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Creation of novel environmentally-friendly synthetic technology of useful carboxylic acids from non-edible biomass

Research Project

Project/Area Number 23710094
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental technology/Environmental materials
Research InstitutionKumamoto University

Principal Investigator

SASAKI MITSURU  熊本大学, 学内共同利用施設等, 准教授 (40363519)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords非可食バイオマス / 水熱技術 / マイクロ波 / 水熱電解 / 5-HMF / 加水分解 / 部分酸化 / 有用化成品素材 / 国際情報交換 / 国際情報交流 / 多価カルボン酸 / セルロース / 環境軽負荷 / イオン液体 / 迅速加水分解
Research Abstract

I aimed to develop a new synthesis technology for producing chemicals from non-edible biomass. The hydrothermal microwave-assisted hydrolysis of marine biomass (Wakame), it was found that low molecular weight fucoidan having an antitumor activity was obtained at lower temperature and shorter treatment time than those at the conventional hydrothermal degradation treatment. Next, in the hydrothermal electrolysis of 5-HMF, which is one of the intermediate products in the biomass hydrothermal treatment, it was possible to obtain a high yield of formic acid and levulinic acid as hydrolysis products, but the production rate of furandicarboxylic acid was quite slow under these conditions. In future the development of novel synthesis technology for high and selective production of useful chemicals and fuels can be realized with hydrothermal-based atmosphere.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (26 results)

All 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 4 results) Presentation (14 results) Remarks (6 results)

  • [Journal Article] Comparation Glycerol Degradation by Microwave Heating and by Hydrothermal Treatment2013

    • Author(s)
      Lailatul Qadariyuah, Siti Machmudah, Armando T. Quitain, Mitsuru Sasaki
    • Journal Title

      Industri

      Volume: 10 Pages: 83-88

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microwave-Hydrothermal Extraction and Degradation of Fucoidan from Deoiled Undaria pinnatifida in Supercritical Carbon Dioxide2013

    • Author(s)
      Armando T. Quitain,Takahisa Kai, Mitsuru Sasaki, Motonobu Goto
    • Journal Title

      Industrial and Engineering Chemistry Research

      Volume: 52 Pages: 7940-7946

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrolysis of Alcohols in High Temperature-High Pressure Water2013

    • Author(s)
      Asli Yuksel, Mitsuru Sasaki, Motonobu Goto
    • Journal Title

      MRS Proceedings

      Volume: 1491

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microwave-Hydrothermal Extraction and Degradation of Fucoidan from Supercritical Carbon Dioxide Deoiled Undaria pinnatifida2013

    • Author(s)
      Armando T. Quitain, Takahisa Kai, Mitsuru Sasaki, Motonobu Goto
    • Journal Title

      Industrial and Engineering Chemistry Research

      Volume: 52 Issue: 23 Pages: 7940-7946

    • DOI

      10.1021/ie400527b

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Degradation and Hydrolysis of Cellulosic Materials for High Yield of Dicarboxylic acids from Cellulosic Biomass with Hydrothermal Electrolysis.2012

    • Author(s)
      Mitsuru Sasaki, Goushi Kouzaki, Armando T. Quitain, and Motonobu Goto
    • Journal Title

      Proceeding of the International Symposium on Supercritical Fluids 2012

      Volume: 1

    • Related Report
      2012 Research-status Report
  • [Journal Article] 水熱電解技術を利用したセルロース系バイオマスからの多価カルボン酸の生成2012

    • Author(s)
      佐々木 満
    • Journal Title

      Cellulose Communications

      Volume: 19 Pages: 22-25

    • NAID

      40019221107

    • Related Report
      2011 Research-status Report
  • [Presentation] Synergistic Effect of Coupling Pressurized CO and HO for Extraction 22 of Alkaloids from Sophora flavescens2013

    • Author(s)
      Ozturk Bulent, Armando T. Quitain, Mitsuru Sasaki, Motonobu Goto
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場,北九州
    • Year and Date
      2013-07-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Development of conversion technology to useful compounds from food processing residue under hydrothermal condition2013

    • Author(s)
      Matsubara Teruaki, Hideo Iwai, Masahiro Tanaka, Munehiro Hoshino, Armando T. Quitain, Mitsuru Sasaki
    • Organizer
      9 th World Congress on Chemical Engineering
    • Place of Presentation
      ソウル・韓国
    • Related Report
      2013 Final Research Report
  • [Presentation] Synergistic Effect of Coupling Pressurized CO2 and H2O for Extraction of Alkaloids from Sophora flavescens2013

    • Author(s)
      Ozturk Bulent, Armando T. Quitain, Mitsuru Sasaki, Motonobu Goto
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of conversion technology to useful compounds from food processing residue under hydrothermal condition2013

    • Author(s)
      Matsubara Teruaki, Hideo Iwai, Masahiro Tanaka, Munehiro Hoshino, Armando T. Quitain, Mitsuru Sasaki
    • Organizer
      9th World Congress of Chemical Engineering
    • Place of Presentation
      ソウル・韓国
    • Related Report
      2013 Annual Research Report
  • [Presentation] 各種バイオマスを原料とした迅速水熱糖化技術および糖の高付加価値物質への変換技術の開発2013

    • Author(s)
      佐々木満,井上尚亮,甲斐貴久, 高本幸平,アルマンド・キタイン
    • Organizer
      日本エネルギー学会 第8回バイオマス科学会議
    • Place of Presentation
      広島大学(東広島市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Hydrothermal Degradation and Hydrolysis of Cellulosic Materials for High Yield of Dicarboxylic acids from Cellulosic Biomass with Hydrothermal Electrolysis.2012

    • Author(s)
      Mitsuru Sasaki, Goushi Kouzaki, Armando T. Quitain, and Motonobu Goto
    • Organizer
      International Symposium on Supercritical Fluids 2012
    • Place of Presentation
      The Hyatt Regency, San Francisco, CA, USA
    • Related Report
      2012 Research-status Report
  • [Presentation] Un-catalyzed wet oxidation of D-glucose with hydrogen peroxide and its combination with hydrotherml electrolysis2012

    • Author(s)
      Mitsuru Sasaki, Teresa Moreno, Goushi Kouzaki, Motonobu Goto, and Maria Jose Cocero
    • Organizer
      International Symposium on Supercritical Fluids 2012
    • Place of Presentation
      The Hyatt Regency, San Francisco, CA, USA
    • Related Report
      2012 Research-status Report
  • [Presentation] Development of a New Oxidation Method of Biomass-Related Materials with Hybrid Hydrothermal Techniques: 1. Reaction Pathway Analysis for Hydrothermal Electrolysis of Primary Alcohols2012

    • Author(s)
      Mitsuru Sasaki, Junki Saito, and Armando T. Quitain
    • Organizer
      第22回MRS-J学術シンポジウム
    • Place of Presentation
      ワールドポーターズ横浜(横浜市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Development of a New Oxidation Method of Biomass-Related Materials with Hybrid Hydrothermal Techniques: 2. Reaction Pathway Analysis for Hydrothermal Degradation/Electrolysis of Sugars and Furan Derivatives2012

    • Author(s)
      Mitsuru Sasaki, Naoaki Inoue, Goushi Kozaki, Wahyudiono, Armando T. Quitain, and Motonobu Goto
    • Organizer
      第22回MRS-J学術シンポジウム
    • Place of Presentation
      ワールドポーターズ横浜(横浜市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Reaction behavior of various biomass with hydrothermal treatments for recovery of useful carbohydrates and platform chemicals2012

    • Author(s)
      Mitsuru Sasaki; Naoaki Inoue; Kohei Takamoto; Takahisa Kai; Armando T. Quitain
    • Organizer
      The 3rd International Cellulose Conference (ICC2012)
    • Place of Presentation
      シャトレーゼ ガトーキングダム サッポロ(札幌市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 水熱反応場を利用したバイオ化成品誘導技術の開発

    • Author(s)
      佐々木 満
    • Organizer
      化学工学会九州支部北九州化学工学懇話会 第50回講演会(招待講演)
    • Place of Presentation
      九州工業大学, 福岡, 日本
    • Related Report
      2011 Research-status Report
  • [Presentation] 水熱電解法を用いたグルコースから糖酸への選択的酸化技術開発

    • Author(s)
      佐々木満、押川貴成、Teresa Moreno、後藤元信
    • Organizer
      セルロース学会第18回年次大会
    • Place of Presentation
      信州大学工学部, 長野, 日本
    • Related Report
      2011 Research-status Report
  • [Presentation] 水熱場におけるセルロースから糖酸の直接合成に関する検討

    • Author(s)
      佐々木満、押川貴成、柴田優作、Teresa Moreno、後藤元信
    • Organizer
      セルロース学会第18回年次大会
    • Place of Presentation
      信州大学工学部, 長野, 日本
    • Related Report
      2011 Research-status Report
  • [Presentation] Hydrothermal Electrolysis of Biomass to Value-Added Chemicals for Promotion and Biomass Utilization

    • Author(s)
      Mitsuru Sasaki; Asli Yuksel; Takanari Oshikawa; Goushi Kouzaki; Naoaki Inoue, Wahyudiono, Motonobu Goto
    • Organizer
      Supergreen2011(招待講演)
    • Place of Presentation
      北京, 中国
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.chem.kumamoto-u.ac.jp/~sasaki/lab.4.html

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.kumamoto-u.ac.jp/~sasaki/sasaki_index.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 熊本大学工学部物質生命化学科 化学工学研究室ホームページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~sasaki/lab_4.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 佐々木満 ホームページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~sasaki/sasaki_index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 熊本大学工学部物質生命化学科 化学工学研究室ホームページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~sasaki/lab_4.html

    • Related Report
      2012 Research-status Report
  • [Remarks] 佐々木 満 ホームページ

    • URL

      http://www.chem.kumamoto-u.ac.jp/~sasaki/sasaki/index.html

    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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