing mechanism dependence on start-up temperature in a polymer electrolyte membrane fuel cell2012

    • Author(s)
      Y. Tabe, M. Saito, K. Fukui, T. Chikahisa
    • Journal Title

      Journal of Power Sources

      Volume: 208巻 Pages: 366-373

    • DOI

      10.1016/j.jpowsour.2012.02.052

    • NAID

      120005946608

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Analysis and Experiments of Major Parameters in Catalyst Layer Structure Affecting on PEFC Performance2012

    • Author(s)
      M. Kobayashi,他2名
    • Journal Title

      ECS Transactions

      Volume: 50 Pages: 415-422

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Water Transfer Phenomena in Micro-Porous Layer of PEFC2012

    • Author(s)
      Y. Aoyama, 他3名
    • Journal Title

      ECS Transactions

      Volume: 50 Pages: 445-452

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ice Formation and Current Distribution in the Catalyst Layer of PEM Fuel Cell at Cold Start2011

    • Author(s)
      R. Ichikawa, Y. Tabe, T. Chikahisa
    • Journal Title

      ECS Transactions

      Volume: 41巻 Issue: 1 Pages: 733-740

    • DOI

      10.1149/1.3635607

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Role of Micro-Porous Layer for Water Transfer Phenomena in PEFC2011

    • Author(s)
      K. Kadowaki, Y. Tabe, T. Chikahisa
    • Journal Title

      ECS Transactions

      Volume: 41巻 Issue: 1 Pages: 431-438

    • DOI

      10.1149/1.3635577

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Role of Micro-Porous Layer for Water Transfer Phenomena in PEFC2011

    • Author(s)
      K.Kadowaki, 他2名
    • Journal Title

      ECS Transactions

      Volume: 41 Pages: 431-438

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ice Formation and Current Distribution in the Catalyst Layer of PEM Fuel Cell at Cold start2011

    • Author(s)
      R.Ichikawa, 他2名
    • Journal Title

      ECS Transactions

      Volume: 41 Pages: 733-740

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] PEFC氷点下起動時における発電停止メカニズム解明のための触媒層内酸素輸送抵抗解析2013

    • Author(s)
      山田一樹,鈴木研悟,田部豊,近久武美
    • Organizer
      第18回動力・エネルギー技術シンポジウム
    • Place of Presentation
      千葉大学けやき会館(千葉市)
    • Year and Date
      2013-06-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 凍結固定化法を用いた固体高分子形燃料電池におけるMPL内水輸送現象のCryo-SEM観察2013

    • Author(s)
      青山祐介,鈴木研悟,田部豊,近久武美,田沼敏弘
    • Organizer
      第50回日本伝熱シンポジウム
    • Place of Presentation
      ウェスティンホテル仙台(仙台市)
    • Year and Date
      2013-05-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体高分子形燃料電池性能に及ぼす触媒層構造影響に関する実験およびモデル計算比較2012

    • Author(s)
      小林将矢,田部豊,近久武
    • Organizer
      日本機械学会2012年度年次大会
    • Place of Presentation
      金沢大学(金沢市)
    • Year and Date
      2012-09-11
    • Related Report
      2013 Final Research Report
  • [Presentation] PEFC氷点下起動時におけるカソード触媒層内氷形成プロセスの観察2012

    • Author(s)
      市川亮輔,山田一樹,田部豊,近久武美
    • Organizer
      第49回日本伝熱シンポジウム
    • Place of Presentation
      富山国際会議場(富山市)
    • Year and Date
      2012-06-01
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体高分子形燃料電池内の生成水移動現象に及ぼすMPLの影響2012

    • Author(s)
      門脇主将,田部豊,近久武美
    • Organizer
      第49回日本伝熱シンポジウム
    • Place of Presentation
      富山国際会議場(富山市)
    • Year and Date
      2012-06-01
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体高分子形燃料電池内の凝縮水分布に及ぼすMPLの影響2011

    • Author(s)
      門脇主将,田部豊,近久武美
    • Organizer
      第16回動力・エネルギー技術シンポジウム
    • Place of Presentation
      関西大学(吹田市)
    • Year and Date
      2011-06-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体高分子形燃料電池内の凝縮水分布に及ぼすMPLの影響2011

    • Author(s)
      門脇主将, 他2名
    • Organizer
      第16回動力・エネルギー技術シンポジウム
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2011-06-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] 氷点下起動時におけるPEFC内凍結現象が常温復帰運転に及ぼす影響2011

    • Author(s)
      市川亮輔,田部豊,近久武美
    • Organizer
      第16回動力・エネルギー技術シンポジウム
    • Place of Presentation
      関西大学(吹田市)
    • Year and Date
      2011-06-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 氷点下起動時におけるPEFC内凍結現象が常温復帰運転に及ぼす影響2011

    • Author(s)
      市川亮輔, 他2名
    • Organizer
      第16回動力・エネルギー技術シンポジウム
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2011-06-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 凍結固定化法を用いた固体高分子形燃料電池におけるMPL内水輸送現象のCryo-SEM観察

    • Author(s)
      青山祐介,鈴木研悟,田部豊,近久武美,田沼敏弘
    • Organizer
      第50回日本伝熱シンポジウム
    • Place of Presentation
      ウェスティンホテル仙台(仙台市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] PEFC氷点下起動時における発電停止メカニズム解明のための触媒層内酸素輸送抵抗解析

    • Author(s)
      山田一樹,鈴木研悟,田部豊,近久武美
    • Organizer
      第18回動力・エネルギー技術シンポジウム
    • Place of Presentation
      千葉大学けやき会館(千葉市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固体高分子形燃料電池内の生成水移動現象に及ぼすMPLの影響

    • Author(s)
      近久武美,他2名
    • Organizer
      第49回日本伝熱シンポジウム
    • Place of Presentation
      富山国際会議場(富山県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] PEFC 氷点下起動時におけるカソード触媒層内氷形成プロセスの観察

    • Author(s)
      山田一樹,他3名
    • Organizer
      第49回日本伝熱シンポジウム
    • Place of Presentation
      富山国際会議場(富山県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 固体高分子形燃料電池性能に及ぼす触媒層構造影響に関する実験およびモデル計算比較

    • Author(s)
      小林将矢,他2名
    • Organizer
      日本機械学会2012年度年次大会
    • Place of Presentation
      金沢大学(石川県)
    • Related Report
      2012 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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