Measurements of the biogenic volatile organic compounds by the new analysis method for the atmospheric trace species

• Project/Area Number: 23710015
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Environmental dynamic analysis
• Research Institution: Tokyo University of Agriculture and Technology (2012-2013); Tokyo Metropolitan University (2011)
• Principal Investigator: NAKASHIMA Yoshihiro 東京農工大学, (連合)農学研究科(研究院), 助教 (20419873)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
• Keywords: 揮発性有機化合物 / 植物 / 微量成分分析 / 環境影響

Research Abstract

It has been thought that the trend of the increment of the photochemical oxidant is probably related to the existence of the unknown volatile organic compounds (VOCs). In the present studies, I focused the plants as the emission source of the unknown VCOs, and measured the biogenic VOCs by the total OH reactivity: the new analysis method for the atmospheric trace species.
As a results, I cannot confirmed the existence of unknown VOCs for the plants emits mainly isoprene. For the plants emits mainly monoterpenes, unfortunately I cannot try the OH reactivity measurements. But many kinds of monoterpenes are observed by the preliminary GC-FID measurements. This results implies the probability of the existence of the unknown species.

Research Products

• [Journal Article] A novel fast gas chromatography method for higher time resolution measurements of speciated monoterpenes in air (2014)
  • Author(s): C. E. Jones, S. Kato, Y. Nakashima, Y. Kajii
  • Journal Title: Atmospheric Measurement and Techniques Volume: 7 Issue: 1 Pages: 1-17
  • DOI: 10.5194/amt-7-1-2014
  • Peer Reviewed
• [Journal Article] Missing peroxy radical sources within a summertime ponderosa pine forest (2014)
  • Author(s): G. M. Wolfe, Y. Nakashima, Y. Kajii et al., (総員24名)
  • Journal Title: Atmospheric Chemistry and Physics Volume: 14 Issue: 9 Pages: 4715-4732
  • DOI: 10.5194/acp-14-4715-2014
  • Peer Reviewed
• [Journal Article] Total OH reactivity measurements in ambient air in a southern Rocky mountain ponderosa pine forest during BEACHON-SRM08 summer campaign (2014)
  • Author(s): Y. Nakashima, S. Kato, Y. Kajii et al., (総員10名)
  • Journal Title: Atmospheric Environment Volume: 85 Pages: 1-8
  • Peer Reviewed
• [Journal Article] 反応性比較法に基づくガスクロマトグラフィーやプロトン移動反応質量分析による大気中 OHラジカル反応性の測定 (2013)
  • Author(s): 加藤俊吾 ,中嶋吉弘 ,梶井克純
  • Journal Title: 分析化学 Volume: 62 Pages: 369-378
  • NAID: 10031159078
  • Peer Reviewed
• [Journal Article] A laser-flash photolysis and laser-induced fluorescence detection technique for measuring total HO2 reactivity in ambient air (2013)
  • Author(s): K. Miyazaki, Y. Nakashima, C. Schoemaecker, C. Fittschen, Y. Kajii
  • Journal Title: Review of Scientific Instruments Volume: 84
  • Peer Reviewed
• [Journal Article] Evaluation of HOx sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem (2013)
  • Author(s): S. Kim, Y. Nakashima, Y. Kajii et al., (総員23名)
  • Journal Title: Atmospheric Chemistry and Physics Volume: 13 Pages: 2031-2044
  • Peer Reviewed
• [Journal Article] 反応性比較法に基づくガスクロマトグラフィーやプロトン移動反応質量分析による大気中OHラジカル反応性の測定 (2013)
  • Author(s): 加藤俊吾, 中嶋吉弘, 梶井克純
  • Journal Title: 分析化学 Volume: 62 Pages: 369-378
  • NAID: 10031159078
  • Peer Reviewed
• [Journal Article] Total OH reactivity measurements in laboratory studies of the photooxidation of isoprene (2013)
  • Author(s): Y. Nakashima
  • Journal Title: Atmospheric Environment Volume: 62 Pages: 243-247
  • DOI: 10.1016/j.atmosenv.2012.08.033
  • Peer Reviewed
• [Journal Article] Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry (2012)
  • Author(s): J.P. Digangi
  • Journal Title: Atmospheric Chemistry and Physics Volume: 12 Issue: 20 Pages: 9529-9543
  • DOI: 10.5194/acp-12-9529-2012
  • Peer Reviewed
• [Journal Article] Comparison of N2O5 mixing ratios during NO3Comp 2007 in SAPHIR (2012)
  • Author(s): H. Fuchs, Y. Nakashima (他21名)
  • Journal Title: Atmospheric Measurements Techniques Volume: 5 Issue: 11 Pages: 2763-2777
  • DOI: 10.5194/amt-5-2763-2012
  • Peer Reviewed
• [Journal Article] 植物から放出されるVOCsの化学分析とOH反応性 (2012)
  • Author(s): 山崎昌平, 中嶋吉弘 (他4名)
  • Journal Title: 大気環境学会誌 Volume: 47 Pages: 9-17
  • Peer Reviewed
• [Journal Article] Air quality diagnosis from comprehensive observations of total OH reactivity and reactive trace species in urban central Tokyo (2012)
  • Author(s): Yoshino, A., Nakashima, Y., Miyazaki, K., Kato, S., Suthawaree, J., Shimo, N., Matsunaga, S., Chatani, S., Apel, E., Greenberg, J., Guenther, A., Ueno, H., Sasaki, H., Hoshi, J., Yokota, H., Ishii, K., Kajii, Y.
  • Journal Title: Atmos.Environ. Volume: 49 Pages: 51-59
  • DOI: 10.1016/j.atmosenv.2011.12.029
  • Peer Reviewed
• [Journal Article] First Direct measurements of formaldehyde flux (2011)
  • Author(s): J.P.DiGangi, Y. Nakashima (他18名)
  • Journal Title: Atmospheric Chemistry ans Physics Volume: 11 Issue: 20 Pages: 10565-10578
  • DOI: 10.5194/acp-11-10565-2011
  • Peer Reviewed
• [Journal Article] Near-Surface Vertical Profiles of Urban Roadside NOx and Fine Particles
  • Author(s): Y. Nakashima, C. Jones, W. Yamanobe, Y. Kajii
  • Journal Title: Aerosol and Air Quality Research Volume: (In press)
  • NAID: 120005712956
  • Peer Reviewed
• [Presentation] Total OH reactivity measurements within a suburban Tokyo forest in late summer 2012 during the AQUAS-TAMA campaign (2013)
  • Author(s): Y. Nakashima, C. Jones, S. Yamazaki, S. Kato, C. Minejima, A. Yoshino, S. Hatakeyama, K. Matsuda, Y. Kajii
  • Organizer: American Geophysical Union Fall Meeting 2013
  • Place of Presentation: San Francisco, US
  • Year and Date: 2013-12-10
• [Presentation] Development of an instrument for the measurements of NO3 and N2O5 by Broad Band Cavity Enhanced Absorption Spectroscopy (BBCEAS) (2013)
  • Author(s): Y. Nakashima, K. Arima, S. Hatakeyama, Y. Kajii
  • Organizer: Asia Oseania Geoscience Society Annual Meeting
  • Place of Presentation: Brisbane, Australia
  • Year and Date: 2013-06-25
• [Presentation] Total OH reactivity measurements within a suburban Tokyo forest in late summer 2012 during the AQUAS-TAMA campaign (2013)
  • Author(s): Y. Nakashima et al., (総員9名, 1番目)
  • Organizer: AGU (American Geophysical Union) Fall Meeting 2013
  • Place of Presentation: サンフランシスコ・米国
• [Presentation] Development of an instrument for the measurements of NO3 and N2O5 by Broad Band Cavity Enhanced Absorption Spectroscopy (BBCEAS) (2013)
  • Author(s): Y. Nakashima, K. Arima, S. Hatakeyama, Y. Kajii
  • Organizer: AOGS (Asia Oceania Geoscience Society) Annual Meeting 2013
  • Place of Presentation: ブリスベン・豪国
• [Presentation] Development of an instrument for the measurement of reaction coefficients of alkenes with O3 and NO3 by Broad band-cavity enhanced absorption spectroscopy (2012)
  • Author(s): Y. Nakashima, K. Arima, Y. Takahashi, Y. Kajii
  • Organizer: 28th Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: Fukuoka, Japan
  • Year and Date: 2012-06-07
• [Presentation] Development of an instrument for the measurement of reaction coefficients of alkenes with O3 and NO3 by Broad band-cavity enhanced absorption spectroscopy (2012)
  • Author(s): Y. Nakashima, K. Arima, Y. Takahashi, Y. Kajii
  • Organizer: 28th symposium on chamical kinetics and dynamics
  • Place of Presentation: 九州大学筑紫キャンパス
• [Presentation] ブロードバンドキャビティエンハンスド吸収分光法を用いた窒素酸化物測定装置の開発 (2012)
  • Author(s): 中嶋 吉弘, 有間 光, 梶井 克純
  • Organizer: 第53回大気環境学会年会
  • Place of Presentation: 神奈川大学横浜キャンパス
• [Presentation] ブロードバンドキャビティエンハンスド吸収分光法を用いたNO3/N2O5測定装置の開発 (2012)
  • Author(s): 中嶋 吉弘, 有間 光, 梶井 克純
  • Organizer: 第18回大気化学討論会
  • Place of Presentation: ホテルパーレンス小野屋
• [Presentation] Total OH reactivity measurements at Manitou Experimental Forest in summer season during BEACHON-ROCS field campaign (2011)
  • Author(s): Y. Nakashima, A. Ida, Y. Kajii, J. Greenberg, T. Karl, S. Kim, A. Turnipseed, A. Guenther, J. DiGangi, S. Henry, F. Keutsch, R. Schnitzhofer, L. Kaser, A. Hansel
  • Organizer: American Geophysical Union Fall Meeting 2011
  • Place of Presentation: San Francisco, US
  • Year and Date: 2011-12-09
• [Presentation] Total OH reactivity measurements at Manitou (2011)
  • Author(s): Y. Nakashima (他14名)
  • Organizer: AGU Fall Meeting 2011
  • Place of Presentation: Moscone Center(アメリカ)
• [Presentation] 夏季北米大陸の森林大気集中観測(BEACHON-ROCS)でのOH反応性測定 (2011)
  • Author(s): 中嶋吉弘 (他12名)
  • Organizer: 大気化学討論会
  • Place of Presentation: 京都大学宇治キャンパス(京都府)
• [Presentation] Development of an NO3 reactivity measurement (2011)
  • Author(s): Y. Nakashima (他2名)
  • Organizer: Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: Tokyo Institute of Technology(東京都)
• [Presentation] 夜間窒素酸化物消失量測定のためのNO3反応性測定装置の開発 (2011)
  • Author(s): 中嶋吉弘(他2名)
  • Organizer: 第52回大気環境学会
  • Place of Presentation: 長崎大学(長崎県)