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Development of anode of high performance lithium ion capacitors using single-walled carbon nanotube thin films

Research Project

Project/Area Number 23686092
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

SATO Yoshinori  東北大学, 環境科学研究科, 准教授 (30374995)

Research Collaborator ITOH Takashi  東北大学, 学際科学フロンティア研究所, 准教授
ONEGAWA Satoshi  NECトーキン株式会社, 部長
HATO Yukinori  NECトーキン株式会社, シニアエキスパート
MIYAGAWA Risa  NECトーキン株式会社, 主任
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥23,530,000 (Direct Cost: ¥18,100,000、Indirect Cost: ¥5,430,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2011: ¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Keywords表面・界面物性 / 単層カーボンナノチューブ / 蓄電池 / リチウムイオンキャパシタ / 電気二重層
Research Abstract

We investigated the properties of lithium ion capacitors (LICs) using highly crystalline single-walled carbon nanotube (SWCNT) thin films with carboxyl groups as an anode. The decrease of the capacity of LICs was suppressed at a high rate, and also the decrease of the capacitance and the increase of the internal resistance were suppressed at overcharging voltages. If the capacitance of SWCNTs is large, we can fabricate a high performance LICs. In contrast, the properties of the LICs decrease at over-discharging voltages. In the future, we need to clarify phenomena caused in SWCNT electrodes in over-discharging.
We synthesized ethylenediaminated SWCNTs (EDA-SWCNTs) from fluorinated SWCNTs and investigated the properties of electric double-layer supercapacitors (EDLSCs) with EDA-SWCNTs as electrodes. Free-standing EDA-SWCNT electrodes for EDLSCs are effective as electrodes and improve the properties of EDLSCs in comparison to binder-free COOH-SWCNT electrodes.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (35 results)

All 2014 2013 2012 2011 Other

All Journal Article (11 results) (of which Peer Reviewed: 9 results) Presentation (20 results) (of which Invited: 2 results) Remarks (4 results)

  • [Journal Article] Structure-property relationships in thermally-annealed multi-walled carbon nanotubes2014

    • Author(s)
      G. Yamamoto, K. Shirasu, Y. Nozaka, Y. Sato, T. Takagi, T. Hashida
    • Journal Title

      Carbon

      Volume: Vol.66 Pages: 219-226

    • DOI

      10.1016/j.carbon.2013.08.061

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural and Electrochemical Characterization of Ethylenediaminated Single-Walled Carbon Nanotubes Prepared from Fluorinated SWCNTs2014

    • Author(s)
      Kohei Bushimata, Shin-ichi Ogino, Kazutaka Hirano, Tatsuhiro Yabune, Kenta Sato, Takashi Itoh, Kenichi Motomiya, Koji Yokoyama, Daiki Mabuchi, Hikaru Nishizaka, Go Yamamoto, Toshiyuki Hashida, Kazuyuki Tohji, Yoshinori Sato
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: accepted

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ラット軟組織内における親水基修飾多層カーボンナノチューブの長期間生体持続性の評価2013

    • Author(s)
      佐藤義倫
    • Journal Title

      東北大学大学院環境科学研究科ニュースレター

      Volume: 15, 6(pdf,依頼論文)

    • URL

      http://www.kankyo.tohoku.ac.jp/newsletter/gses-news_no15

    • Related Report
      2013 Final Research Report
  • [Journal Article] Long-term biopersistence of tangled oxidized carbon nanotubes inside and outside macrophages in rat subcutaneous tissue2013

    • Author(s)
      Y. Sato, A. Yokoyama, Y. Nodasaka, T. Kohgo, K. Motomiya, H. Matsumoto, E. Nakazawa, T. Numata, M. Zhang, M. Yudasaka, H. Hara, R. Araki, O. Tsukamoto, H. Saito, T. Kamino, F. Watari, K. Tohji
    • Journal Title

      Scientific Reports

      Volume: 3 Issue: 1 Pages: 1-9

    • DOI

      10.1038/srep02516

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Helicity Selective Photoreaction of Single-walled Carbon Nanotubes with Organosulfur Compounds in the Presence of Oxygen2013

    • Author(s)
      Maeda, Y.; Higo, J.; Amagai, Y.; Matsui, J.; Ohkubo, K.; Yoshigoe, Y.; Hashimoto, M.; Eguchi, K.; Yamada, M.; Hasegawa, T.; Sato, Y.; Zhou, J.; Lu, J.; Miyashita, T.; Fukuzumi, S.; Murakami, T.; Tohji, K.; Nagase, S; Akasaka, T.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 16 Pages: 6356-6362

    • DOI

      10.1021/ja402199n

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aryl Iodides as Strong Inhibitor for Gold and Gold-Based Bimetallic quasi-Homogeneous Catalysis2013

    • Author(s)
      R. N. Dhital, C. Kamonsatikul, E. Somsook, Y. Sato, H. Sakurai
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 25 Pages: 2542-2544

    • DOI

      10.1039/c3cc39019e

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of the structure of the nanotube on the mechanicalproperties of binder-free multi-walled carbon nanotube solids2012

    • Author(s)
      Y.Sato, H.Nishizaka, S.Sawano, A.Yoshinaka, K.Hirano, S.Hashiguchi, T.Arie, S.Akita, G.Yamamoto, T.Hashida, H.Kimura, K.Motomiya, K.Tohji
    • Journal Title

      Carbon

      Volume: 50 Issue: 1 Pages: 34-39

    • DOI

      10.1016/j.carbon.2011.07.047

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] カーボンナノチューブ固化体の高機能高強度特性2011

    • Author(s)
      佐藤義倫
    • Journal Title

      セラミックスデータブック2011

      Volume: 39(依頼論文)(ISBN4-905959-93-X)

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] Chemical Speciation Analysis for Amorphous Boron and Precipitated Boron Carbide in Sintered Boron-Added Carbon Nanotubes2011

    • Author(s)
      石黒三岐雄,佐藤義倫,田路和幸,我妻和明
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 60 Issue: 10 Pages: 807-811

    • DOI

      10.2116/bunsekikagaku.60.807

    • NAID

      10029482363

    • ISSN
      0525-1931
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boron-Assisted Transformation to Rod-Like Graphitic Carbons from Multi-Walled Carbon Nanotubes in Boron-Mixed Multi-Walled Carbon Nanotube Solids2011

    • Author(s)
      Yoshinori Sato, Hikaru Nishizaka, Kenichi Motomiya, Go Yamamoto, Akira Okubo, Hisamichi Kimura, Mikio Ishikuro, Kazuaki Wagatsuma, Toshiyuki Hashida, Kazuyuki Tohji
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 3巻 Issue: 7 Pages: 2431-2439

    • DOI

      10.1021/am200335n

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and Electrochemical Characterization of Ethylenediaminated Single-Walled Carbon Nanotubes Prepared from Fluorinated SWCNTs

    • Author(s)
      K. Bushimata, S.–I. Ogino, K. Hirano, T. Yabune, K. Sato, T. Itoh, K. Motomiya, K. Yokoyama, D. Mabuchi, H. Nishizaka, G. Yamamoto, T. Hashida, K. Tohji, Y. Sato
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: (Accepted)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] フッ素化カーボンナノチューブを用いた機能材料開発2014

    • Author(s)
      佐藤義倫
    • Organizer
      日本材料学会ナノ材料部門委員会 2013年度 第2回講演会
    • Place of Presentation
      京都府、京都市
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] In vivo long-term biopersistence of tangled oxidized multi-walled carbon nanotubes inside and outside macrophages in rat subcutaneous tissue2013

    • Author(s)
      Y. Sato, A. Yokoyama, K. Motomiya, H. Matsumoto, E. Nakagawa, T. Kamino, T. Numata, M. Yudasaka, K. Tohji
    • Organizer
      3rd Nano Today Conference
    • Place of Presentation
      Republic of Singapore, Singapore(Poster)
    • Year and Date
      2013-12-11
    • Related Report
      2013 Final Research Report
  • [Presentation] Tensile Strength of Individual Multi-Walled Carbon Nanotube Constituting MWCNT Fiber2013

    • Author(s)
      H. Suzuki, Y. Sato, G. Yamamoto, K. Motomiya, T. Hashida, K. Tohji
    • Organizer
      3rd Nano Today Conference
    • Place of Presentation
      Republic of Singapore, Singapore(Poster)
    • Year and Date
      2013-12-09
    • Related Report
      2013 Final Research Report
  • [Presentation] Properties of electric double layer capacitors using aminated single-walled carbon nanotube electrode2013

    • Author(s)
      K. Bushimata, Y. Sato, K. Hirano, T. Yabune, T. Itoh, K. Motomiya, H. Ishida, K. Tohji
    • Organizer
      2013 MRS Fall Meetings
    • Place of Presentation
      USA, Boston(Poster)
    • Year and Date
      2013-12-04
    • Related Report
      2013 Final Research Report
  • [Presentation] 長期間によるラット軟組織内のマクロファージ内外に存在する酸素含有官能基修飾多層カーボンナノチューブの生体持続性2013

    • Author(s)
      佐藤義倫,横山敦郎,中澤英子,沼田朋子,湯田坂雅子,本宮憲一,田路和幸
    • Organizer
      公益社団法人日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      長野県,長野市(Oral)
    • Year and Date
      2013-09-05
    • Related Report
      2013 Final Research Report
  • [Presentation] フッ素化カーボンナノチューブを用いた機能材料開発2013

    • Author(s)
      佐藤義倫
    • Organizer
      日本材料学会ナノ材料部門委員会2013年度第2回講演会
    • Place of Presentation
      京都府,京都市(Oral; Invited talk)
    • Year and Date
      2013-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] 長期間による胸部軟組織に埋入された親水性多層カーボンナノチューブの構造評価2013

    • Author(s)
      佐藤義倫
    • Organizer
      ライフサイエンス分野シンポジウムバイオマテリアルの新展開
    • Place of Presentation
      愛知県,名古屋市愛知県,名古屋市
    • Year and Date
      2013-01-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Properties of electric double layer capacitors using aminated single-walled carbon nanotube electrodes2013

    • Author(s)
      Kohei Bushimata, Yoshinori Sato, Kazutaka Hirano, Tatsuhiro Yabune, Takashi Itoh, Kenichi Motomiya, Hideki Ishida, Kazuyuki Tohji
    • Organizer
      2013 MRS Fall Meetings
    • Place of Presentation
      United States of America, Boston
    • Related Report
      2013 Annual Research Report
  • [Presentation] Tensile Strength of Individual Multi-Walled Carbon Nanotube Constituting MWCNT Fiber2013

    • Author(s)
      Hideaki Suzuki, Yoshinori Sato, Go Yamamoto, Kenichi Motomiya, Toshiyuki Hashida and Kazuyuki Tohji
    • Organizer
      3rd Nano Today Conference
    • Place of Presentation
      Republic of Singapore, Singapore
    • Related Report
      2013 Annual Research Report
  • [Presentation] In vivo long-term biopersistence of tangled oxidized multi-walled carbon nanotubes inside and outside macrophages in rat subcutaneous tissue2013

    • Author(s)
      Yoshinori Sato, Atsuro Yokoyama, Kenichi Motomiya, Hiroaki Matsumoto, Eiko Nakagawa, Takeo Kamino, Tomoko Numata, Masako Yudasaka, Kazuyuki Tohji
    • Organizer
      3rd Nano Today Conference
    • Place of Presentation
      Republic of Singapore, Singapore
    • Related Report
      2013 Annual Research Report
  • [Presentation] 長期間によるラット軟組織内のマクロファージ内外に存在する酸素含有官能基修飾多層カーボンナノチューブの生体持続性2013

    • Author(s)
      佐藤義倫、横山敦郎、中澤英子、沼田朋子、湯田坂雅子、本宮憲一、田路和幸
    • Organizer
      公益社団法人日本セラミックス協会 第26回秋季シンポジウム
    • Place of Presentation
      長野県、長野市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structural characterization of oxidized multi-walled carbon nanotubes in and outside of the macrophage of the rat subcutaneous tissue over 2 years in vivo2012

    • Author(s)
      Y. Sato, A. Yokoyama, K. Motomiya, E. Nakagawa, T. Numata, M. Yudasaka, K. Tohji
    • Organizer
      small sciences symposium : Frontiers in Nanomedicine
    • Place of Presentation
      Republic of Singapore, Singapore(Poster)
    • Year and Date
      2012-12-12
    • Related Report
      2013 Final Research Report
  • [Presentation] 長期間による胸部軟組織に埋入された親水性多層カーボンナノチューブの構造評価2012

    • Author(s)
      佐藤義倫,横山敦郎,中澤英子, Zhang Minfang,湯田坂雅子,本宮憲一,田路和幸
    • Organizer
      第39回炭素材料学会年会
    • Place of Presentation
      長野県,長野市(Oral)
    • Year and Date
      2012-11-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 長期間による胸部軟組織のマクロファージ内での化学修飾多層カーボンナノチューブの構造変形2012

    • Author(s)
      佐藤義倫,横山敦郎,中澤英子, Zhang Minfang,湯田坂雅子,本宮憲一,田路和幸
    • Organizer
      第43回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      宮城県,仙台市(Poster)
    • Year and Date
      2012-09-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Are functionalized multi-walled carbon nanotubes biodegraded within the living body?2012

    • Author(s)
      Y. Sato, A. Yokoyama, E. Nakagawa, T. Kamino, M. Zhang, M. Yudasaka, K. Motomiya, K. Tohji
    • Organizer
      NT12: 13th International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Australia, Brisbane(Poster)
    • Year and Date
      2012-06-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Are functionalized multi-walled carbon nanotubes biodegraded within the living body?

    • Author(s)
      Yoshinori Sato, Atsuro Yokoyama, Eiko Nakagawa, Takeo Kamino, Minfang Zhang, Masako Yudasaka, Kenichi Motomiya, Kazuyuki Tohji
    • Organizer
      NT12: 13th International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Brisbane、Australia
    • Related Report
      2012 Annual Research Report
  • [Presentation] 長期間による胸部軟組織のマクロファージ内での化学修飾多層カーボンナノチューブの構造変形

    • Author(s)
      佐藤義倫、横山敦郎、中澤英子、Zhang Minfang、湯田坂雅子、本宮憲一、田路和幸
    • Organizer
      第43回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      仙台市、宮城県
    • Related Report
      2012 Annual Research Report
  • [Presentation] 長期間による胸部軟組織に埋入された親水性多層カーボンナノチューブの構造評価

    • Author(s)
      佐藤義倫、横山敦郎、中澤英子、Zhang Minfang、湯田坂雅子、本宮憲一、田路和幸
    • Organizer
      第39回炭素材料学会年会
    • Place of Presentation
      長野市、長野県
    • Related Report
      2012 Annual Research Report
  • [Presentation] Structural characterization of oxidized multi-walled carbon nanotubes in and outside of the macrophage of the rat subcutaneous tissue over 2 years in vivo

    • Author(s)
      Yoshinori Sato, Atsuro Yokoyama, Kenichi Motomiya, Eiko Nakagawa, Tomoko Numata, Masako Yudasaka, Kazuyuki Tohji
    • Organizer
      small sciences symposium: Frontiers in Nanomedicine
    • Place of Presentation
      Mandarin Orchard Hotel、Orchard Road、Singapore
    • Related Report
      2012 Annual Research Report
  • [Presentation] 長期間による胸部軟組織に埋入された親水性多層カーボンナノチューブの構造評価

    • Author(s)
      佐藤 義倫
    • Organizer
      ライフサイエンス分野シンポジウム バイオマテリアルの新展開
    • Place of Presentation
      名古屋市、愛知県
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Remarks] ラット軟組織内における多層カーボンナノチューブの長期間生体持続性を評価(東北大学)

    • URL

      http://www.tohoku.ac.jp/japanese/2013/09/press20130902-01.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 東北大、生体内に移植したCNTが長期安定することをラットで実証(日刊工業新聞)

    • URL

      http://www.nikkan.co.jp/news/nkx0720130905eaah.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 東北大など、ラット軟組織内における多層カーボンナノチューブの長期間生体持続性を評価(日本経済新聞)

    • URL

      http://release.nikkei.co.jp/detail.cfm?relID=344526&lindID=5

    • Related Report
      2013 Annual Research Report
  • [Remarks] "small sciences symposium"でのポスター賞受

    • URL

      http://ncsimd.kankyo.tohoku.ac.jp/

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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