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Separation and Recovery of Rare-Earth Metals Using Molten Salt Electrolysis and Alloy Electrodes

Research Project

Project/Area Number 23710092
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental technology/Environmental materials
Research InstitutionOsaka University

Principal Investigator

KONISHI Hirokazu  大阪大学, 大学院・工学研究科, 助教 (60379120)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords溶融塩 / 希土類金属 / リサイクル技術 / 電気化学 / 分離 / 希土類元素 / リサイクル
Research Abstract

In order to investigate the probability of Tb separation from Nd and Pr, alloy samples were prepared by potentiostatic electrolysis at several potential for 1 h in LiCl-KCl eutectic melts added TbCl3, NdCl3 and PrCl3 at 723 K. From the results of ICP-AES analysis, the mass ratio of Tb/Nd and Tb/Pr in the alloy sample was found to be 56 and 41 at 0.70 V and 0.68-0.69 V, respectively. Furthermore, the mass ratio of Tb/(Nd+Pr) in the alloy sample was found to be 51 at 0.65 V.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (19 results)

All 2012 2011 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (10 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Separation of Dy and Nd (La)Using Molten Salt and an AlloyDiaphragm2012

    • Author(s)
      H. Konishi, H. Ono, T. Nohira and T.Oishi
    • Journal Title

      ECS Transactions

      Volume: 50(11) Pages: 463-472

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Formation of Tb-NiAlloys in a Molten LiCl-KCl-TbCl3System2012

    • Author(s)
      H. Konishi, K. Mizuma, H. Ono, E.Takeuchi, T. Nohira and T. Oishi
    • Journal Title

      ECS Transactions

      Volume: 50(11) Pages: 561-569

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Formation ofRE-Ni (RE=Pr, Nd, Dy) Alloys in MoltenHalides2012

    • Author(s)
      T. Nohira, S. Kobayashi, K. Kondo, K.Yasuda, R. Hagiwara, T. Oishi and H.Konishi
    • Journal Title

      ECS Transactions

      Volume: 50(11) Pages: 473-482

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Separation of Dy from ModelMagnet Scraps Using Molten SaltElectrochemical Process2012

    • Author(s)
      H. Konishi, H. Ono, T. Oishi and T.Nohira
    • Journal Title

      Journal ofJSEM (Journal of the Japanese Societyfor Experimental Mechanics)

      Volume: 12(Special issue) Pages: 243-248

    • NAID

      10031048129

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Separation of Dy and Nd (La) Using Molten Salt and an Alloy Diaphragm2012

    • Author(s)
      小西宏和
    • Journal Title

      ECS Transactions

      Volume: 50 Pages: 463-472

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Formation of Tb-Ni Alloys in a Molten LiCl-KCl-TbCl3 System2012

    • Author(s)
      小西宏和
    • Journal Title

      ECS Transactions

      Volume: 50 Pages: 561-569

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Separation of Dy from Model Magnet Scraps Using Molten Salt Electrochemical Process2012

    • Author(s)
      小西宏和
    • Journal Title

      Journal of JSEM

      Volume: 12 Pages: 243-248

    • NAID

      10031048129

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Separation of Dy from NdMagnet Scrap Using Molten Salt and AlloyDiaphragm2012

    • Author(s)
      H. Konishi, H. Ono, E. Takeuchi, T Oishiand T. Nohira
    • Organizer
      Fifth International Congresson the Science and Technology ofSteelmaking (ICS2012)
    • Place of Presentation
      Dresden, Germany.
    • Related Report
      2012 Final Research Report
  • [Presentation] Electrochemical Formation of RE Alloys (RE= Dy, Nd) in a Molten LiCl-KCl System andSeparation of Dy, Ninth InternationalConference on Molten Slags2012

    • Author(s)
      H. Konishi, H. Ono, T Oishi and T. Nohira
    • Organizer
      Fluxes andSalts (MOLTEN12)
    • Place of Presentation
      Beijing,China.
    • Related Report
      2012 Final Research Report
  • [Presentation] 溶融 LiCl-KCl 中における選択的 Dy 合金化とその Dy(III)濃度依存性2012

    • Author(s)
      小西宏和,岡田竜太朗,小野英樹,竹内栄一,大石哲雄,野平俊之
    • Organizer
      電気化学第79回大会
    • Place of Presentation
      浜松
    • Related Report
      2012 Final Research Report
  • [Presentation] Separation of Dy from Nd Magnet Scrap Using Molten Salt and Alloy Diaphragm2012

    • Author(s)
      小西宏和
    • Organizer
      The Fifth International Congress on the Science and Technology of Steelmaking (ICS2012)
    • Place of Presentation
      Dresden, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electrochemical Formation of RE Alloys (RE = Dy, Nd) in a Molten LiCl-KCl System and Separation of Dy2012

    • Author(s)
      小西宏和
    • Organizer
      Ninth International Conference on Molten Slags, Fluxes and Salts (MOLTEN12)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Annual Research Report
  • [Presentation] 溶融LiCl-KCl中における選択的Dy合金化とそのDy(III)濃度依存性2012

    • Author(s)
      小西宏和,岡田竜太朗,小野英樹,竹内栄一,大石哲雄,野平俊之
    • Organizer
      電気化学第79回大会
    • Place of Presentation
      アクトシティ浜松(静岡県)
    • Related Report
      2011 Research-status Report
  • [Presentation] 溶融塩電解と合金隔膜を用いた希土類金属の分離2011

    • Author(s)
      小西宏和, 小野英樹, 大石哲雄, 野平俊之
    • Organizer
      (社)日本金属学会 2011 秋季講演大会
    • Place of Presentation
      宜野湾.
    • Related Report
      2012 Final Research Report
  • [Presentation] 溶融塩電解と合金隔膜を用いた希土類金属の分離2011

    • Author(s)
      小西宏和,小野英樹,大石哲雄,野平俊之
    • Organizer
      (社)日本金属学会 2011秋季講演大会
    • Place of Presentation
      沖縄コンベンションセンター(沖縄県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Separation of Dy by Molten Salt Electrochemical Process2011

    • Author(s)
      小西宏和,小野英樹,大石哲雄,野平俊之
    • Organizer
      6th International Symposium on Advanced Fluid/Solid Science and Technology in Experimental Mechanics
    • Place of Presentation
      ホテル日航関西空港(大阪)
    • Related Report
      2011 Research-status Report
  • [Presentation] 溶融塩電解を用いた新規な希土類金属の分離・回収法2011

    • Author(s)
      小西宏和
    • Organizer
      (社)日本鉄鋼協会・(社)日本金属学会 平成23年度材料化学研究会・鉄鋼プロセス研究会 合同研究会 特別講演(招待講演)
    • Place of Presentation
      大阪大学(大阪)
    • Related Report
      2011 Research-status Report
  • [Book] リサイクル・廃棄物事典2012

    • Author(s)
      中村崇,小西宏和
    • Publisher
      (株)産業調査会 事典出版センター
    • Related Report
      2012 Final Research Report
  • [Remarks] 大阪大学 研究者総覧

    • URL

      http://www.dma.jim.osaka-u.ac.jp/view?l=ja&u=3738

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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