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Improvement of strength and conductivity for Cu-Ti alloys aged in a hydrogen atmosphere

Research Project

Project/Area Number 23686104
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Material processing/treatments
Research InstitutionTohoku University

Principal Investigator

SEMBOSHI Satoshi  東北大学, 金属材料研究所, 准教授 (00364026)

Co-Investigator(Renkei-kenkyūsha) SATO Shigeo  東北大学, 金属材料研究所, 准教授 (40509056)
Project Period (FY) 2011-11-18 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2012: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords組織制御 / 銅合金 / 水素 / 相変態 / 時効析出 / 力学特性 / 電気伝導性 / 構造評価 / 導電率 / 強度 / 透過型電子顕微鏡 / X線回折 / 導電性材料 / 抽出分離 / 状態図
Research Abstract

We attempted to prepare Cu-Ti based alloys with a high strength and a high electrical conductivity by hydrogenation procedures. The electrical conductivity of Cu-Ti alloys was significantly improved without degradation of the mechanical properties by aging in a hydrogen atmosphere. The strengthening was primarily due to fine dispersion of needle-shaped Cu4Ti precipitates, which was similar with the case of conventional aging in vacuum. The enhancement of the conductivity was due to a reduction of a concentration of solute Ti in the matrix phase, which was caused by co-precipitation of Cu4Ti and TiH2. The balance of the strength and conductivity was improved by aging under a higher hydrogen pressure at a low temperature. Prior-deformation before aging was also useful to improve the properties. Eventually, we demonstrated that optimizing the thermomechanical process conditions imparted an excellent balance of strength and conductivity, of more than 950 MPa and 25% IACS, respectively.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (48 results)

All 2014 2013 2012 2011 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (20 results) (of which Invited: 4 results) Remarks (6 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Investigation of precipitation behavior in age-hardenable Cu-Ti alloys by an extraction-based approach2014

    • Author(s)
      S. Semboshi, M. Ishikuro, S. Sato, K. Wagatsuma, A. Iwase, and T. Takasugi
    • Journal Title

      Metallurgical and Materials Transactions A

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of dislocations on spinodal decomposition, precipitation, and age-hardening of Cu–Ti alloy2014

    • Author(s)
      S. Sato, A. Hasegawa, S. Semboshi, and K. Wagatsuma
    • Journal Title

      High Temperature Materials and Processes

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of high-strength and high-conductivity Cu-Ti alloy wire by aging in a hydrogen atmosphere2013

    • Author(s)
      S. Semboshi and T. Takasugi
    • Journal Title

      Journal of Alloys and Compounds

      Volume: Vol. 580

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Extraction of precipitates from age-hardenable Cu-Ti alloy2013

    • Author(s)
      S. Semboshi, M. Ishikuro, S. Sato, K. Wagatsuma, and T. Takasugi
    • Journal Title

      Materials Characterization

      Volume: Vol.82 (8) Pages: 23-31

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 抽出分離法を利用したCu-Ti合金中時効析出物の定量的評価2013

    • Author(s)
      千星聡,石黒三岐雄,佐藤成男,我妻和明,高杉隆幸,高維林,菅原章
    • Journal Title

      銅と銅合金

      Volume: Vo1. 52 Pages: 30-35

    • NAID

      40019779725

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of titanium hydride in dilute Cu-Ti alloy by aging in hydrogen atmosphere and its effects on electrical and mechanical properties2013

    • Author(s)
      S. Semboshi, S. Yamauchi, and H. Numakura
    • Journal Title

      Materials Transaction

      Volume: Vol. 54 Pages: 520-527

    • NAID

      10030953911

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid state bonding of alloy designed Cu-Zn brass and steel associated with phase transformation by spark plasma sintering2013

    • Author(s)
      N. Masahashi, S. Semboshi, K. Watanebe, Y. Higuchi, H. Yamagata, and Y. Ishizaki
    • Journal Title

      Journal of Materials Science

      Volume: 48 Pages: 5801-5809

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of high-strength and high-conductivity Cu-Ti alloy wire by aging in a hydrogen atmosphere2013

    • Author(s)
      S. Semboshi and T. Takasugi:
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 580

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 抽出分離法を利用したCu-Ti合金中時効析出物の定量的評価2013

    • Author(s)
      千星 聡, 石黒 三岐雄, 佐藤 成男, 我妻 和明, 高杉 隆幸, 高 維林, 菅原 章
    • Journal Title

      銅と銅合金

      Volume: 52 Pages: 30-35

    • NAID

      40019779725

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of energetic heavy ion on hardness of Al-Mg-Si alloys2013

    • Author(s)
      D. Ueyama, Y. Saitoh, F. Hori, Y. Kaneno, K. Nishida, K. Dohi, N. Soneda, S. Semboshi, and A. Iwase
    • Journal Title

      Nuclear Instruments and Methods in Physics Research, Section B

      Volume: 314 Pages: 107-111

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 水素中時効によるCu-Ti希薄合金中のチタン水素化物の生成とその電気的・力学的特性への影響2012

    • Author(s)
      千星聡,山内智史,沼倉宏
    • Journal Title

      日本金属学会誌

      Volume: Vol. 76 Pages: 496-503

    • NAID

      10030953911

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thin hydroxyapatite coating on titanium fabricated by a chemical coating process using calcium-phosphate slurry2012

    • Author(s)
      N. Ohtsu, Y. Nakamura, S. Semboshi
    • Journal Title

      Surface and Coatings Technology

      Volume: Vol. 206 Pages: 2616-2621

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 水素中時効によるCu-Ti希薄合金中のチタン水素化物の生成とその電気的・力学的特性への影響2012

    • Author(s)
      千星 聡
    • Journal Title

      日本金属学会誌

      Volume: 76 Pages: 496-503

    • NAID

      10030953911

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aging of Copper-Titanium dilute alloys in hydrogen atmosphere : Influence of prior-deformation on strength and electrical conductivity2011

    • Author(s)
      S. Semboshi, S. Orimo, H. Suda, W.L. Gao and A. Sigawara
    • Journal Title

      Materials Transaction

      Volume: Vol. 52 Pages: 2137-2142

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of aging temperature on electrical conductivity and hardness of Cu-3 at.% Ti alloy aged in a hydrogen atmosphere2011

    • Author(s)
      S. Semboshi, T. Nishida, H. Numakura, T. Al-Kassaab and R. Kirchheim
    • Journal Title

      Metallurgical Materials Transaction A

      Volume: Vol. 42A Pages: 2136-2143

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aging of Cu-3 at.% Ti Alloys in Hydrogen Atmosphere : Influence of Hydrogen Pressure on Strength and Electrical Conductivity2011

    • Author(s)
      S. Semboshi, T. Nishida and H. Numakura
    • Journal Title

      Materials Transaction

      Volume: Vol. 52 Pages: 605-609

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 水素中で時効したCu-4.2 at.% Ti合金の強度、導電性に及ぼす予ひずみの効果2011

    • Author(s)
      千星聡,折茂慎一,須田久,鈴木基彦,高維林,菅原章
    • Journal Title

      銅と銅合金

      Volume: Vo1. 50 Pages: 185-189

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aging of Copper-Titanium dilute alloys in hydrogen atmosphere: Influence of prior-deformation on strength and electrical conductivity2011

    • Author(s)
      S. Semboshi, S. Orimo, H. Suda, W.L. Gao and A. Sigawara
    • Journal Title

      Materials Transaction

      Volume: 52 Pages: 2137-2142

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aging of Cu-3 at.% Ti Alloys in Hydrogen Atmosphere: Influence of Hydrogen Pressure on Strength and Electrical Conductivity2011

    • Author(s)
      S. Semboshi, T. Nishida and H. Numakura
    • Journal Title

      Materials Transaction

      Volume: 52 Pages: 605-609

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 水素中で時効したCu-4.2 at.% Ti 合金の強度、導電性に及ぼす予ひずみの効果2011

    • Author(s)
      千星聡, 折茂慎一, 須田久, 鈴木基彦, 高維林, 菅原章
    • Journal Title

      銅と銅合金

      Volume: 50 Pages: 185-189

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] プラズマ窒化によるCu-Ti希薄合金の表面改質2014

    • Author(s)
      千星聡、岩瀬彰宏、大津直史、辻宣佳
    • Organizer
      日本金属学会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2014-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] Evaluation of precipitates behavior in age-hardenable Cu-Ti alloys using extraction procedure2013

    • Author(s)
      S. Semboshi, M. Ishikuro, S. Sato, K. Wagatsuma, A. Iwase, W.L. Gao and A. Sugawara
    • Organizer
      THERMEC'2013 (International Conference on Processing and Manufacturing of Advanced Materials)
    • Place of Presentation
      Las Vegas, USA
    • Year and Date
      2013-12-05
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Cu-Ti-N合金の時効析出挙動2013

    • Author(s)
      池田潤、千星聡、岩瀬彰宏、高維林、菅原章
    • Organizer
      日本銅学会
    • Place of Presentation
      関西大学
    • Year and Date
      2013-11-17
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 時効析出型Cu-Ti合金における時効熱処理にともなうミクロ構造因子変化2013

    • Author(s)
      佐藤成男、長谷川啓史、千星聡、我妻和明
    • Organizer
      日本銅学会
    • Place of Presentation
      関西大学
    • Year and Date
      2013-11-17
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Cu-Ti希薄合金における時効析出物の抽出分離による解析2013

    • Author(s)
      千星聡、石黒三岐雄、佐藤成男、我妻和明、高杉隆幸
    • Organizer
      日本金属学会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2013-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Cu-Ti希薄合金における時効析出物の抽出分離による解析2013

    • Author(s)
      千星聡、石黒三岐雄、佐藤成男、我妻和明、高杉隆幸
    • Organizer
      日本金属学会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Improvement of mechanical and electrical properties for age-hardenable Cu-Ti dilute alloys by hydrogenation process2012

    • Author(s)
      S. Semboshi and T. Takasugi
    • Organizer
      2012 MRS fall meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2012-11-29
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] Fabrication of high-strength and high-conductivity Cu-Ti alloy wire by aging in a hydrogen atmosphere2012

    • Author(s)
      S. Semboshi and T. Takasugi
    • Organizer
      MH2012 (International Symposium on Metal-Hydrogen Systems 2012)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2012-10-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 時効析出型Cu-Ti合金中析出物の抽出分離2012

    • Author(s)
      千星聡、石黒三岐雄、佐藤成男、我妻和明、高杉隆幸
    • Organizer
      日本金属学会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] 線引加工-水素中時効したチタン銅合金線材の強度および導電性2012

    • Author(s)
      千星聡、折茂慎一
    • Organizer
      日本金属学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2012-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Fabrication of high-strength and high-conductivity Cu-Ti alloy wire by aging in a hydrogen atmosphere2012

    • Author(s)
      S. Semboshi and T. Takasugi
    • Organizer
      MH2012 (International Symposium on Metal-Hydrogen Systems 2012)
    • Place of Presentation
      京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] 抽出分離法を利用したCu-Ti合金中時効析出物の構造・組成解析2012

    • Author(s)
      千星聡、石黒三岐雄、佐藤成男、我妻和明、高維林、菅原章
    • Organizer
      日本銅学会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 時効析出型Cu-Ti合金中析出物の抽出分離2012

    • Author(s)
      千星聡、石黒三岐雄、佐藤成男、我妻和明、高杉隆幸
    • Organizer
      日本金属学会
    • Place of Presentation
      松山市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Cu-Ti合金に生ずるスピノーダル分解と時効析出のX線散乱法を用いた解析2011

    • Author(s)
      長谷川啓史、佐藤成男、高橋洋平、千星聡、我妻和明
    • Organizer
      日本分析化学会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Microstructure, strength and electrical conductivity of Cu-Ti alloys heavily cold-rolled and aged in a hydrogen atmosphere2011

    • Author(s)
      S. Semboshi, H. Numakura, H. Suda, W.L. Gao and A. Sugawara
    • Organizer
      THERMEC'2011 (International Conference on Processing and Manufacturing of Advanced Materials)
    • Place of Presentation
      Quebec, Canada
    • Year and Date
      2011-08-01
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Microstructure, strength and electrical conductivity of Cu-Ti alloys heavily cold-rolled and aged in a hydrogen atmosphere2011

    • Author(s)
      S. Semboshi, H. Numakura, H. Suda, W.L. Gao and A. Sugawara
    • Organizer
      THERMEC’2011
    • Place of Presentation
      Quebec, Canada
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] 水素中時効によるCu-Ti合金の強度-導電性バランスの制御2011

    • Author(s)
      千星聡、折茂慎一
    • Organizer
      材料における水素有効利用研究会
    • Place of Presentation
      屋久島
    • Related Report
      2011 Annual Research Report
  • [Presentation] Evaluation of precipitates behavior in age-hardenable Cu-Ti alloys using extraction procedure

    • Author(s)
      S. Semboshi, M. Ishikuro, S. Sato, K. Wagatsuma, A. Iwase, W.L. Gao and A. Sugawara
    • Organizer
      PRICM 7 (The 7th Pacific Rim International Conference on Advanced Materials and Processing)
    • Place of Presentation
      LasVegas, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] プラズマ窒化によるCu-Ti希薄合金の表面改質

    • Author(s)
      千星聡、岩瀬彰宏、大津直史、辻宣佳
    • Organizer
      日本金属学
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 微量窒素添加したCu-Ti合金の時効による特性と組織の変化

    • Author(s)
      池田潤、千星聡、岩瀬彰宏
    • Organizer
      日本金属学
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Remarks] □メゾスコピック組織制御分野

    • URL

      http://www.mesoscopic.imr.tohoku.ac.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] □東北大学金属材料研究所関西センター

    • URL

      http://www.kansaicenter.imr.tohoku.ac.jp/index.html

    • Related Report
      2013 Final Research Report
  • [Remarks] メゾスコピック組織制御分野

    • URL

      http://www.mesoscopic.imr.tohoku.ac.jp/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 東北大学金属材料研究所関西センター

    • URL

      http://www.kansaicenter.imr.tohoku.ac.jp/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 東北大学金属材料研究所 関西センター

    • URL

      http://www.kansaicenter.imr.tohoku.ac.jp/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 関西センター メゾスコピック組織性工学分野

    • URL

      http://www.mesoscopic.imr.tohoku.ac.jp/

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] Cu-Ti系合金および製造方法2013

    • Inventor(s)
      千星 聡
    • Industrial Property Rights Holder
      DOWAメタルテック
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-189885
    • Filing Date
      2013-09-12
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] Cu-Ti系合金および製造方法2013

    • Inventor(s)
      千星聡
    • Industrial Property Rights Holder
      千星聡
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-189885
    • Filing Date
      2013-09-12
    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-15   Modified: 2019-07-29  

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