• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of novel host molecule-metal ion complexes having enzyme-like catalytic activities for the highly efficient removal and degradation of toxic compounds

Research Project

Project/Area Number 23710090
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental technology/Environmental materials
Research InstitutionNagoya University

Principal Investigator

MATSUMIYA Hiroaki  名古屋大学, エコトピア科学研究所, 准教授 (10362287)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsチアカリックスアレーン / 複核金属錯体 / 金属ナノ粒子 / アルキルアンモニウム塩 / アドミセル / 加水分解 / 還元的脱塩素化 / 起泡分離 / 環境汚染物質 / 捕集 / 反応促進 / セリウム(IV) / イオン液体 / ヘテロポリ酸
Research Abstract

The present study was conducted with a view to developing highly efficient environ mental purification systems by which the removal and subsequent detoxification of hazardous chemicals can be achieved with novel host molecule metal ion complexes having enzyme-like activities. Taking fenitrothion and perchloroethylene as examples of hazardous chemicals, hybrid materials were prepared for their removal from water followed by their degradation. As an extension of the present study, quaternary ammonium salts having chemical structures similar to those of surfactants of importance in the above-mentioned hybrid materials were applied as reaction media to hydrolyze cellulose, which is a key step in processing plant-origin biomasses, and to convert the hydrolysis products into a platform chemical of valuable materials.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (18 results)

All 2013 2012 2011

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (12 results)

  • [Journal Article] Collection of trace metals with cationic surfactant-silica particles followed by flotation with an anionic surfactant for seawater analysis2012

    • Author(s)
      H. Matsumiya, K. Kitakata, M. Hiraide
    • Journal Title

      Analytical and Bioanalytical Chemistry

      Volume: vol.402, no.5 Pages: 1973-1977

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ionic liquid-based extraction of heteropoly molybdic acids for the sensitive determination of Si, P, and As in high-purity iron2012

    • Author(s)
      H. Matsumiya, Y. Inagaki, M. Hiraide
    • Journal Title

      ISIJ International

      Volume: vol.52, no.1 Pages: 101-104

    • NAID

      10030746187

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 界面活性剤ミセル溶液中におけるセリウム(IV)-チアカリックス[4]アレーン錯体のリン酸エステルに対する加水分解触媒活性2012

    • Author(s)
      永井真二,松宮弘明,平出正孝
    • Journal Title

      分析化学

      Volume: vol.61, no.8 Pages: 723-726

    • NAID

      10030495395

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phosphoester Hydrolysis Catalyzed by a Dinuclear Cerium(IV)-Thiacalix[4]arene Complex in Micellar Solutions2012

    • Author(s)
      永井真二,松宮弘明,平出正孝
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 61 Issue: 8 Pages: 723-726

    • DOI

      10.2116/bunsekikagaku.61.723

    • NAID

      10030495395

    • ISSN
      0525-1931
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Collection of trace metals with cationic 文字数制限で以下略2012

    • Author(s)
      H. Matsumiya, K. Kitakata, M. Hiraide
    • Journal Title

      Analytical and Bioanalytical Chemistry

      Volume: 402 Issue: 5 Pages: 1973-1977

    • DOI

      10.1007/s00216-011-5608-9

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ionic Liquid-based Extraction of Heteropoly Molybdic Acids for the Sensitive Determination of Si, P, and As in High-purity Iron2012

    • Author(s)
      H. Matsumiya, Y. Inagaki, M. Hiraide
    • Journal Title

      ISIJ International

      Volume: 52 Issue: 1 Pages: 101-104

    • DOI

      10.2355/isijinternational.52.101

    • NAID

      10030746187

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 水中テトラクロロエチレンの迅速捕集とその場分解を指向する Fe/Ni担持アドミセルの調製2013

    • Author(s)
      赤星祐樹,近藤傑,松宮弘明
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市)
    • Related Report
      2013 Final Research Report
  • [Presentation] 水中テトラクロロエチレンの迅速捕集とその場分解を指向するFe/Ni担持アドミセルの調製2013

    • Author(s)
      赤星祐樹,近藤傑,松宮弘明
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋)
    • Related Report
      2013 Annual Research Report
  • [Presentation] チアカリックスアレーン錯体を利用するイムノアッセイ用標識の設計2012

    • Author(s)
      松宮弘明,福島浩之,平出正孝
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス(石川県金沢市)
    • Related Report
      2013 Final Research Report
  • [Presentation] アドミセルによる水中有機リン系農薬フェニトロチオンの濃縮および加水分解と簡易定量2012

    • Author(s)
      松宮弘明,彦坂博之,平出正孝
    • Place of Presentation
      金沢大学角間キャンパス(石川県金沢市)
    • Related Report
      2013 Final Research Report
  • [Presentation] 環境水中の医療用ガドリニウム錯体の存在形態別分析2012

    • Author(s)
      井上博人,松宮弘明,平出正孝
    • Organizer
      第31回溶媒抽出討論会
    • Place of Presentation
      石川県文教会館(石川県金沢市)
    • Related Report
      2013 Final Research Report
  • [Presentation] チアカリックスアレーン錯体を利用するイムノアッセイ用標識の設計2012

    • Author(s)
      松宮弘明,福島浩之,平出正孝
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス(金沢)
    • Related Report
      2012 Research-status Report
  • [Presentation] アドミセルによる水中有機リン系農薬フェニトロチオンの濃縮および加水分解と簡易定量2012

    • Author(s)
      松宮弘明,彦坂博之,平出正孝
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス(金沢)
    • Related Report
      2012 Research-status Report
  • [Presentation] 環境水中の医療用ガドリニウム錯体の存在形態別分析2012

    • Author(s)
      井上博人,松宮弘明,平出正孝
    • Organizer
      第31回溶媒抽出討論会
    • Place of Presentation
      石川県文教会館(金沢)
    • Related Report
      2012 Research-status Report
  • [Presentation] イオン液体を用いるヘテロポリ酸の抽出と高純度鉄分析への応用2011

    • Author(s)
      松宮弘明,稲垣育亮,平出正孝
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市)
    • Related Report
      2013 Final Research Report
  • [Presentation] Chemical speciation of clinically used Gd complexes in environmental water2011

    • Author(s)
      H. Matsumiya, H. Inoue, M. Hiraide
    • Organizer
      International Symposium on EcoTopia Science 2011
    • Place of Presentation
      Nagoya University (Nagoya, Japan)
    • Related Report
      2013 Final Research Report
  • [Presentation] イオン液体を用いるヘテロポリ酸の抽出と高純度鉄分析への応用2011

    • Author(s)
      松宮弘明,稲垣育亮,平出正孝
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋)
    • Related Report
      2011 Research-status Report
  • [Presentation] Chemical speciation of clinically used 文字数制限で以下略2011

    • Author(s)
      H. Matsumiya, H. Inoue, M. Hiraide
    • Organizer
      International Symposium on EcoTopia Science 2011
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋)
    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi