Development of novel host molecule-metal ion complexes having enzyme-like catalytic activities for the highly efficient removal and degradation of toxic compounds
| Project/Area Number |
23710090
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Environmental technology/Environmental materials
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | チアカリックスアレーン / 複核金属錯体 / 金属ナノ粒子 / アルキルアンモニウム塩 / アドミセル / 加水分解 / 還元的脱塩素化 / 起泡分離 / 環境汚染物質 / 捕集 / 反応促進 / セリウム(IV) / イオン液体 / ヘテロポリ酸 |
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| Research Abstract |
The present study was conducted with a view to developing highly efficient environ mental purification systems by which the removal and subsequent detoxification of hazardous chemicals can be achieved with novel host molecule metal ion complexes having enzyme-like activities. Taking fenitrothion and perchloroethylene as examples of hazardous chemicals, hybrid materials were prepared for their removal from water followed by their degradation. As an extension of the present study, quaternary ammonium salts having chemical structures similar to those of surfactants of importance in the above-mentioned hybrid materials were applied as reaction media to hydrolyze cellulose, which is a key step in processing plant-origin biomasses, and to convert the hydrolysis products into a platform chemical of valuable materials.
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Report
(4 results)
Research Products
(18 results)
