High Pressure Organic Syntheses in Nanopore Fields under Atmospheric Pressure

• Project/Area Number: 23710109
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Nanostructural science
• Research Institution: Chiba University (2012-2013); Shinshu University (2011)
• Principal Investigator: ITOH Tsutomu 千葉大学, 共用機器センター, 特任助教 (40586822)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
• Keywords: ナノ構造化学 / ナノ表面・界面 / 擬高圧効果 / 分子吸着現象 / エネルギー効率化 / 高圧有機化学 / ナノ材料 / 表面・界面物性

Research Abstract

We developed an efficient ambient pressure synthesis method using quasi-high pressure effects of reactant molecules in carbon nanopores to induce high pressure organic synthesis reactions: Copper phthalocyanine and trans-1,2-cyclohexanediol. This quasi-high pressure organic syntheses in nanopores should be widely applicable to general liquid-phase high pressure organic synthesis reactions without using an autoclave reactor. This new synthesis route can also contribute to establish economical, ecological, and innovative industrial developments.

Research Products

• [Journal Article] Non-porous reference carbon for N2 (77.4 K) and Ar (87.3 K) adsorption (2014)
  • Author(s): Ana Silvestre-Albero, Tsutomu Itoh 他5名
  • Journal Title: Carbon Volume: 66 Pages: 699-704
  • DOI: 10.1016/j.carbon.2013.09.068
  • Peer Reviewed
• [Journal Article] The First Atomistic Modelling-Aided Reproduction of Morphologically Defective Single Walled Carbon Nanohorns (2013)
  • Author(s): S.Furmaniak、A. P.Terzyk、K.Kaneko、P. A. Gauden、P. Kowlaczyk、T. Itoh
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 15巻 Issue: 4 Pages: 1232-1240
  • DOI: 10.1039/c2cp43371k
  • Peer Reviewed
• [Journal Article] Well-Defined Mesoporosity on Lignocellulosic-Derived Activated Carbons (2012)
  • Author(s): A. Silvestre-Albero、M. Goncalves、 T.Itoh、K.Kaneko、M.Endo、M.Thommes、 F. Rodriguez-Reinoso、J. SilvestreAlbero
  • Journal Title: Carbon Volume: 50巻 Issue: 1 Pages: 66-72
  • DOI: 10.1016/j.carbon.2011.08.007
  • Peer Reviewed
• [Journal Article] Formation of CO_x Free H_2 and Cup-stacked Carbon Nanotubes over Nano-Ni Dispersed Single Wall Carbon Nanohorns (2012)
  • Author(s): S. Wang, T. Itoh, T. Fujimori, M. M. Castro, A. S. Albero, F. Rodriguez-Reinoso, T. Ohba, H. Kanoh, K. Kaneko
  • Journal Title: Langmuir Volume: 28 Issue: 19 Pages: 7564-7571
  • DOI: 10.1021/la3006986
  • Peer Reviewed
• [Journal Article] Supercritical Hydrogen Adsorptivity of Amorphous Carbon Mesotubes (2011)
  • Author(s): Yusuke Kawase, Tsutomu Itoh 他11名
  • Journal Title: Ads. Sci. Tech. Volume: 29 Issue: 8 Pages: 819-830
  • DOI: 10.1260/0263-6174.29.8.819
  • Peer Reviewed
• [Presentation] N-ヘテロ環を有する四脚分子の球状集合体を経由した結晶化 (2014)
  • Author(s): 富永昌英、橋本千尋、伊藤努武、小原一朗、山口健太郎、東屋功
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学東山キャンパス
  • Year and Date: 2014-03-28
• [Presentation] N-ヘテロ環を有する四脚分子の球状集合体を経由した結晶化 (2014)
  • Author(s): 富永 昌英、伊藤 努武 他4名
  • Organizer: 日本化学会第94春季年会(2014)
  • Place of Presentation: 名古屋大学 東山キャンパス
• [Presentation] 導電性オリゴマーの金色塗布膜の作製と物性 (2013)
  • Author(s): 田川 麗央、伊藤 努武 他2名
  • Organizer: 色材協会創立85周年記念会議
  • Place of Presentation: タワーホール船堀
• [Presentation] Single WallCarbon Nanotubes Adsorption-Treated with Aromatic Hydrocarbons (2012)
  • Author(s): T.Itoh、K.Fujisawa、S.-Y.Hong、Y.-C.Choi、 K.Takeuchi、 M.Endo、 T.Fujimori、 K.Kaneko
  • Organizer: IACIS2012
  • Place of Presentation: 仙台国際センター
  • Year and Date: 2012-05-17
• [Presentation] Surface Modification of Single Wall Carbon Nanotube by Adding Treatment of Aromatic Hydrocarbons (2012)
  • Author(s): Tsutomu Itoh
  • Organizer: CBNM-3
  • Place of Presentation: Nagano, Japan
• [Presentation] Single Wall Carbon Nanotubes Adsorption-Treated with Aromatic Hydrocarbons (2012)
  • Author(s): Tsutomu Itoh
  • Organizer: IACIS2012
  • Place of Presentation: Sendai, Japan
• [Presentation] π電子共役系分子付加による単層カーボンナノチューブの表面修飾 (2012)
  • Author(s): 伊藤 努武
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川県横浜市
• [Presentation] Preparation and Characterization of Polycyclic Aromatic Hydrocarbon- Pillared Single Wall Carbon Nanotube Bundles (2011)
  • Author(s): Tsutomu Itoh
  • Organizer: SJNANO2011
  • Place of Presentation: Toledo, Spain
  • Year and Date: 2011-09-12
• [Presentation] Polycyclic Aromatic Hydrocarbon-Pillared Single Wall Carbon Nanotube Bundles (2011)
  • Author(s): T. Itoh、T. Fujimori1、K. Fujisawa、K. Oshida、S.-Y. Hong、Y.-C. Choi、K. Takeuchi1、M. Endo、K. Kaneko
  • Organizer: Carbon2011
  • Place of Presentation: 上海理工大学
  • Year and Date: 2011-07-28
• [Presentation] Polycyclic Aromatic Hydrocarbon-Pillared Single Wall Carbon Nanotube Bundles (2011)
  • Author(s): Tsutomu Itoh
  • Organizer: Carbon2011
  • Place of Presentation: Shanghai, China
  • Year and Date: 2011-07-28
• [Patent(Industrial Property Rights)] ナノ空間を利用した有機化合物の製造方法 (2012)
  • Inventor(s): 金子克美、阿部梢、伊藤努武
  • Industrial Property Rights Holder: 金子克美、阿部梢、伊藤努武
  • Industrial Property Rights Type: 特許
  • Filing Date: 2012-05-14
• [Patent(Industrial Property Rights)] ナノ空間を利用した有機化合物の製造方法 (2012)
  • Inventor(s): 金子 克美、阿部 梢、伊藤 努武
  • Industrial Property Rights Holder: 金子 克美、阿部 梢、伊藤 努武
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-111022
  • Filing Date: 2012-05-14